公开(公告)号：US3619135A

公开(公告)日：1971-11-09

申请号：US3619135D

申请日：1969-01-29

Applicant: CELANESE CORP

Inventor： MACLEAN ALEXANDER F

IPC: C01C3/00 ,  C07C9/06 ,  C07C121/18

CPC classification number: C01C3/003 ,  Y10S585/942

Abstract: Certain organic reactants which are free from aliphatic unsaturation and which are capable of yielding free radicals upon treatment with peroxides are oxidized, in the liquid phase in an aqueous medium, with certain peroxy compounds to form freeradical intermediates which are then allowed to react further with themselves or with other components of the reaction medium to form useful end products. Preferred features include the slow addition of the peroxy compound to the reaction zone and the use of certain metalic ions to improve yields. The process may be used for the reaction of HCN and carboxylic acids to produce nitriles; the conversion of tertiary alkanols to ketones; and the production of cyanogen from hydrogen cyanide.

公开(公告)号：US3825580A

公开(公告)日：1974-07-23

申请号：US31450772

申请日：1972-12-13

Applicant: TOA GOSEI CHEM IND

Inventor： KATO H ,  TSUZI I ,  AZUMA K ,  TATEMICHI H

IPC: C08F22/30 ,  C07C121/18

CPC classification number: C07C255/00 ,  C08F22/30

Abstract: WHEREIN R IS AN ALKENYL, ALKINYL, ALKENYLOXYALKYL OR CYCLOALKENYL GROUP, AND AT LEAST 0.1% BY WEIGHT BASED ON THE WEIGHT OF THE COMPOSITION IS NOT ONLY INSTANTI ANEOUSLY ADHESIVE ADHESIVE COMPOSITION IS NOT ONLY INSTANTANEOUSLY ADHESIVE AT ROOM TEMPERATURE BUT ALSO HAS A SUFFICIENTLY PRACTICAL BONDING STRENGTH EVEN AT SUCH A HIGH TEMPERATURE AS 150* C. OR B ABOVE.

CH2=C(CN)COOR

A HEAT-RESISTANT ADHESIVE COMPOSITION COMPRISING A RADICAL POLYMERIZABLE A-CYANOACRYLATE REPRESENTED BY THE FORMULA,

公开(公告)号：US3565940A

公开(公告)日：1971-02-23

申请号：US3565940D

申请日：1969-02-20

Applicant: GRACE W R & CO

Inventor： BROWN PATRICK MICHAEL ,  MASELLI JAMES MICHAEL

IPC: C07C121/18

CPC classification number: C07C253/18 ,  Y02P20/582 ,  C07C255/03

Abstract: A METHOD OF PREPARING ACETONITRILE BY THE CATALYTIC AMMONIATION OF ETHYLENE AND/OR PROPYLENE BY PASSING A MIXTURE OF ETHYLENE AND/OR PROPYLENE AND AMMONIA THROUGH A BED OF A CATALYST AT A TEMPERATURE OF ABOUT 300-600*C. WHEREIN THE CATALYST IS A NITRIDE OF TUNGSTEN OR IRON.

公开(公告)号：US4179462A

公开(公告)日：1979-12-18

申请号：US869400

申请日：1978-01-16

Applicant: Gisela Olive ,  Salvador Olive

Inventor： Gisela Olive ,  Salvador Olive

IPC: C07C120/00 ,  C07C121/18 ,  C07C121/32

CPC classification number: C07C255/00

Abstract: A process for preparing acetonitrile by high temperature reaction of carbon monoxide, hydrogen and ammonia over a transition metal in reduced valence state as catalyst.

Abstract translation: 一种通过一氧化碳，氢和氨在过渡金属中以还原态催化作用的高温反应制备乙腈的方法。

公开(公告)号：US3870746A

公开(公告)日：1975-03-11

申请号：US21784372

申请日：1972-01-14

Applicant: DEGUSSA

Inventor： LUSSLING THEODOR ,  SCHREYER GERD ,  THEISSEN FERDINAND ,  WEIGERT WOLFGANG

IPC: C07C20060101 ,  C07C121/18 ,  C07C121/32

CPC classification number: C07C255/00 ,  Y10S203/03

Abstract: Pure acetonitrile is recovered from aqueous acetonitrile by extracting with an organic solvent which has little miscibility with water, boils higher than acetonitrile and does not form an azeotrope with acetonitrile. The portion of the extract boiling up to 76*C is distilled off. The remaining acetonitrile containing more difficulty volatile portion is freed from the residual water by addition of an entraining agent and recovering the pure acetonitrile by a fractional distillation.

Abstract translation: 通过用与水混溶性小的有机溶剂提取，从乙腈水溶液中回收纯乙腈，沸点高于乙腈，不与乙腈形成共沸物。 将沸腾至76℃的提取物部分蒸馏掉。 通过加入夹带剂将含有更难挥发性部分的剩余乙腈从残余水中除去，并通过分馏回收纯乙腈。

公开(公告)号：US3586704A

公开(公告)日：1971-06-22

申请号：US3586704D

申请日：1968-12-09

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ELLIS ALAN F

IPC: C07C51/097 ,  C09F1/00 ,  C07C53/00 ,  C07C97/16 ,  C07C121/16 ,  C07C121/18 ,  C11C1/00

CPC classification number: C07C255/00 ,  C07C51/097 ,  C07C53/126

Abstract: A PROCESS IS PROPOSED FOR THE PREPARATION OF A REACTION PRODUCT CONTAINING AT LEAST ONE COMPOUND SELECTED FROM AN ALKYL NITRILE, A FATTY ACID AND A FATTY ACID AMIDE. THE PROCESS COMPRISES REACTING A 1-NITRO-2-NITROSOALKANE, SUCH AS 1-NITRO-2-NITROSOHEXANE, OR A 1-NITROALKANONE-2 OXIME, SUCH AS 1-NITROHEXANONE-2 OXIME, WITH AQUEOUS SULFURIC ACID IN WHICH THE CONCENTRATION OF THE H2SO4 IS SUFFICIENT TO FORM A ONE PHASE REACTION MEDIUM WITH THE 1-NITRO CONTAINING CHARGE STOCK AND, OPTIONALLY, IN THE PRESENCE OF A LOWER ALKYL FATTY ACID, SUCH AS ACETIC ACID, AS A DILUENT. PHOSPHORIC ACID IN THE SAME CONCENTRATION RANGE CAN BE SUBSTITUTED FOR THE SULFURIC ACID TO PRODUCE A REACTION PRODUCT CONTAINING AT LEAST ONE COMPOUND SELECTED FROM A FATTY ACID AND A FATTY ACID AMIDE.

公开(公告)号：US4231955A

公开(公告)日：1980-11-04

申请号：US057547

申请日：1979-07-13

Applicant: Clarence D. Chang ,  William H. Lang ,  Rene B. LaPierre

Inventor： Clarence D. Chang ,  William H. Lang ,  Rene B. LaPierre

IPC: C07C255/24 ,  C07C120/00 ,  C07C121/16 ,  C07C121/18 ,  C07C121/43

CPC classification number: C07C255/00

Abstract: A method is provided for synthesizing alkylnitriles and alkylaminonitriles by reacting formaldehyde, a C.sub.1 -C.sub.5 monohydric alcohol and a compound having the formula R.sub.1 R.sub.2 NH where R.sub.1 and R.sub.2 are selected from the group consisting of hydrogen and alkyl groups containing 1 to 5 carbon atoms under effective conditions in the presence of a catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12 and a constraint index within the approximate range of 1 to 12 and recovering from the resulting reaction mixture, a product containing at least one of the above nitrile compounds.

Abstract translation: 提供了一种用于通过甲醛，一种C 1 -C 5一元醇和具有式R 1 R 2 NH的化合物，其中R 1和R 2选自氢和在有效条件下含有1至5个碳原子的烷基的方法来合成烷基腈和烷基氨基腈的方法 在包含二氧化硅与氧化铝比至少为约12的结晶硅铝酸盐沸石和大约1至12范围内的约束指数的催化剂存在下，从所得反应混合物中回收含有至少一种 以上腈化合物。

公开(公告)号：US4119497A

公开(公告)日：1978-10-10

申请号：US731633

申请日：1976-10-12

Applicant: Felipe Ocampo ,  Francisco Meza ,  Francisco Aguirre

Inventor： Felipe Ocampo ,  Francisco Meza ,  Francisco Aguirre

IPC: B01D3/36 ,  C07C20060101 ,  C07C21/18 ,  C07C121/18

CPC classification number: C07C255/00

Abstract: The present invention refers to a process for the purification of acetonitrile from crude acetonitrile or mixtures containing the same, which comprises the following operations:(a) transformation of hydrogen cyanide and acrylonitrile into compounds of higher molecular weight,(b) removal of most of the water in an azeotropic distillation column, and(c) separation of acetonitrile from the compounds of higher molecular weight and residual water in rectifying columns.

Abstract translation: 本发明涉及从粗乙腈或其混合物中纯化乙腈的方法，其包括以下操作：

公开(公告)号：US3600424A

公开(公告)日：1971-08-17

申请号：US3600424D

申请日：1967-08-15

Applicant: UGINE KUHLMANN

Inventor： LAVIRON CHARLES ,  SCHMIDGEN MICHEL

IPC: C01C3/02 ,  C01C3/04 ,  C07C121/30 ,  C07C121/18

CPC classification number: C01C3/0295 ,  C07C253/32 ,  C07C255/08

Abstract: A PROCESS FOR PURIFYING NITRILE-CONTAINING COMPOSITIONS, PARTICULARLY COMPOSITIONS CONTAINING HYDROCYANIC ACID OR NITRILES SUCH AS ACRYLONITRILE. THE PROCESS INVOLVES FREEING THE NITRILES OF EPOXIDE IMPURITIES BY CONVERTING THE LATTER TO THE CORRESPONDING GLYCOLS BY HYDRATION IN THE PRESENCE OF ACIDS. THE NITRILES ARE THEN DISTILLED TO LEAVE THE GLYCOLS AS TAIL PRODUCTS.

公开(公告)号：US3501533A

公开(公告)日：1970-03-17

申请号：US3501533D

申请日：1967-09-06

Applicant: ALLIED CHEM

Inventor： ANELLO LOUIS G ,  SWEENEY RICHARD F

IPC: C07C43/12 ,  B01D3/36 ,  C07C121/18

CPC classification number: C07C43/123