摘要:
In the recovery and purification of acrylonitrile or methacrylonitrile obtained by the ammoxidation reaction of propylene or isobutylene, the bottoms stream associated with the column for extractively distilling acrylonitrile or methacrylonitrile is both reduced in size and increased in polymer concentration by removing a vapor stream containing water from the lower fourth of said column, thus reducing the amount of solids-containing waste streams to be treated.
摘要:
In a process for the plural stage recovery of acrylonitrile, comprising a first stage extractive distillation zone, a second stage rectification zone and a third stage stripping zone; an improvement which comprises, maintaining the contents of the first stage extractive distillation zone and the second stage rectification zone at a pH in the range of about 5.5 to 7.5.
摘要:
Crude acrylonitrile or crude methacrylonitrile containing small amounts of water and HCN are fractionally distilled in a drying column to take an overhead stream of nitrile, water and HCN and a bottoms stream of the nitrile and HCN. The invention is a vapor side stream taken from the bottom half of the column which is very convenient to purify by a simple fractional distillation.
摘要:
D R A W I N G A PROCESS FOR THE REDUCTION OF METHACRYLONITRILE CONTENT OF PRODUCT ACRYLONITRILE WHICH COMPRISES INTRODUCING AT LEAST A PORTION OF A BOTTOM FRACTION FROM ANY ACRYLONITRILE HEAVY ENDS SPLITTER COLUMN INTO AN ABSORBING COLUMN, TAKING OVERHEAD FROM SAID ABOSRBING COLUMN A FRACTION CONTAINING AT LEAST PART OF THE METHACRYLONITRILE, TAKING A BOTTOM, FRACTION FROM THE ABSORBING COLUMN, REMOVING THE ABSORBING SOLVENT FROM THE BOTTOM FRACTION AND RETURNING THE ACRYLONTRILE IN THE BOTTOM FRACTION TO THE ACRYLONTRILE HEAVY ENDS SPLITTER COLUMN.