公开(公告)号：US09765256B2

公开(公告)日：2017-09-19

申请号：US14786623

申请日：2014-05-13

申请人： ROSNEFT OIL COMPANY

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Tatyana Modestovna Yumasheva

IPC分类号： C09K8/80 ,  C08F32/06 ,  C08F132/06

CPC分类号： C09K8/80 ,  C08F32/06 ,  C08F132/06

摘要： The polymer proppant and method for producing the same relate to oil and gas production technology using materials of high-molecular weight compounds with higher requirements for physical and mechanical properties. The proppant is used as propping granules utilized in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant whose material provides a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The polymer proppant represents microspheres of metathesis-radically cross-linked mixture of oligocyclopentadienes.

公开(公告)号：US20160075939A1

公开(公告)日：2016-03-17

申请号：US14786642

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTIVO "ROSNEFT OIL COMPANY"

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva

IPC分类号： C09K8/80

CPC分类号： C09K8/80 ,  C08F220/10

摘要： The material for proppant and method for producing the same relate to the chemistry of high-molecular weight compounds, and more particularly, to polymer materials with high requirements for physical and mechanical properties, for instance, for the production of proppants, i.e., propping granules, used in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The method consists in the following. A mixture of oligocyclopentadienes is obtained by heating dicyclopentadiene (DCPD) to a temperature of 150-220° C. and holding at this temperature for 15-360 minutes. The oligomerization of dicyclopentadiene occurs. The mixture of oligomers is cooled down to 20-50° C., and polymer stabilizers, radical initiators, methacrylates and a catalyst are sequentially added thereto. The resultant polymer matrix is heated up to a temperature of 50-340° C. and is held at this temperature for 1-360 minutes, and thereafter is cooled down to room temperature. A metathesis polymerization (MP) and radical polymerization (RP) cross-linkage of the mixture of oligocyclopentadienes with methacrylic esters occurs.

摘要翻译： 用于支撑剂的材料及其制备方法涉及高分子量化合物的化学性质，更具体地说涉及对物理和机械性能要求高的聚合物材料，例如用于生产支撑剂，即支撑颗粒 用于石油和天然气生产中通过水力压裂成形的方法。 通过实施本发明的技术结果是在不低于100℃的温度下提供抗压强度至少为150MPa的支撑剂材料的热强度增加。该方法包括以下。 通过将二环戊二烯（DCPD）加热至150-220℃并在该温度下保持15-360分钟来获得低聚环戊二烯的混合物。 发生二环戊二烯的低聚。 将低聚物的混合物冷却至20-50℃，并向其中依次加入聚合物稳定剂，自由基引发剂，甲基丙烯酸酯和催化剂。 将所得聚合物基体加热至50-340℃，并在该温度下保持1-360分钟，然后冷却至室温。 发生低聚环戊二烯与甲基丙烯酸酯的混合物的易位聚合（MP）和自由基聚合（RP）交联。

公开(公告)号：US09926487B2

公开(公告)日：2018-03-27

申请号：US14786607

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO “ROSNEFT OIL COMPANY”

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80 ,  C08F232/06 ,  C08F220/18

CPC分类号： C09K8/80 ,  C08F220/18 ,  C08F232/06

摘要： The increased thermal strength polymer proppant and method for producing the same relate to the oil and gas production technology using materials of high-molecular compounds, especially to proppants of polymer materials with high requirements for the physical and mechanical characteristics, utilized as propping granules in the oil and gas production by a method of hydraulic fracturing. The proppant is made of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The proppant represents microspheres having a roundness and sphericity of at least 0.9 for no less than 80% by weight, whose average size being in the range 0.25-1.1 mm and a bulk density being in the range of 0.5-0.7 g/cm3. The technical result is an increase in thermal strength of the proppant material, providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

公开(公告)号：US20160130498A1

公开(公告)日：2016-05-12

申请号：US14786623

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO "ROSNEFT OIL COMPANY"

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Tatyana Modestovna Yumasheva

IPC分类号： C09K8/80

CPC分类号： C09K8/80 ,  C08F32/06 ,  C08F132/06

摘要： The polymer proppant and method for producing the same relate to oil and gas production technology using materials of high-molecular weight compounds with higher requirements for physical and mechanical properties. The proppant is used as propping granules utilized in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant whose material provides a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The polymer proppant represents microspheres of metathesis-radically cross-linked mixture of oligocyclopentadienes.

摘要翻译： 聚合物支撑剂及其制备方法涉及使用对物理和机械性能要求较高的高分子量化合物材料的油气生产技术。 支撑剂用作石油和天然气生产中的支撑颗粒，通过水力压裂成形的方法。 通过实施本发明实现的技术结果是在不低于100℃的温度下其材料提供至少150MPa的抗压强度的支撑剂的热强度的增加。聚合物支撑剂表示复分解的微球 低聚环戊二烯的交联混合物。

公开(公告)号：US10113103B2

公开(公告)日：2018-10-30

申请号：US14786598

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO “ROSNEFT OIL COMPANY”

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80 ,  C08G61/08 ,  C08F232/08

摘要： A polymer material for proppant in the form of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters is obtained by mixing dicyclopentadiene with methacrylic esters and polymer stabilizers, heating the mixture to a temperature of 150-220° C., holding at said temperature for 15-360 minutes, and then cooling down to 20-50° C. A radical initiator and a catalyst are added successively to the resultant mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The polymer matrix is heated to a temperature of 50-340° C., is held at this temperature for 1-360 minutes and then is cooled to room temperature. A technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material, providing a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

公开(公告)号：US20160075938A1

公开(公告)日：2016-03-17

申请号：US14786598

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO "ROSNEFT OIL COMPANY"

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80

CPC分类号： C09K8/80 ,  C08F232/08 ,  C08G61/08 ,  C08G2261/418

摘要： A polymer material for proppant in the form of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters is obtained by mixing dicyclopentadiene with methacrylic esters and polymer stabilizers, heating the mixture to a temperature of 150-220° C., holding at said temperature for 15-360 minutes, and then cooling down to 20-50° C. A radical initiator and a catalyst are added successively to the resultant mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The polymer matrix is heated to a temperature of 50-340° C., is held at this temperature for 1-360 minutes and then is cooled to room temperature. A technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material, providing a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

摘要翻译： 通过将二环戊二烯与甲基丙烯酸酯和聚合物稳定剂混合，将该混合物混合至150-220℃的温度，通过将该混合物加热至150-220℃的温度，得到支链剂聚合物材料，该聚合物材料为易位 - 自由基交联的低聚环戊二烯和甲基碳代降冰片烯酯的混合物 在所述温度下15-360分钟，然后冷却至20-50℃。自由基引发剂和催化剂依次加入到所得的低聚环戊二烯和甲基碳代降冰片烯酯的混合物中。 将聚合物基体加热到50-340℃的温度，在该温度下保持1-360分钟，然后冷却至室温。 通过实施本发明而获得的技术结果是支撑剂材料的热强度增加，在不低于100℃的温度下提供至少150MPa的抗压强度。

公开(公告)号：US10053620B2

公开(公告)日：2018-08-21

申请号：US14786642

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO “ROSNEFT OIL COMPANY”

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva

IPC分类号： C09K8/60 ,  C09K8/528 ,  C09K8/80 ,  C08F220/10

CPC分类号： C09K8/80 ,  C08F220/10

摘要： The material for proppant and method for producing the same relate to the chemistry of high-molecular weight compounds, and more particularly, to polymer materials with high requirements for physical and mechanical properties, for instance, for the production of proppants, i.e., propping granules, used in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The method consists in the following. A mixture of oligocyclopentadienes is obtained by heating dicyclopentadiene (DCPD) to a temperature of 150-220° C. and holding at this temperature for 15-360 minutes. The oligomerization of dicyclopentadiene occurs. The mixture of oligomers is cooled down to 20-50° C., and polymer stabilizers, radical initiators, methacrylates and a catalyst are sequentially added thereto. The resultant polymer matrix is heated up to a temperature of 50-340° C. and is held at this temperature for 1-360 minutes, and thereafter is cooled down to room temperature. A metathesis polymerization (MP) and radical polymerization (RP) cross-linkage of the mixture of oligocyclopentadienes with methacrylic esters occurs.

公开(公告)号：US20160060510A1

公开(公告)日：2016-03-03

申请号：US14786607

申请日：2014-05-13

申请人： (OTKRYTOE AKTSYONERNOE OBSCHESTVO "ROSNEFT OIL COMPANY"

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80

CPC分类号： C09K8/80 ,  C08F220/18 ,  C08F232/06

摘要： The increased thermal strength polymer proppant and method for producing the same relate to the oil and gas production technology using materials of high-molecular compounds, especially to proppants of polymer materials with high requirements for the physical and mechanical characteristics, utilized as propping granules in the oil and gas production by a method of hydraulic fracturing. The proppant is made of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The proppant represents microspheres having a roundness and sphericity of at least 0.9 for no less than 80% by weight, whose average size being in the range 0.25-1.1 mm and a bulk density being in the range of 0.5-0.7 g/cm3. The technical result is an increase in thermal strength of the proppant material, providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

摘要翻译： 增加的热强度聚合物支撑剂及其制备方法涉及使用高分子化合物材料的油气生产技术，特别是用于物理和机械特性要求高的聚合物材料的支撑剂，用作支撑颗粒在 通过水力压裂的方法生产油气。 支撑剂由低聚环戊二烯和甲基羧基降冰片烯酯的复分解自由基交联混合物制成。 支撑剂代表不小于80重量％的圆度和球形度至少为0.9的微球，其平均尺寸在0.25-1.1mm的范围内，堆积密度在0.5-0.7g / cm3的范围内。 技术结果是支撑剂材料的热强度增加，在不低于100℃的温度下提供至少150MPa的抗压强度。