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公开(公告)号：US5463145A
公开(公告)日：1995-10-31
申请号：US316673
申请日：1994-09-30
CPC分类号： C07C29/141 , C07C29/16 , C07C45/58 , C07C45/80
摘要： 1,3-Propanediol is prepared in a process comprising the steps of:contacting, in an essentially non-water-miscible organic solvent, ethylene oxide with carbon monoxide and hydrogen in the presence of a catalytic amount of a non-phosphine-ligated cobalt compound and an effective amount of a lipophilic quaternary phosphonium salt promoter at a temperature within the range of about 50.degree. to about 100.degree. C. and a pressure within the range of about 500 to about 5000 psig, to produce an intermediate product mixture comprising less than 15 wt % 3-hydroxypropanal;adding an aqueous liquid to said intermediate product mixture and extracting into said aqueous liquid a major portion of the 3-hydroxypropanal at a temperature less than about 100.degree. C. to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the concentration of 3-hydroxypropanal in the intermediate product mixture, and an organic phase comprising at least a portion of the cobalt compound and at least a portion of the lipophilic quaternary phosphonium salt;contacting the aqueous phase comprising 3-hydroxypropanal with hydrogen in the presence of a hydrogenation catalyst at a pressure of at least about 100 psig and a temperature during at least a portion of the hydrogenation step of at least 40.degree. C. to provide a hydrogenation product mixture comprising 1,3-propanediol.
摘要翻译： 以包括以下步骤的方法制备1,3-丙二醇：在催化量的非磷化氢连接的钴存在下，在基本上与水可混溶的有机溶剂中，使环氧乙烷与一氧化碳和氢气接触 化合物和有效量的亲脂性季鏻盐助催化剂，其温度范围为约50至约100℃，压力范围为约500至约5000psig，以产生包含较少量的中间产物混合物 超过15重量％的3-羟基丙醛; 向所述中间产物混合物中加入水性液体并在低于约100℃的温度下将3-羟基丙醛的主要部分提取到所述水性液体中，以提供比3-浓度更高的浓度的3-羟基丙醛的水相 - 羟基丙醛，以及包含至少一部分钴化合物和至少一部分亲脂性季鏻盐的有机相; 在氢化催化剂的存在下，在至少约100psig的压力和在至少40℃的至少一部分氢化步骤期间的温度下使包含3-羟基丙醛的水相与氢气接触以提供氢化产物 混合物包含1,3-丙二醇。
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公开(公告)号：US5545767A
公开(公告)日：1996-08-13
申请号：US316679
申请日：1994-09-30
CPC分类号： C07C29/16 , C07C29/141 , C07C45/58
摘要： 1,3-propanediol is prepared in a process comprising the steps of:contacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of an effective amount of a non-phosphine-ligated cobalt catalyst and an effective amount of a lipophilic phenol at a temperature within the range of about 50.degree. to about 100.degree. C. and a pressure within the range of about 500 to about 5000 psig, under reaction conditions effective to produce an intermediate product mixture comprising less than about 15 wt % 3-hydroxypropanal;adding an aqueous liquid to said intermediate product mixture and extracting into said aqueous liquid at a temperature less than about 100.degree. C. a major portion of the 3-hydroxypropanal so as to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the concentration of 3-hydroxypropanal in said intermediate product mixture and an organic phase comprising at least a portion of the cobalt catalyst or a cobalt-containing derivative thereof and at least a portion of the lipophilic phenol;contacting the aqueous phase comprising 3-hydroxypropanal with hydrogen in the presence of a hydrogenation catalyst at a pressure of at least about 100 psig and a temperature during at least a portion of the hydrogenation step of at least 40.degree. C. to provide a hydrogenation product mixture comprising 1,3-propanediol.
摘要翻译： 以包括以下步骤的方法制备1,3-丙二醇：在有效量的非磷化氢连接的钴催化剂存在下，将环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中接触， 在约50℃至约100℃的温度范围内的有效量的亲油性苯酚和在约500至约5000psig范围内的压力，在有效产生包含小于约 15重量％3-羟基丙醛; 向所述中间产物混合物中加入水性液体并在小于约100℃的温度下将3-羟基丙醛的主要部分萃取到所述水性液体中，以提供包含比浓度更高的浓度的3-羟基丙醛的水相 所述中间产物混合物中的3-羟基丙醛和包含至少一部分钴催化剂或其含钴衍生物和至少一部分亲脂性酚的有机相; 在氢化催化剂的存在下，在至少约100psig的压力和在至少40℃的至少一部分氢化步骤期间的温度下使包含3-羟基丙醛的水相与氢气接触以提供氢化产物 混合物包含1,3-丙二醇。
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公开(公告)号：US5463144A
公开(公告)日：1995-10-31
申请号：US316671
申请日：1994-09-30
申请人： Joseph B. Powell , Lynn H. Slaugh , Thomas C. Forschner , Terry B. Thomason , Thomas C. Semple , Paul R. Weider , Juan P. Arhancet
发明人： Joseph B. Powell , Lynn H. Slaugh , Thomas C. Forschner , Terry B. Thomason , Thomas C. Semple , Paul R. Weider , Juan P. Arhancet
CPC分类号： C07C45/58 , C07C29/141 , C07C29/16 , C07C45/80
摘要： 1,3-propanediol is prepared in a process comprising the steps of:contacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of an effective amount of a non-phosphine-ligated cobalt catalyst and an effective amount of a lipophilic quaternary ammonium salt at a temperature within the range of about 50.degree. to about 100.degree. C. and a, pressure within the range of about 500 to about 5000 psig, under reaction conditions effective to produce an intermediate product mixture comprising less than 15 wt % 3-hydroxypropanal;adding an aqueous liquid to said intermediate product mixture and extracting into said aqueous liquid at a temperature less than about 100.degree. C. a major portion of the 3-hydroxypropanal so as to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the-concentration of 3-hydroxypropanal in said intermediate product mixture and an organic phase comprising at least a portion of the cobalt catalyst or a cobalt-containing derivative thereof and at least a portion of the lipophilic quaternary ammonium salt;contacting the aqueous phase comprising 3-hydroxypropanal with hydrogen in, the presence of a hydrogenation catalyst at a pressure of at least about 100 psig and a temperature during at least a portion of the hydrogenation step of at least 40.degree. C. to provide a hydrogenation product mixture comprising 1,3-propanediol.
摘要翻译： 以包括以下步骤的方法制备1,3-丙二醇：在有效量的非磷化氢连接的钴催化剂存在下，将环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中接触， 在有效量的亲油性季铵盐的温度范围为约50至约100℃，和a，压力范围为约500至约5000psig，在有效产生中间产物混合物的反应条件下，包括 小于15重量％的3-羟基丙醛; 向所述中间产物混合物中加入水性液体，并在低于约100℃的温度下将3-羟基丙醛的主要部分萃取到所述含水液体中，以提供包含比所述中间产物混合物更高浓度的3-羟基丙醛的水相， 所述中间产物混合物中的3-羟基丙醛的浓度和包含至少一部分钴催化剂或其含钴衍生物和至少一部分亲脂性季铵盐的有机相; 在氢化催化剂存在下，在至少约100psig的压力和在至少40℃的至少一部分氢化步骤期间的温度下使包含3-羟基丙醛的水相与氢接触以提供氢化 产物混合物包含1,3-丙二醇。
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公开(公告)号：US4692536A
公开(公告)日：1987-09-08
申请号：US917948
申请日：1986-10-14
申请人： Robert W. Lang
发明人： Robert W. Lang
CPC分类号： C07C47/14 , C07C45/511 , C07C45/516 , C07C47/17 , C07C47/24 , C07F7/188
摘要： The reaction of dimethylformamide, R.sup.1 R.sup.2 R.sup.3 SiX and RY in the presence of zinc or the reaction of dimethylformamide, R.sup.1 R.sup.2 R.sup.3 SiX and a zinc compound RZnY.yL affords hemiaminals of formula I ##STR1## R is e.g. polyhalogenated alkyl containing at least one fluorine atom; R.sup.1, R.sup.2 and R.sup.3 are e.g. alkyl; L is a ligand; X is chlorine or bromine; Y is chlorine, bromine or iodine and y is 1 or 2.
摘要翻译： 二甲基甲酰胺，R1R2R3SiX和RY在锌存在下的反应或二甲基甲酰胺，R1R2R3SiX和锌化合物RZnY.yL的反应，得到式I的半氨基化合物。 含有至少一个氟原子的多卤代烷基; R1，R2和R3是例如。 烷基; L是配体; X是氯或溴; Y是氯，溴或碘，y是1或2。
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6.发明申请公开(公告)号：US20120164355A1
公开(公告)日：2012-06-28
申请号：US13157657
申请日：2011-06-10
申请人： Pei-Chen Huang , Kuo-Chang Wang , Kuo-Liang Yeh , An-Cheng Chen , Kung-Lung Cheng , Shyue-Ming Jang
发明人： Pei-Chen Huang , Kuo-Chang Wang , Kuo-Liang Yeh , An-Cheng Chen , Kung-Lung Cheng , Shyue-Ming Jang
CPC分类号： C09K19/46 , C09K19/3066 , C09K19/44 , C09K2019/0466 , C09K2019/123 , C09K2019/3004 , C09K2019/3009 , C09K2019/301 , C09K2019/3016 , C09K2019/3037 , C09K2019/3083 , Y10T428/10
摘要： A liquid crystal compound of Formula (1) is provided. In Formula (1), R is hydrogen, linear or branching C1-15 alkyl, linear or branching C1-15 alkyl (wherein any one of —CH2— is replaced by —O—, —S—, —CO—, —CO—O—, or —O—CO—), linear or branching C2-15 alkenyl, or linear or branching C2-15 alkenyl (wherein any one of —CH2— is replaced by —O—, —S—, —CO—, —CO—O—, or —O—CO—), A and B are, independently, cyclohexane, cyclohexane (wherein any one of —CH2— is replaced by —O— or —NH—), benzene, or benzene (wherein any one of —CH2═ is replaced by —N═), X is a single bond, —CO—O—, —O—CO—, —CH2O—, —OCH2—, —CH2CH2—, —C═C—, —C≡C—, —CF2O—, or —OCF2—, Q is oxygen or CH2, Y is CF3, CF2H, or CFH2, L1, L2, and L3 are, independently, hydrogen or fluorine, and m is 0, 1, or 2.
摘要翻译： 提供式（1）的液晶化合物。 在式（1）中，R是氢，直链或支链C 1-15烷基，直链或支链C 1-15烷基（其中-CH 2 - 中的任一个被-O - ， - S - ， - CO - ， - CO -O-或-O-CO-），直链或支链C2-15烯基，或直链或支链C2-15烯基（其中-CH2-中的任一个被-O - ， - S - ， - CO- ，-CO-O-或-O-CO-），A和B独立地是环己烷，环己烷（其中-CH 2 - 被-O - 或-NH-取代的任何一个），苯或苯（ 其中-CH 2 - 中的任一个被-N =取代），X是单键，-CO-O-，-O-CO-，-CH 2 O-，-OCH 2 - ， - CH 2 CH 2 - ， - C≡C- ，-C≡C-，-CF2O-或-OCF2-，Q是氧或CH2，Y是CF3，CF2H或CFH2，L1，L2和L3独立地是氢或氟，m是0， 1或2。
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公开(公告)号：US5463146A
公开(公告)日：1995-10-31
申请号：US316677
申请日：1994-09-30
CPC分类号： C07C45/58 , C07C29/141 , C07C29/16 , C07C45/80
摘要： 1,3-propanediol is prepared in a process comprising the steps of:(a) contacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of an effective amount of a non-phosphine-ligated cobalt catalyst and an effective amount of a lipophilic arsine at a temperature within the range of about 50 to about 100.degree. C. and a pressure within the range of about 500 to about 5000 psig, under reaction conditions effective to produce an intermediate product mixture comprising less than about 15 wt % 3-hydroxypropanal;(b) adding an aqueous liquid to said intermediate product mixture and extracting into said aqueous liquid at a temperature less than about 100.degree. C. a major portion of the 3-hydroxypropanal so as to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the concentration of 3-hydroxypropanal in said intermediate product mixture and an organic phase comprising at least a portion of the cobalt catalyst or a cobalt-containing derivative thereof and at least a portion of the lipophilic arsine;(c) separating the aqueous phase from the organic phase;(d) contacting the aqueous phase comprising 3-hydroxypropanal with hydrogen in the presence of a hydrogenation catalyst at a pressure of at least about 100 psig and a temperature during at least a portion of the hydrogenation step of at least 40.degree. C. to provide a hydrogenation product mixture comprising 1,3-propanediol;(e) recovering 1,3-propanediol from said hydrogenation product mixture; and(f) returning at least a portion of the organic phase comprising cobalt compound and lipophilic arsine to the process of step (a).The process enables the production of 1,3-propanediol in high yields and selectivity without the use of a phosphine-ligated cobalt catalyst.
摘要翻译： 以包括以下步骤的方法制备1,3-丙二醇：（a）在有效量的非磷化氢连接的钴的存在下，将环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中接触 催化剂和有效量的亲油胂在约50至约100℃的温度和约500至约5000psig范围内的压力下，在有效产生包含较少的中间产物混合物的反应条件下 比约15重量％的3-羟基丙醛; （b）向所述中间产物混合物中加入含水液体并在低于约100℃的温度下将3-羟基丙醛的主要部分萃取到所述水性液体中，以提供含有更高浓度的3-羟基丙醛的水相 所述中间产物混合物中的3-羟基丙醛的浓度和包含至少一部分钴催化剂或其含钴衍生物和至少一部分亲脂性胂的有机相; （c）将水相与有机相分离; （d）在氢化催化剂的存在下，在至少约100psig的压力和至少一部分氢化步骤的至少40℃的温度下使包含3-羟基丙醛的水相与氢气接触，以提供 包含1,3-丙二醇的氢化产物混合物; （e）从所述氢化产物混合物回收1,3-丙二醇; 和（f）将包含钴化合物和亲脂性胂的至少一部分有机相返回到步骤（a）的方法。 该方法能够以高产率和选择性生产1,3-丙二醇，而不需要使用磷化氢连接的钴催化剂。
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8.发明授权Method for producing a 5-bromo-1-pentanal compound or an acetal derivative thereof 失效5-溴-1-戊醛化合物或其缩醛衍生物的制备方法
公开(公告)号：US4760195A
公开(公告)日：1988-07-26
申请号：US78825
申请日：1987-07-28
申请人： Masaaki Kubo , Kazuhiro Okura
发明人： Masaaki Kubo , Kazuhiro Okura
IPC分类号： B01J19/12 , C07C41/48 , C07C43/313 , C07C45/00 , C07C45/63 , C07C47/14 , C07C47/17 , C07C67/00 , C07D317/08 , C07D317/16 , C07D319/06
CPC分类号： B01J19/123 , C07C41/48 , C07C45/63 , C07C47/14
摘要： A 5-bromo-1-pentanal compound of the formula (I): ##STR1## wherein R.sup.1 and R.sup.2 respectively represent, independently from each other, a member selected from the group consisting of a hydrogen atom and alkyl radicals having 1 to 7 carbon atoms, or an acetal derivative of said 5-bromo-1-pentanal compound, is produced by subjecting a starting compound selected from the group consisting of 4-pentenal compounds of the formula (II): ##STR2## wherein R.sup.1 and R.sup.2 are as defined above, and acetal derivatives of the above-mentioned compounds, to a free radical addition reaction with hydrogen bromide in a liquid medium at a temperature of 10.degree. C. to 60.degree. C.; in the presence of a free radical initiator or by irradiating ultraviolet rays to the reaction mixture, and by collecting the resultant reaction product from the reaction mixture.
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