公开(公告)号：US20170145128A1

公开(公告)日：2017-05-25

申请号：US15320040

申请日：2015-06-16

Applicant: SABIC Global Technologies B.V.

Inventor： Hesham A. Al-Shobilly ,  Ahmad Abdullah Alshaiban ,  Abdulrahman Albeladi ,  Abderrahman Meddad ,  Riyadh A. Al Humoud

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F4/6565 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18

Abstract: The invention relates to a process for the preparation of ethylene-propylene copolymers having —a weight average molecular weight of 800,000-1,800,000, —a molecular weight distribution of 3-8, —an ethylene content of 1-10 wt %, preferably 1.5 to 5.5 wt %. —a melt flow in the range of 1.5-8 dg/min measured with a load of 21.6 kg at 230° C. and —a xylene soluble content of 2-15 wt % by converting propylene into the UHMWEP copolymer without pre-polymerization in the presence of a polymerization catalyst under a condition where the volume ratio of H2 to propylene is at most 0.0020, wherein the catalyst comprises a catalyst component and a co-catalyst, wherein the catalyst component is obtained by a process wherein a compound with formula Mg(OAIk)xCly wherein x is larger than 0 and smaller than 2, y equals 2−x and each Alk, independently, represents an alkyl group, is contacted with a titanium tetraalkoxide and/or an alcohol in the presence of an inert dispersant to give an intermediate reaction product and wherein the intermediate reaction product is contacted with titanium tetrachloride in the presence of an internal donor.

公开(公告)号：US09988474B2

公开(公告)日：2018-06-05

申请号：US15320040

申请日：2015-06-16

Applicant: SABIC Global Technologies B.V.

Inventor： Hesham A. Al-Shobilly ,  Ahmad Abdullah Alshaiban ,  Abdulrahman Albeladi ,  Abderrahman Meddad ,  Riyadh A. Al Humoud

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F4/6565 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18

Abstract: The invention relates to a process for the preparation of ethylene-propylene copolymers having —a weight average molecular weight of 800,000-1,800,000, —a molecular weight distribution of 3-8, —an ethylene content of 1-10 wt %, preferably 1.5 to 5.5 wt %. —a melt flow in the range of 1.5-8 dg/min measured with a load of 21.6 kg at 230° C. and —a xylene soluble content of 2-15 wt % by converting propylene into the UHMWEP copolymer without pre-polymerization in the presence of a polymerization catalyst under a condition where the volume ratio of H2 to propylene is at most 0.0020, wherein the catalyst comprises a catalyst component and a co-catalyst, wherein the catalyst component is obtained by a process wherein a compound with formula Mg(OAIk)xCly wherein x is larger than 0 and smaller than 2, y equals 2−x and each Alk, independently, represents an alkyl group, is contacted with a titanium tetraalkoxide and/or an alcohol in the presence of an inert dispersant to give an intermediate reaction product and wherein the intermediate reaction product is contacted with titanium tetrachloride in the presence of an internal donor.