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公开(公告)号:US20180194868A1
公开(公告)日:2018-07-12
申请号:US15754445
申请日:2016-07-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Orass M. Hamed , Nayef M. Al-Enazi , Vugar O. Aliyev , Abderrahman Meddad
CPC classification number: C08F2/34 , B01J8/0015 , B01J21/063 , B01J21/08 , B01J23/002 , B01J23/26 , B01J35/023 , B01J35/1023 , B01J35/1047 , B01J37/0203 , B01J37/0205 , B01J37/088 , B01J2523/00 , B60K15/03 , C08F10/02 , C08F110/14 , C08F2500/07 , C08F210/16 , C08F4/69 , C08F4/6372 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/04 , B01J2523/47 , B01J2523/67
Abstract: The invention relates to a gas phase polymerisation process for the production of ethylene polymers in the presence of a catalyst composition based on a chromium compound, a titanium compound and a silica support material. The silica support material has a surface area (SA) between 685 m2/g and 800 m2/g, a pore volume (PV) between 1.65 and 1.85 cm3/g and an average particle size in the range between 25 and 35 micrometres. The catalyst composition is injected by a dry catalyst feeder into the polymerization reactor.
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公开(公告)号:US11001651B2
公开(公告)日:2021-05-11
申请号:US16340918
申请日:2017-10-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Patrick Elisabeth Luc Voets , Abderrahman Meddad , Henrica Norberta Alberta Maria Steenbakkers-Menting , Akhlaq Moman
IPC: C08F10/06 , C08F110/06 , B29C55/12 , C08J5/18 , B29C55/00 , B29K623/00
Abstract: The invention relates to a biaxially oriented polypropylene (BOPP) film comprising a propylene homopolymer or propylene-ethylene copolymer having an ethylene content of at most 1.0 wt % based on the propylene-ethylene copolymer having an Mw/Mn in the range from 5.0 to 12, wherein Mw stands for the weight average molecular weight and Mn stands for the number average weight and wherein Mw and Mn are measured according to ASTM D6474-12, an XS in the range from 1.0 to 6.0 wt %, wherein XS stands for the amount of xylene solubles which are measured according to ASTM D 5492-10, a melt flow rate in the range of 1 to 10 dg/min as measured according to IS01133 (2.16 kg/230° C.) and a crystal size distribution as indicated by a height/width ratio of the highest peak of the first cooling curve of at least 0.70 W/g° C. as determined by ASTM D3418-08 using a heating and cooling rate of 10° C./min.
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公开(公告)号:US10106631B2
公开(公告)日:2018-10-23
申请号:US15319889
申请日:2014-06-20
Applicant: SABIC GLOBAL TECHNOLOGIES B.V. , Abderrahman Meddad , Mansour Taftaf , Hesham Al-Shobilly
Inventor: Abderrahman Meddad , Mansour Taftaf , Hesham Al-Shobilly
IPC: C08F110/06
Abstract: The invention relates to a process for the preparation of polypropylene having —a molecular weight (Mw) of 450,000-950,000, —a molecular weight distribution of 3-6, —a melt flow in the range of 7-14 dg/min measured with a load of 21.6 kg at 230° C. or 0.05-2 dg/min measured with a load of 2.16 kg at 230° C. and —a xylene soluble content of 2-6 wt % by converting propylene into the polypropylene without pre-polymerization in the presence of a polymerization catalyst under a condition where the volume ratio of H2 to propylene is at most 0.0020, wherein the catalyst comprises a catalyst component, a co-catalyst and an external donor, wherein the catalyst component is obtained by a process wherein a compound with formula Mg(OAlk)xCly wherein x is larger than 0 and smaller than 2, y equals 2−x and each Alk, independently, represents an alkyl group, is contacted with a titanium tetraalkoxide and/or an alcohol in the presence of an inert dispersant to give an intermediate reaction product and wherein the intermediate reaction product is contacted with titanium tetrachloride in the presence of an internal donor, and wherein the molar ratio of the co-catalyst to the external donor is 3.3-5.2, preferably 3.8-4.4.
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公开(公告)号:US20240035203A1
公开(公告)日:2024-02-01
申请号:US18266106
申请日:2021-12-07
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Abderrahman Meddad , Fahad Al-Mutairy , Henrica Norberta Alberta Maria Steenbakkers-Menting , Hendrik Kormelink , Tinashe Victor Mandishonha Ndoro , Gert Boven , Ronald Julianus Peter Schipper , Marco Dohmen
CPC classification number: D01D5/0985 , D01F6/06
Abstract: A melt-blown web contains melt-blown fibers obtained by a) melt-mixing a propylene-based polymer, a first peroxide and a second peroxide at temperatures between 180° C. and 240° C., preferably between 200° C. and 220° C., wherein the first peroxide has a half-life time of 1 hour at a first temperature T1/2 1 and the second peroxide has a half-life time of 1 hour at a second temperature T1/2 2, wherein T1/2 2 is higher than T1/2 1 and b) processing the composition obtained by step a) by a melt-blown process at temperatures between 240° C. and 300° C., preferably between 245° C. and 280° C., to provide the melt-blown fibers.
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公开(公告)号:US09988474B2
公开(公告)日:2018-06-05
申请号:US15320040
申请日:2015-06-16
Applicant: SABIC Global Technologies B.V.
Inventor: Hesham A. Al-Shobilly , Ahmad Abdullah Alshaiban , Abdulrahman Albeladi , Abderrahman Meddad , Riyadh A. Al Humoud
IPC: C08F210/06
CPC classification number: C08F210/06 , C08F4/6565 , C08F4/651 , C08F210/16 , C08F2500/01 , C08F2500/12 , C08F2500/24 , C08F2500/18
Abstract: The invention relates to a process for the preparation of ethylene-propylene copolymers having —a weight average molecular weight of 800,000-1,800,000, —a molecular weight distribution of 3-8, —an ethylene content of 1-10 wt %, preferably 1.5 to 5.5 wt %. —a melt flow in the range of 1.5-8 dg/min measured with a load of 21.6 kg at 230° C. and —a xylene soluble content of 2-15 wt % by converting propylene into the UHMWEP copolymer without pre-polymerization in the presence of a polymerization catalyst under a condition where the volume ratio of H2 to propylene is at most 0.0020, wherein the catalyst comprises a catalyst component and a co-catalyst, wherein the catalyst component is obtained by a process wherein a compound with formula Mg(OAIk)xCly wherein x is larger than 0 and smaller than 2, y equals 2−x and each Alk, independently, represents an alkyl group, is contacted with a titanium tetraalkoxide and/or an alcohol in the presence of an inert dispersant to give an intermediate reaction product and wherein the intermediate reaction product is contacted with titanium tetrachloride in the presence of an internal donor.
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公开(公告)号:US20170129973A1
公开(公告)日:2017-05-11
申请号:US15319889
申请日:2014-06-20
Applicant: Abderrahman Meddad , Mansour Taftaf , Hesham Al-Shobilly , SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Abderrahman Meddad , Mansour Taftaf , Hesham Al-Shobilly
IPC: C08F110/06
CPC classification number: C08F110/06 , C08F2500/01 , C08F2500/12 , C08F2500/24 , C08F4/6565
Abstract: The invention relates to a process for the preparation of polypropylene having —a molecular weight (Mw) of 450,000-950,000, —a molecular weight distribution of 3-6, —a melt flow in the range of 7-14 dg/min measured with a load of 21.6 kg at 230° C. or 0.05-2 dg/min measured with a load of 2.16 kg at 230° C. and —a xylene soluble content of 2-6 wt % by converting propylene into the polypropylene without pre-polymerization in the presence of a polymerization catalyst under a condition where the volume ratio of H2 to propylene is at most 0.0020, wherein the catalyst comprises a catalyst component, a co-catalyst and an external donor, wherein the catalyst component is obtained by a process wherein a compound with formula Mg(OAlk)xCly wherein x is larger than 0 and smaller than 2, y equals 2-x and each Alk, independently, represents an alkyl group, is contacted with a titanium tetraalkoxide and/or an alcohol in the presence of an inert dispersant to give an intermediate reaction product and wherein the intermediate reaction product is contacted with titanium tetrachloride in the presence of an internal donor, and wherein the molar ratio of the co-catalyst to the external donor is 3.3-5.2, preferably 3.8-4.4.
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公开(公告)号:US12091535B2
公开(公告)日:2024-09-17
申请号:US17289055
申请日:2019-11-15
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Abderrahman Meddad , Mansour Al-Otaibi , Fahad S. Al-Mutairy
CPC classification number: C08L23/16 , C08K5/098 , C08K5/20 , C08L23/0815 , D04H3/007 , C08L2203/12 , C08L2205/02
Abstract: The invention relates to a composition comprising: (A) a random copolymer of propylene and a comonomer, wherein the comonomer is ethylene and/or an α-olefin having 4 to 8 carbon atoms, wherein the amount of propylene-derived units is 90 to 99 wt % and the amount of comonomer-derived units is 1.0 to 10 wt % based on the random copolymer, (B) a C10-C30 aliphatic carboxylic acid amide and (C) a nucleating agent comprising a metal salt of hexahydrophthalic acid represented by formula (I) wherein M1 and M2 are the same or different, and may be combined into one cation, and are selected from at least one metal cation of calcium, strontium, lithium, and monobasic aluminum; and wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 are either the same or different and are individually selected from the group consisting of hydrogen, C1-C9 alkyl, hydroxy, C1-C9 alkoxy, C1-C9 alkyleneoxy, amine, and C1-C9 alkylamine, halogens, and phenyl, wherein the amount of (B) in the composition is 1000 to 5000 ppm based on the total weight of the composition and the amount of (C) in the composition is 100 to 1000 ppm based on the total weight of the composition.
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8.
公开(公告)号:US11591456B2
公开(公告)日:2023-02-28
申请号:US17047584
申请日:2019-04-24
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Anantharaman Dhanabalan , Maria Soliman , Anirban Ganguly , Sangita Nandi , Prem Prakash Pathak , Kummetha Raghunatha Reddy , Abderrahman Meddad , Sadasivam Gopalakrishnan
Abstract: Polymer blends, methods of making the polymer blends, and articles of manufacture that include the polymer blends are described. A polymer blend can include a high density polyethylene (HDPE) polymer and a random block copolymer. The random block copolymer can include two different saturated alkane blocks between aromatic blocks (e.g., two styrenic blocks).
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公开(公告)号:US10577435B2
公开(公告)日:2020-03-03
申请号:US15754445
申请日:2016-07-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Orass M. Hamed , Nayef M. Al-Enazi , Vugar O. Aliyev , Abderrahman Meddad
IPC: C08F2/34 , C08F10/02 , C08F110/14 , B01J21/06 , B01J21/08 , B01J23/26 , B01J35/02 , B01J35/10 , B01J37/08 , B01J37/02 , B01J8/00 , B60K15/03 , B01J23/00
Abstract: The invention relates to a gas phase polymerisation process for the production of ethylene polymers in the presence of a catalyst composition based on a chromium compound, a titanium compound and a silica support material. The silica support material has a surface area (SA) between 685 m2/g and 800 m2/g, a pore volume (PV) between 1.65 and 1.85 cm3/g and an average particle size in the range between 25 and 35 micrometres. The catalyst composition is injected by a dry catalyst feeder into the polymerization reactor.
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公开(公告)号:US20190023870A1
公开(公告)日:2019-01-24
申请号:US15757665
申请日:2016-09-02
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Imam Khasim Hadimani , Ahmad Abdullah Alshaiban , Abdulrahman Al-Beladi , Abderrahman Meddad , Musaad Al-Sadhan , Saad Nasser Al-Hussain
IPC: C08K5/1545 , C08F210/06
Abstract: The invention relates to a composition comprising A) polyolefin and B) one or more compounds selected from the group of galactopyranoside derivatives, galactopyranose derivatives, mannopyranoside derivatives, mannopyranose derivatives, mannofuranoside derivatives and mannofuranose derivatives, wherein the amount of component B) is from 0.25 to 5 wt % based on the total composition. The invention relates to use of the composition in injection molding.
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