公开(公告)号：US09815775B1

公开(公告)日：2017-11-14

申请号：US15141930

申请日：2016-04-29

申请人： The Government of the United States of America as Represented by the Secretary of the Navy

发明人： Michael E. Wright ,  Benjamin G. Harvey

IPC分类号： C07C253/04 ,  C07C37/16 ,  C07C37/00 ,  D06M13/345 ,  C12P13/00 ,  C08G65/38 ,  D06M101/40

CPC分类号： C07C253/04 ,  C07C37/002 ,  C07C37/003 ,  C07C37/16 ,  C07C41/18 ,  C07C41/20 ,  C07C41/30 ,  C07C261/02 ,  C08G65/38 ,  C12P13/002 ,  D06M13/345 ,  D06M2101/40 ,  C07C43/23

摘要： A vanillin is found to be a useful starting material for preparing new monomers that can be further applied to make high Tg composite resins that are in turn useful for making composite parts.

公开(公告)号：US08222445B2

公开(公告)日：2012-07-17

申请号：US12529697

申请日：2008-08-15

申请人： Harald Strittmatter ,  Stefan Koger

发明人： Harald Strittmatter ,  Stefan Koger

IPC分类号： C07C255/05 ,  C07C255/06 ,  C07C253/04

CPC分类号： C07C253/04 ,  C07C253/34 ,  C07C255/05

摘要： The present invention relates to an industrially usable process for preparing alkali metal and alkaline earth metal tricyanomethanides in particularly high purity.

摘要翻译： 本发明涉及工业上可用于制备特别高纯度的碱金属和碱土金属三氰基甲烷化物的方法。

公开(公告)号：US3867422A

公开(公告)日：1975-02-18

申请号：US42273873

申请日：1973-12-07

申请人： DEGUSSA

发明人： HEIMBERGER WERNER ,  SCHMITT HERMANN ,  SCHREYER GERD ,  THEISSEN FERDINAND ,  WEIGERT WOLFGANG

IPC分类号： C07C255/04 ,  C07C20060101 ,  C07C67/00 ,  C07C253/00 ,  C07C253/04 ,  C07C253/32 ,  C07C121/20 ,  C07C121/22

CPC分类号： C07C255/00

摘要： Malonodinitrile produced from cyanogen halide and acetonitrile and containing fumarodinitrile as an impurity is purified and stabilized by recrystallizing from an aliphatic alcohol or dialkyl ether in the presence of benzonitrile.

摘要翻译： 由氰卤化物和乙腈生成的含有作为杂质的烟草腈的丙二腈是通过在苄腈存在下从脂族醇或二烷基醚中重结晶来纯化和稳定的。

公开(公告)号：US20180215626A1

公开(公告)日：2018-08-02

申请号：US15938606

申请日：2018-03-28

申请人： Arkema France

发明人： Yves Bernardin ,  Xavier Marcarian ,  Romain Billon

IPC分类号： C01C3/02 ,  C07C253/04 ,  C07C231/12 ,  C07C231/06 ,  C07C67/20 ,  C07C51/06

CPC分类号： C01C3/0212 ,  C01C3/022 ,  C07C51/06 ,  C07C67/20 ,  C07C231/06 ,  C07C231/12 ,  C07C253/04 ,  Y02P20/129

摘要： Present invention relates to a process and an installation (100) for the preparation of hydrogen cyanide by the Andrussow process, and more precisely for improving the conditions of mixing the reactant gases before feeding the Andrussow type reactor (60), in order to improve safety, to avoid any risk of explosion and to produce HCN in safe and efficient manner. The installation is configured in such a manner that oxygen is pre-mixed with air with a ratio comprised between 20.95% and 32.5% by volume, preferably between 25% and 30.5% by volume; methane containing gas and ammonia are simultaneously added in the pre-mixture of oxygen-enriched air in such a manner that the volumic ratio of methane to ammonia is comprised between 1.35 and 1.02 depending on the content of oxygen into air; said obtained reactant gases mixture having a temperature comprised between 80° C. and 120° C., preferably between 95° C. and 115° C. for feeding the Andrussow type reactor (60).

公开(公告)号：US20130184485A1

公开(公告)日：2013-07-18

申请号：US13577278

申请日：2011-02-01

申请人： Matthias Gotta ,  Bernd Wilhelm Lehnemann ,  Waldemar Maximilian Czaplik ,  Matthias Mayer ,  Axel Jacobi Von Wangelin

发明人： Matthias Gotta ,  Bernd Wilhelm Lehnemann ,  Waldemar Maximilian Czaplik ,  Matthias Mayer ,  Axel Jacobi Von Wangelin

IPC分类号： C07C253/04 ,  C07C1/30 ,  C07C17/26 ,  C07C209/74 ,  C07C41/24

CPC分类号： C07C253/04 ,  C07B37/04 ,  C07B49/00 ,  C07C1/30 ,  C07C1/326 ,  C07C17/26 ,  C07C17/2632 ,  C07C41/24 ,  C07C41/30 ,  C07C67/343 ,  C07C209/68 ,  C07C209/74 ,  C07C253/30 ,  C07C2527/128 ,  C07C2531/22 ,  C07C2603/26 ,  C07C11/02 ,  C07C15/44 ,  C07C43/2055 ,  C07C43/205 ,  C07C69/612 ,  C07C25/24 ,  C07C211/48 ,  C07C255/50

摘要： What is described is a process for preparing organic compounds of the general formula (I) R—R′  (I) by converting a corresponding compound of the general formula (II) R—X   (II) in which X is fluorine, chlorine, bromine or iodine to an organomagnesium compound of the general formula (III) [M+]n[RmMgXkY1]  (III) wherein compounds of the formula (III) are reacted with a compound of the general formula (IV) characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic amounts of an iron compound, based on the compound of the general formula (II), and optionally in the presence of b) a nitrogen-, oxygen- and/or phosphorus-containing additive in a catalytic or stoichiometric amount, based on the compound of the general formula (II).

摘要翻译： 描述的是通过将相应的通式（II）RX（II）的化合物（其中X是氟，氯，溴或溴）或其盐，其中R 1，R 2， 碘与通式（III）的化合物（III）反应的通式（III）的有机镁化合物[M +] n [RmMgXkY1]（III）其中式（III）化合物与通式（IV）的化合物反应，其特征在于（III ）与（IV）化合物在（a）催化量的铁化合物（基于通式（II）的化合物）存在下进行，任选在b）氮，氧和/或磷 基于通式（II）的化合物，催化剂或化学计量的添加剂。

公开(公告)号：US4434316A

公开(公告)日：1984-02-28

申请号：US478997

申请日：1983-03-25

申请人： Willie J. Barnette

发明人： Willie J. Barnette

IPC分类号： C07C7/148 ,  B01J31/00 ,  B01J31/22 ,  C07B61/00 ,  C07C1/00 ,  C07C7/17 ,  C07C11/00 ,  C07C11/02 ,  C07C11/08 ,  C07C67/00 ,  C07C253/00 ,  C07C253/04 ,  C07C255/04 ,  C07C255/07 ,  C07C7/00

CPC分类号： C07C7/17 ,  C07C253/34

摘要： Process for separating alkenes, e.g., butene, from alkadienes, e.g., butadiene by preferentially hydrocyanating the diene and thereafter recovering the unreacted alkenes.

摘要翻译： 通过优选氢化氰化二烯并随后回收未反应的烯烃，从烯烃例如丁二烯中分离烯烃例如丁烯的方法。

公开(公告)号：US10287237B1

公开(公告)日：2019-05-14

申请号：US15782223

申请日：2017-10-12

申请人： The United States of America, as represented by the Secretary of the Navy

发明人： Michael E. Wright ,  Benjamin G. Harvey

IPC分类号： C07C253/04 ,  C07C37/00 ,  C07C37/16 ,  C12P13/00 ,  C08G65/38 ,  D06M13/345 ,  D06M101/40

摘要： A method for converting vanillin to bis(cyanate) ester monomers, comprising treating vanillin with a reductive coupling agent to form at least one olefin. The olefin or olefins are treated with hydrogen and a metal catalyst to hydrogenate said olefin. The hydrogenated olefin or olefins are treated with at least one cyanogen halide and a base in an organic solvent to afford at least one olefin monomer. The olefin monomer or monomers are purified by recrystallization or precipitation from an organic solvent.

公开(公告)号：US20160194212A1

公开(公告)日：2016-07-07

申请号：US14905435

申请日：2014-07-18

申请人： ARKEMA FRANCE

发明人： Yves BERNARDIN ,  Xavier MARCARIAN ,  Romain BILLON

IPC分类号： C01C3/02 ,  C07C253/04 ,  C07C231/12 ,  C07C231/06 ,  C07C51/06 ,  C07C67/20

CPC分类号： C01C3/0212 ,  C01C3/022 ,  C07C51/06 ,  C07C67/20 ,  C07C231/06 ,  C07C231/12 ,  C07C253/04 ,  Y02P20/129

摘要： Present invention relates to a process and an installation (100) for the preparation of hydrogen cyanide by the Andrussow process, and more precisely for improving the conditions of mixing the reactant gases before feeding the Andrussow type reactor (60), in order to improve safety, to avoid any risk of explosion and to produce HCN in safe and efficient manner. The installation is configured in such a manner that oxygen is pre-mixed with air with a ratio comprised between 20.95% and 32.5% by volume, preferably between 25% and 30.5% by volume; methane containing gas and ammonia are simultaneously added in the pre-mixture of oxygen-enriched air in such a manner that the volumic ratio of methane to ammonia is comprised between 1.35 and 1.02 depending on the content of oxygen into air; said obtained reactant gases mixture having a temperature comprised between 80° C. and 120° C., preferably between 95° C. and 115° C. for feeding the Andrussow type reactor (60).

摘要翻译： 本发明涉及一种用于通过Andrussow方法制备氰化氢的方法和装置（100），更准确地说，涉及在提供安德鲁梭型反应器（60）之前改进混合反应气体的条件，以提高安全性 ，以避免任何爆炸的危险，并以安全有效的方式生产HCN。 该装置以这样一种方式配置，使氧与空气预混合，其比例为20.95至32.5％（体积），优选为25％至30.5％（体积）; 含甲烷的气体和氨同时加入到富氧空气的预混合物中，使得甲烷与氨的体积比在1.35和1.02之间，这取决于氧气进入空气的含量; 所述获得的反应气体混合物的温度为80℃至120℃，优选为95℃至115℃，用于供给安德鲁苏型反应器（60）。

公开(公告)号：US20140275538A1

公开(公告)日：2014-09-18

申请号：US13880843

申请日：2012-04-09

申请人： Mukund Keshav Gurjar ,  Golakchandra Sudarshan Maikap ,  Shashikant Gangaram Joshi ,  Sachin Aravind Badhe ,  Samit Satish Mehta

发明人： Mukund Keshav Gurjar ,  Golakchandra Sudarshan Maikap ,  Shashikant Gangaram Joshi ,  Sachin Aravind Badhe ,  Samit Satish Mehta

IPC分类号： C07D239/48 ,  C07C253/04

CPC分类号： C07D239/48 ,  C07C253/04 ,  C07C253/30 ,  C07C269/06 ,  C07C271/28 ,  C07C255/42

摘要： Disclosed is process for the preparation of a key Rilpivirine intermediate namely, (E)-4-(2-cyanoethenyl)-2,6-dimethylphenylamine hydrochloride (II) by a process comprising reaction of the tetrafluoroborate salt of the diazonium ion of 2,6-dimethyl-4-amino-1-carboxybenzyl phenylamine (VI) with acrylonitrile in presence of palladium acetate, followed by treatment with an acid and its subsequent conversion to the hydrochloride salt (II), wherein the undesired Z isomer is less than 0.5% and provides Rilpivirine hydrochloride having Z isomer less than 0.1%.

摘要翻译： 公开的是通过包括使重氮鎓四氟硼酸盐的反应的方法，即（E）-4-（2-氰基乙烯基）-2,6-二甲基苯基胺盐酸盐（II）来制备关键的利利培里中间体，即 （VI）与丙烯腈在乙酸钯存在下反应，然后用酸处理，随后转化成盐酸盐（II），其中不希望的Z异构体小于0.5 并且提供具有Z异构体小于0.1％的盐酸利昔维林。

公开(公告)号：US20110060155A1

公开(公告)日：2011-03-10

申请号：US12529697

申请日：2008-08-15

申请人： Harald Strittmatter ,  Stefan Koger

发明人： Harald Strittmatter ,  Stefan Koger

IPC分类号： C07C253/04

CPC分类号： C07C253/04 ,  C07C253/34 ,  C07C255/05

摘要： The present invention relates to an industrially usable process for preparing alkali metal and alkaline earth metal tricyanomethanides in particularly high purity.

摘要翻译： 本发明涉及工业上可用于制备特别高纯度的碱金属和碱土金属三氰基甲烷化物的方法。