公开(公告)号：US10113103B2

公开(公告)日：2018-10-30

申请号：US14786598

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO “ROSNEFT OIL COMPANY”

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80 ,  C08G61/08 ,  C08F232/08

摘要： A polymer material for proppant in the form of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters is obtained by mixing dicyclopentadiene with methacrylic esters and polymer stabilizers, heating the mixture to a temperature of 150-220° C., holding at said temperature for 15-360 minutes, and then cooling down to 20-50° C. A radical initiator and a catalyst are added successively to the resultant mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The polymer matrix is heated to a temperature of 50-340° C., is held at this temperature for 1-360 minutes and then is cooled to room temperature. A technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material, providing a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

公开(公告)号：US20160075938A1

公开(公告)日：2016-03-17

申请号：US14786598

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO "ROSNEFT OIL COMPANY"

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80

CPC分类号： C09K8/80 ,  C08F232/08 ,  C08G61/08 ,  C08G2261/418

摘要： A polymer material for proppant in the form of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters is obtained by mixing dicyclopentadiene with methacrylic esters and polymer stabilizers, heating the mixture to a temperature of 150-220° C., holding at said temperature for 15-360 minutes, and then cooling down to 20-50° C. A radical initiator and a catalyst are added successively to the resultant mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The polymer matrix is heated to a temperature of 50-340° C., is held at this temperature for 1-360 minutes and then is cooled to room temperature. A technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material, providing a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

摘要翻译： 通过将二环戊二烯与甲基丙烯酸酯和聚合物稳定剂混合，将该混合物混合至150-220℃的温度，通过将该混合物加热至150-220℃的温度，得到支链剂聚合物材料，该聚合物材料为易位 - 自由基交联的低聚环戊二烯和甲基碳代降冰片烯酯的混合物 在所述温度下15-360分钟，然后冷却至20-50℃。自由基引发剂和催化剂依次加入到所得的低聚环戊二烯和甲基碳代降冰片烯酯的混合物中。 将聚合物基体加热到50-340℃的温度，在该温度下保持1-360分钟，然后冷却至室温。 通过实施本发明而获得的技术结果是支撑剂材料的热强度增加，在不低于100℃的温度下提供至少150MPa的抗压强度。

公开(公告)号：US09926487B2

公开(公告)日：2018-03-27

申请号：US14786607

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO “ROSNEFT OIL COMPANY”

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80 ,  C08F232/06 ,  C08F220/18

CPC分类号： C09K8/80 ,  C08F220/18 ,  C08F232/06

摘要： The increased thermal strength polymer proppant and method for producing the same relate to the oil and gas production technology using materials of high-molecular compounds, especially to proppants of polymer materials with high requirements for the physical and mechanical characteristics, utilized as propping granules in the oil and gas production by a method of hydraulic fracturing. The proppant is made of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The proppant represents microspheres having a roundness and sphericity of at least 0.9 for no less than 80% by weight, whose average size being in the range 0.25-1.1 mm and a bulk density being in the range of 0.5-0.7 g/cm3. The technical result is an increase in thermal strength of the proppant material, providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

公开(公告)号：US10053620B2

公开(公告)日：2018-08-21

申请号：US14786642

申请日：2014-05-13

申请人： OTKRYTOE AKTSYONERNOE OBSCHESTVO “ROSNEFT OIL COMPANY”

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva

IPC分类号： C09K8/60 ,  C09K8/528 ,  C09K8/80 ,  C08F220/10

CPC分类号： C09K8/80 ,  C08F220/10

摘要： The material for proppant and method for producing the same relate to the chemistry of high-molecular weight compounds, and more particularly, to polymer materials with high requirements for physical and mechanical properties, for instance, for the production of proppants, i.e., propping granules, used in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The method consists in the following. A mixture of oligocyclopentadienes is obtained by heating dicyclopentadiene (DCPD) to a temperature of 150-220° C. and holding at this temperature for 15-360 minutes. The oligomerization of dicyclopentadiene occurs. The mixture of oligomers is cooled down to 20-50° C., and polymer stabilizers, radical initiators, methacrylates and a catalyst are sequentially added thereto. The resultant polymer matrix is heated up to a temperature of 50-340° C. and is held at this temperature for 1-360 minutes, and thereafter is cooled down to room temperature. A metathesis polymerization (MP) and radical polymerization (RP) cross-linkage of the mixture of oligocyclopentadienes with methacrylic esters occurs.

公开(公告)号：US20160060510A1

公开(公告)日：2016-03-03

申请号：US14786607

申请日：2014-05-13

申请人： (OTKRYTOE AKTSYONERNOE OBSCHESTVO "ROSNEFT OIL COMPANY"

发明人： Vladimir Vladimirovich Afanasiev ,  Sergey Anatolievich Alkhimov ,  Nataliya Borisovna Bespalova ,  Egor Vladimirovich Shutko ,  Tatyana Modestovna Yumasheva ,  Igor Alekseevich Kiselev ,  Olga Vasilievna Masloboyschikova

IPC分类号： C09K8/80

CPC分类号： C09K8/80 ,  C08F220/18 ,  C08F232/06

摘要： The increased thermal strength polymer proppant and method for producing the same relate to the oil and gas production technology using materials of high-molecular compounds, especially to proppants of polymer materials with high requirements for the physical and mechanical characteristics, utilized as propping granules in the oil and gas production by a method of hydraulic fracturing. The proppant is made of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The proppant represents microspheres having a roundness and sphericity of at least 0.9 for no less than 80% by weight, whose average size being in the range 0.25-1.1 mm and a bulk density being in the range of 0.5-0.7 g/cm3. The technical result is an increase in thermal strength of the proppant material, providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C.

摘要翻译： 增加的热强度聚合物支撑剂及其制备方法涉及使用高分子化合物材料的油气生产技术，特别是用于物理和机械特性要求高的聚合物材料的支撑剂，用作支撑颗粒在 通过水力压裂的方法生产油气。 支撑剂由低聚环戊二烯和甲基羧基降冰片烯酯的复分解自由基交联混合物制成。 支撑剂代表不小于80重量％的圆度和球形度至少为0.9的微球，其平均尺寸在0.25-1.1mm的范围内，堆积密度在0.5-0.7g / cm3的范围内。 技术结果是支撑剂材料的热强度增加，在不低于100℃的温度下提供至少150MPa的抗压强度。