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公开(公告)号:US11692062B2
公开(公告)日:2023-07-04
申请号:US16469336
申请日:2017-12-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Dadasaheb V. Patil , Matthew L. Kuhlman , Peter Johnson
CPC classification number: C08G65/4093 , C08G65/4006 , C08G73/10 , C08G73/1003 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/1071 , C08L79/08
Abstract: A method of making polyetherimide comprising reacting a first diamine having four bonds between the amine groups, a second diamine having greater than or equal to five bonds between the amine groups, 4-halophthalic anhydride and 3-halophthalic in the presence of a solvent and a polymer additive to produce a mixture comprising 3,3′-bis(halophthalimide)s, 3,4′-bis(halophthalimide)s, 4,4′-bis(halophthalimide)s, solvent and the polymer additive wherein the molar ratio of 3-halophthalic anhydride to 4-halophthalic anhydride is 98:02 to 50:50 and the molar ratio of the first diamine to the second diamine is 98:02 to 02:98; and reacting the mixture with an alkali metal salt of a dihydroxy aromatic compound to produce a polyetherimide having a cyclics content less than or equal to 5 weight percent, based on the total weight of the polyetherimide, wherein the polymer additive dissolves in the solvent at the imidization reaction temperature and pressure.
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公开(公告)号:US10899887B2
公开(公告)日:2021-01-26
申请号:US16302268
申请日:2017-05-09
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Dadasaheb V. Patil , Viswanathan Kalyanaraman
Abstract: A copolyimide includes the reaction product of an aromatic dianhydride component including a substituted or unsubstituted pyromellitic dianhydride or a functional derivative thereof and an aromatic bis(ether phthalic anhydride) or a functional derivative thereof, and an organic diamine component comprising a substituted or unsubstituted phenylene diamine and a diaminodiphenyl sulfone. Articles and compositions including the copolyimides and methods of manufacturing a polyimide film are also described.
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3.
公开(公告)号:US20190292319A1
公开(公告)日:2019-09-26
申请号:US16302268
申请日:2017-05-09
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Dadasaheb V. Patil , Viswanathan Kalyanaraman
Abstract: A copolyimide includes the reaction product of an aromatic dianhydride component including a substituted or unsubstituted pyromellitic dianhydride or a functional derivative thereof and an aromatic bis(ether phthalic anhydride) or a functional derivative thereof, and an organic diamine component comprising a substituted or unsubstituted phenylene diamine and a diaminodiphenyl sulfone. Articles and compositions including the copolyimides and methods of manufacturing a polyimide film are also described.
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4.
公开(公告)号:US20190127575A1
公开(公告)日:2019-05-02
申请号:US16093282
申请日:2017-04-14
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Dadasaheb V. Patil , Prakash Sista , Robert Russell Gallucci
Abstract: A polymer composition that includes, based on the total weight of the polymers: 1-99 weight percent, of a polymer component comprising a polyarylether ketone, a polybenzimdazole, a polyimide, a poly(aryl ether sulfone), a poly(phenylene sulfide), or a combination comprising at least one of the foregoing; and 1-99 weight percent, of a polyisoindolinone, wherein the polyisoindolinone comprises: 1-100 mole percent, preferably 5-100 mole percent, of isoindolinone ether ketone units of the formula (I) and 0-99 mole percent, of arylene ether ketone units of the formula (II) wherein the variables are as defined herein.
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5.
公开(公告)号:US20190040201A1
公开(公告)日:2019-02-07
申请号:US16073518
申请日:2017-01-30
Applicant: SABIC Global Technologies B.V.
Inventor: Dadasaheb V. Patil , Manojkumar Chellamuthu
Abstract: A polymer composition including a polyetherimide comprising repeating units of formula (1) and formula (2) [Formula should be inserted here] wherein the repeating units of formula (1) are present in an amount of at least 10 mole %, preferably 20 to 100 mole %, Z is independently at each occurrence derived from a biphenol; Z′ is independently at each occurrence a group of formulas (3) to (13) as defined herein, preferably bisphenol A, 1,2-dihydroxybenzene, 1,1-bis(4-hydroxyphenyl)-1-phenyl-ethane, isophorone bisphenol (1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane), spirobiindane bisphenol, dimethylindanone bisphenol, 3,3′-dimethylbisphenol cyclohexane, or fluorenone bisphenol; and R is independently at each occurrence as a C6-20 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C2-20 alkylene group or a halogenated derivative thereof, a C3-8 cycloalkylene group or halogenated derivative thereof; wherein the polyetherimide has a Tg of greater than 200° C.
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