Radiation curable inkjet ink sets

    公开(公告)号:US12122928B2

    公开(公告)日:2024-10-22

    申请号:US17777472

    申请日:2020-11-06

    申请人: AGFA NV

    摘要: A radiation curable inkjet ink set comprising a cyan inkjet ink containing a beta-copper phthalocyanine pigment and a polymerizable composition; a magenta inkjet ink containing a magenta or red pigment and a polymerizable composition; a yellow inkjet ink containing a yellow pigment and a polymerizable composition; and a black inkjet ink containing a carbon black pigment and a polymerizable composition; wherein the polymerizable compositions of the cyan, magenta, yellow and black inkjet inks include on average: a) 20.0 to 40.0 wt % of phenoxyethyl acrylate; b) 23.0 to 32.0 wt % of isobornyl acrylate; c) 1.0 to 14.4 wt % of monomer selected from the group consisting of 4-acryloylmorpholine and a monomer according to Formula (I), wherein X represents C or O, n represents 1, 2 or 3 and m represents 0 or 1; and d) up to 14.0 wt % of a multifunctional monomer or oligomer; wherein all weight percentages (wt %) are based upon the total weight of the inkjet ink; and wherein 0, 1 or 2 of the cyan, magenta, yellow and black inkjet inks deviate in a range a) to d) and this deviation is no more than 1.0 wt %.

    SHELF-STABLE BUILD MATERIALS FOR 3D PRINTING

    公开(公告)号:US20240317909A1

    公开(公告)日:2024-09-26

    申请号:US18733455

    申请日:2024-06-04

    申请人: 3D Systems, Inc.

    摘要: build materials for 3D printing applications are described herein which, in some embodiments, comprise monomeric species operable for producing articles with high Tg and/or high heat deflection temperature while maintaining shelf stability. In one aspect, a polymerizable liquid comprises at least 20 weight percent isocyanurate polyacrylate; a photoinitiator component; and a crystallization inhibitor component comprising monomeric curable material, oligomeric curable material or mixtures thereof, wherein the polymerizable liquid does not exhibit crystallization over a period of 28 days at a storage temperature of 5-10° C.

    Ink jet recording method
    6.
    发明授权

    公开(公告)号:US12097714B2

    公开(公告)日:2024-09-24

    申请号:US17204951

    申请日:2021-03-18

    摘要: Provided is an ink jet recording method including recording an infrared absorbing image by applying a first ink, which contains an infrared absorber and a first curable compound, onto an impermeable substrate by an ink jet method, semi-curing the infrared absorbing image by irradiating the infrared absorbing image with active energy rays, recording a non-infrared absorbing image by applying a second ink, which has a content of the infrared absorber of lower than 0.1% by mass and contains a second curable compound, to a surface of the substrate with the infrared absorbing image by the ink jet method, and curing the semi-cured infrared absorbing image and the non-infrared absorbing image by irradiating these images with active energy rays.

    Ink Set and Inkjet Printing Methods
    7.
    发明公开

    公开(公告)号:US20240309233A1

    公开(公告)日:2024-09-19

    申请号:US18547019

    申请日:2022-02-15

    申请人: Agfa NV

    摘要: An ink set for manufacturing decorative laminates including pigmented free radical curable inkjet inks and a free radical curable liquid, wherein the pigmented free radical curable inkjet inks include a colour pigment and a polymerizable composition containing 10 to 90 wt % of one or more monofunctional polymerizable compounds; wherein the free radical curable liquid includes a polymerizable composition containing 15 wt % or more of polyfunctional polymerizable compounds and 15 wt % or more of a specific monofunctional polymerizable compound; and wherein all weight percentages wt % are based upon the total weight of the polymerizable composition in the pigmented free radical curable inkjet ink or the polymerizable composition in the free radical curable liquid.

    POLYESTER RESIN, ACTIVE ENERGY RAY-CURABLE INK COMPOSITION CONTAINING SAME, AND METHOD FOR PRODUCING SAME

    公开(公告)号:US20240301223A1

    公开(公告)日:2024-09-12

    申请号:US18283422

    申请日:2022-01-27

    摘要: To provide a resin for ink compositions that is usable in the preparation of active energy ray-curable ink compositions and that can increase a proportion of biomass-derived ingredients.
    A polyester resin that is a condensation polymer of an acid ingredient including a fatty acid containing an epoxy group and a polybasic acid, and a polyhydric alcohol is employed, wherein the fatty acid has a peroxide value of 1 meq/kg or more in terms of triglyceride. Such a resin is prepared by a process for producing the polyester resin through heating a mixture containing an epoxidized oil or fat, a polybasic acid, and a polyhydric alcohol to subject to a transesterification reaction and a polycondensation reaction, wherein the epoxidized oil or fat has a peroxide value of 1 meq/kg or more.