Water-and oil-repellency imparting ester oligomers comprising perfluoroalkyl moieties
    1.
    发明授权
    Water-and oil-repellency imparting ester oligomers comprising perfluoroalkyl moieties 有权
    防水防油赋予酯低聚物包含全氟烷基部分

    公开(公告)号:US06753380B2

    公开(公告)日:2004-06-22

    申请号:US09803708

    申请日:2001-03-09

    申请人: Zai-Ming Qiu

    发明人: Zai-Ming Qiu

    IPC分类号: C08L6702

    摘要: Fluorochemical ester compositions comprising one or more compounds or oligomers having at least on fluorine-containing repeatable unit and at least one fluorine-containing terminal group are described. The compositions are useful as coatings or incorporated as melt additives. The fluorochemical compositions impart oil and water repellency to the substrate. In other aspects, this invention relates to processes for imparting oil and water repellency characteristics to substrates and articles.

    摘要翻译: 含有一种或多种具有至少含氟可重复单元和至少一个含氟末端基团的化合物或低聚物的含氟化合物组合物被描述。 该组合物可用作涂料或作为熔融添加剂掺入。 含氟化合物赋予基底油和拒水性。 在其它方面,本发明涉及赋予基材和制品防油拒斥特性的方法。

    Polyester resin composition
    3.
    发明授权
    Polyester resin composition 有权
    聚酯树脂组合物

    公开(公告)号:US06579935B1

    公开(公告)日:2003-06-17

    申请号:US09890159

    申请日:2001-07-27

    IPC分类号: C08L6702

    摘要: According to the present invention, a polyester resin composition superior in the impact resistance, especially low-temperature impact resistance, and in the stiffness as well as in the fracture toughness can be obtained. The polyester resin composition according to the present invention is a composition which comprises, per 100 parts by weight of a polyester resin (A), 5-200 parts by weight of a graft-modified ethylene/&agr;-olefin random copolymer (B) obtained by grafting onto an ethylene/&agr;-olefin random copolymer (B-1) composed of ethylene unit and of an &agr;-olefin unit of 6-20 carbon atoms an unsaturated carboxylic acid or its derivative (B-2), wherein the grafting amount of the unsaturated carboxylic acid or its derivative (B-2) is 0.01-10% by weight and wherein the said ethylene/&agr;-olefin random copolymer (B-1) before being graft-modified has (a) a content of the &agr;-olefin unit of 6-20 carbon atoms of 6-25 mole % and (b) a melt flow rate (ASTM D 1238, 190° C., 2.16 kg load) of 0.1-50 g/10 min.

    摘要翻译: 根据本发明,可以获得耐冲击性,特别是低温耐冲击性以及刚度以及断裂韧性优异的聚酯树脂组合物。 根据本发明的聚酯树脂组合物是一种组合物,其包含相对于100重量份的聚酯树脂(A),5-200重量份获得的接枝改性的乙烯/α-烯烃无规共聚物(B) 通过接枝到由乙烯单元和6-20个碳原子的α-烯烃单元组成的乙烯/α-烯烃无规共聚物(B-1)不饱和羧酸或其衍生物(B-2)上,其中接枝量 的不饱和羧酸或其衍生物(B-2)为0.01-10重量%,并且其中所述乙烯/α-烯烃无规共聚物(B-1)在接枝改性之前具有(a)α的含量 6-20摩尔%的6-20个碳原子的α-烯烃单元和(b)0.1-50克/ 10分钟的熔体流动速率(ASTM D 1238,190℃,2.16千克负载)。

    Powder coating compositions and method
    4.
    发明授权
    Powder coating compositions and method 有权
    粉末涂料组合物和方法

    公开(公告)号:US06472472B2

    公开(公告)日:2002-10-29

    申请号:US09880421

    申请日:2001-06-13

    IPC分类号: C08L6702

    摘要: Powder coating compositions for metal substrates, a method of powder coating a metal substrate, and a metal article are disclosed. The powder coating composition is a thermoplastic material and comprises: (a) a first polyester having a weight average molecular weight of about 10,000 to about 80,000 and a Tg of greater than 45° C. to about 100° C., (b) a second polyester having a weight average molecular weight of about 10,000 to about 70,000 and a Tg of about −10° C. to about 45° C., and optionally, (c) a modifying resin, such as an epoxy resin having an epoxy equivalent weight of about 500 to about 15,000, wherein the Tg of the first and second polyesters differ by about 5° C. to about 60° C. The powder coating composition is applied to a metal substrate to provide a composition film having a thickness of about 1 to about 200 microns.

    摘要翻译: 公开了用于金属基材的粉末涂料组合物,金属基材的粉末涂覆方法和金属制品。 粉末涂料组合物是热塑性材料,包括:(a)重均分子量为约10,000至约80,000,Tg大于45℃至约100℃的第一聚酯,(b) 重均分子量为约10,000至约70,000,Tg为约-10℃至约45℃的第二聚酯,和(c)改性树脂,例如具有环氧当量的环氧树脂 重量约500至约15,000,其中第一和第二聚酯的Tg相差约5℃至约60℃。将粉末涂料组合物施加到金属基材上以提供厚度为约 1至约200微米。

    Biaxially oriented polyester film with improved dyeability
    5.
    发明授权
    Biaxially oriented polyester film with improved dyeability 有权
    双轴取向聚酯薄膜具有改善的染色性

    公开(公告)号:US06444299B1

    公开(公告)日:2002-09-03

    申请号:US09714825

    申请日:2000-11-17

    IPC分类号: C08L6702

    CPC分类号: C08L67/02 C08L2666/18

    摘要: A biaxially oriented polyester film with improved dyeability is prepared by meltblending 55 to 90 wt. % of polyethylene terephthalate and 10 to 45 wt. % of polytrimethylene terephthalate.

    摘要翻译: 通过将55-90重量%的熔融共混制备具有改进的可染性的双轴取向聚酯膜。 %的聚对苯二甲酸乙二醇酯和10至45wt。 %的聚对苯二甲酸丙二醇酯。

    Process for coating olefinic substrates
    6.
    发明授权
    Process for coating olefinic substrates 失效
    烯烃基材涂层工艺

    公开(公告)号:US06423778B1

    公开(公告)日:2002-07-23

    申请号:US09343952

    申请日:1999-06-30

    IPC分类号: C08L6702

    摘要: A free paint film is formed and applied to a substrate with heat, pressure, or both. The free paint film includes an outer layer formed from a composition that includes an olefinic material. The olefinic material is an olefin-based block copolymer with an olefin block that is at least substantially saturated and at least one (poly)ester or (poly)ether block, an at least substantially saturated polyolefin polyol having a number average molecular weight of from about 500 to about 20,000 or a derivative thereof, or a combination of both.

    摘要翻译: 形成自由的漆膜并将其施加到具有热,压力或两者的基底上。 游离漆膜包括由包含烯烃材料的组合物形成的外层。 烯烃材料是具有至少基本上饱和的烯烃嵌段和至少一种(多)酯或(多)醚嵌段,至少基本上饱和的数均分子量为 约500至约20,000或其衍生物,或两者的组合。

    Thermoplastic polyester resin composition
    7.
    发明授权
    Thermoplastic polyester resin composition 失效
    热塑性聚酯树脂组合物

    公开(公告)号:US06399695B1

    公开(公告)日:2002-06-04

    申请号:US09107419

    申请日:1998-06-30

    IPC分类号: C08L6702

    CPC分类号: C08L67/02 C08L23/00

    摘要: The purposes of the present invention are to provide highly impact-resistant thermoplastic polyester resin inexpensively and promote the recycling of PET bottles, which are dumped as waste. To attain the purposes, a carboxyl-modified metallocene catalyzed polyolefin elastomer or a glycidyl methacrylate adduct to the elastomer is melt-blended with a thermoplastic polyester resin, particularly, the powder of recycled PET bottles. Additionally, a filler can be mixed, if necessary.

    摘要翻译: 本发明的目的是廉价地提供高抗冲击性的热塑性聚酯树脂,并促进作为废弃物倾倒的PET瓶的再循环。 为了达到这个目的,羧基改性的茂金属催化聚烯烃弹性体或与弹性体的甲基丙烯酸缩水甘油酯加合物与热塑性聚酯树脂,特别是再生PET瓶的粉末熔融共混。 另外,如果需要,可以混合填料。

    Isocyanate-modified epoxy-functional polyester with crosslinking agent
    9.
    发明授权
    Isocyanate-modified epoxy-functional polyester with crosslinking agent 失效
    异氰酸酯改性环氧官能聚酯与交联剂

    公开(公告)号:US06262186B1

    公开(公告)日:2001-07-17

    申请号:US09429791

    申请日:1999-10-29

    IPC分类号: C08L6702

    摘要: An isocyanate-modified epoxy-functional polyester is prepared by the reaction of an epihalohydrin in the presence of a base with a carboxyl-functional polyester resin (II) obtained by reacting (a) at least one aromatic or (cyclo)aliphatic dicarboxylic acid A having aromatic or secondary carboxyl groups, or the anhydride thereof, (b) at least one diol B having primary or secondary hydroxyl groups, (c) compound C1 having one monofunctional primary or secondary hydroxyl group and/or at least one compound C2 having one primary or secondary hydroxyl group and one tertiary aliphatic carboxyl group, and, optionally, (d) a dihydroxymonocarboxylic acid having a tertiary aliphatic carboxyl group and two aliphatic hydroxyl groups, and/or (e) a trihydroxyalkane (E1) or tetrahydroxyalkane (E2), to produce an epoxy-functional polyester whose terminal hydroxyl groups are reacted with an isocyanate.

    摘要翻译: 异氰酸酯改性的环氧官能聚酯通过表面卤代醇在碱存在下与羧基官能聚酯树脂(II)的反应制备,所述羧基官能聚酯树脂(II)通过使(a)至少一种芳族或(环)脂族二羧酸A 具有芳族或次级羧基或其酸酐,(b)至少一种具有伯或仲羟基的二元醇B,(c)具有一个单官能伯或仲羟基的化合物C1和/或至少一个具有一个羟基的化合物C2 (d)具有叔脂族羧基和两个脂族羟基的二羟基单羧酸,和/或(e)三羟基烷烃(E1)或四羟基烷烃(E2)的二羟基单羧酸, ,以制备端基羟基与异氰酸酯反应的环氧官能聚酯。