摘要:
The invention concerns a method of treating phosphate-containing waste, in particular phosphate-containing ash from waste-incineration plants, by wet-chemical digestion in order to obtain compounds of aluminum, calcium, phosphorus and nitrogen.
摘要:
A process for producing high-analysis dicalcium phosphate containing phosphatic fertilizers and by-product calcium nitrate. It comprises reacting phosphate rock with nitric acid, followed by pyrolysis of the resulting acidulate to effect liberation of approximately one-half of the initially consumed nitric acid. Recycling of this liberated nitric acid allows production of available phosphate with approximately one-half the acid equivalents normally consumed during sulfuric acid processing. The calcium nitrate in the resulting pyrolyzate is separated from the phosphatic constituent by dissolution in water followed by filtration. Depending upon the initial HNO.sub.3 :CaO acidulation ratio, the available phosphate content of the resulting solid phosphatic fertilizers is high enough (48% P.sub.2 O.sub.5) to allow their use either for bulk blending with nitrogen and potash salts to produce complete grade fertilizers or for direct application as a phosphate nutrient. The resulting calcium nitrate stream may be processed to produce a variety of solid or fluid nitrogen fertilizer products. No "throw away" by-products (other than possibly siliceous gangue) are produced.
摘要:
The invention concerns mixtures of alkali salts of sulfosuccinic acid dialkylesters and higher aliphatic alcohols, and the use of these mixtures as defoaming agents for mineral acid decomposition media, in particular media decomposing phosphates.
摘要:
A CRYSTALLIZATION DEVICE IS PROVIDED HAVING A CRYSTALLIZATION ENCLOSURE WHICH IS DIVIDED INTO A PLURALITY OF VERTICAL STAGES BY A PLURALITY OF FLUIDIZATION CONTAINERS. LIQUOR FOR TREATMENT IS INTRODUCED AT THE LOWER PORTION OF THE ENCLOSURE AND EXHAUSTED LIQUOR IS REMOVED AT THE UPPER PORTION OF THE ENCLOSURE. A HEAT EXCHANGE FLUID, FOR EXAMPLE A COOLANT, IS CIRCULATED IN THE ENCLOSURE WHICH IS CHOSEN FOR ITS IMMISCIBILITY AND CHEMICAL NON-REACTIVITY WITH THE LIQUOR. FULLY GROWN CRYSTALS ARE USED TO
COOL THE COOLANT BEFORE BEING REMOVED FROM THE ENCLOSURE IN ORDER TO MINIMIZE ENERGY LOSSES.