Method for producing cellulose ether
    2.
    发明授权
    Method for producing cellulose ether 有权
    生产纤维素醚的方法

    公开(公告)号:US09481738B2

    公开(公告)日:2016-11-01

    申请号:US13398247

    申请日:2012-02-16

    申请人: Mitsuo Narita

    发明人: Mitsuo Narita

    CPC分类号: C08B1/08 C08B11/00 C08B11/193

    摘要: Provided is a method for producing cellulose ether whose aqueous solution is transparent and contains a smaller amount of water-insoluble portion. The method comprises at least the steps of: providing at least two alkali cellulose materials having different compositions, each of the materials having been prepared by bringing a pulp into contact with a solution of alkali metal hydroxide and draining; and mixing the at least two alkali cellulose materials having different compositions, wherein each weight ratio of the alkali metal hydroxide in each of the alkali cellulose materials having different compositions to a solid component in the pulp (alkali metal hydroxide/solid component in pulp) is equal to 0.4 to 2.5 times of a weight ratio of alkali metal hydroxide in the alkali cellulose obtained in the step of mixing to solid components in a sum of pulps used for preparation of the alkali cellulose materials.

    摘要翻译: 本发明提供水溶液透明且含有较少量的水不溶部分的纤维素醚的制造方法。 该方法至少包括以下步骤:提供具有不同组成的至少两种碱性纤维素材料,每种材料都是通过使纸浆与碱金属氢氧化物溶液接触并排出而制备的; 并混合至少两种具有不同组成的碱性纤维素材料,其中每种具有不同组成的碱性纤维素材料中的碱金属氢氧化物与纸浆中的固体组分(碱金属氢氧化物/纸浆中的固体组分)的重量比为 等于在用于制备碱纤维素材料的纸浆中与固体组分混合的步骤中获得的碱性纤维素中碱金属氢氧化物的重量比的0.4至2.5倍。

    Method for producing cationized cellulose and method for producing cationized hydroxyalkyl cellulose
    4.
    发明授权
    Method for producing cationized cellulose and method for producing cationized hydroxyalkyl cellulose 有权
    阳离子化纤维素的制造方法及阳离子化羟烷基纤维素的制造方法

    公开(公告)号:US09040681B2

    公开(公告)日:2015-05-26

    申请号:US13581760

    申请日:2011-02-28

    摘要: A production method of a cationized cellulose or a cationized hydroxyalkylcellulose, including step 1 for adding a cationizing agent to cellulose and mechanically decrystallizing the cellulose and step 2 for adding a basic compound to the mixture obtained in step 1 and mechanically decrystallizing the cellulose, or a production method of a cationized cellulose or a cationized hydroxyalkylcellulose, including a step 3 for adding a basic compound to cellulose and mechanically decrystallizing the cellulose and step 4 for adding a cationizing agent to the mixture obtained in step 3 and mechanically decrystallizing the cellulose. The cellulose and the cationizing agent are allowed to react with each other in step 2 or step 4.

    摘要翻译: 阳离子化纤维素或阳离子化羟烷基纤维素的制备方法,包括步骤1,用于向纤维素中加入阳离子化剂并机械地使纤维素脱结晶,步骤2用于向步骤1中获得的混合物中加入碱性化合物,并机械使纤维素脱结晶,或 阳离子化纤维素或阳离子化羟烷基纤维素的制造方法,包括将碱性化合物添加到纤维素中并使纤维素机械去结晶的步骤3和步骤4,将步骤3中获得的混合物中的阳离子化剂添加到机械中使纤维素脱结晶。 使纤维素和阳离子化剂在步骤2或步骤4中彼此反应。

    Nanomaterial of polyglycerol grafted cellulose nanocrystal dendrimer and preparation method thereof

    公开(公告)号:US11760843B2

    公开(公告)日:2023-09-19

    申请号:US18125690

    申请日:2023-03-23

    IPC分类号: C08B1/06 C08G83/00

    CPC分类号: C08G83/003 C08B1/06

    摘要: The invention provides a nanomaterial of polyglycerol grafted cellulose nanocrystal dendrimer and a preparation method thereof. In the present invention, the cotton linter pulp is pulverized into flocculent fibers, fed to sulfuric acid, and reacted. After centrifugation, dialysis and ultrasonic cell disruption, cellulose nanocrystals are obtained. Carboxylated cellulose nanocrystals are further obtained after oxidation with TEMPO, dialysis, and freeze-drying. The carboxylated nanocrystals are further added to DMF, and under a nitrogen atmosphere, glycidol is grafted to the hydroxyl groups on the surface by heating with stirring. After the reaction is completed, the product is centrifuged, dried under vacuum, dialyzed, and freeze dried to obtain a nanomaterial of primary polyglycerol grafted cellulose nanocrystals. Dendrimers with different particle size ranges can be prepared by controlling the number of reactions, which contain a large number of hydroxyl groups on the surface, and are amenable to various modifications.