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公开(公告)号：US10201783B2
公开(公告)日：2019-02-12
申请号：US15828547
申请日：2017-12-01
发明人： Jing Luo , Congzhi Zhang , Yongying Luo
摘要： A desulfurization absorption tower, a method for setting up the same and a method for operating the same. The tower may include an internal anti-corrosion layer that may be used for contacting the flue gas and the desulfurization absorption liquid, may define the tower chamber, and may include stainless steel plate whose thickness is 1.0 mm to 6.0 mm. The tower body may include an external supporting layer that may be used for supporting the anti-corrosion layer and may include carbon steel. The supporting layer and the anti-corrosion layer may be designed to jointly bear a load, wherein the supporting layer may be designed to bear a large part of the load, and the anti-corrosion layer may be designed to bear a small part of the load.
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2.发明授权公开(公告)号：US09527037B2
公开(公告)日：2016-12-27
申请号：US13883099
申请日：2011-11-08
CPC分类号： B01D53/96 , B01D9/0013 , B01D9/0054 , B01D53/1425 , B01D53/1475 , B01D2009/0086 , B01D2251/104 , B01D2251/106 , B01D2251/306 , B01D2251/604 , B01D2251/606 , B01D2252/20484 , B01D2252/20494 , B01D2257/504 , C01B17/56 , Y02C10/06 , Y02P20/152
摘要： A method for processing an amine-based solvent contaminated by the introduction of sulfur oxides is provided. A potassium compound is introduced into a contaminated solvent, and the contaminated solvent is cooled so that a solubility of a potassium sulfate becomes less than a specified concentration of potassium sulfate. Further, an oxidizing agent is introduced into the contaminated solvent so that a potassium sulfite is oxidized to potassium sulfate. The potassium sulfate is filtered out, wherein a prepared solvent is formed. Further, a device for processing an amine-based, sulfur oxide-contaminated solvent is provided.
摘要翻译： 提供了通过引入硫氧化物而污染的胺类溶剂的加工方法。 将钾化合物引入污染的溶剂中，并将被污染的溶剂冷却，使得硫酸钾的溶解度变得小于规定浓度的硫酸钾。 此外，将氧化剂引入污染的溶剂中，使得亚硫酸钾被氧化成硫酸钾。 过滤出硫酸钾，其中形成制备的溶剂。 此外，提供了用于处理胺类，硫氧化物污染溶剂的装置。
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公开(公告)号：US20050106089A1
公开(公告)日：2005-05-19
申请号：US10715492
申请日：2003-11-19
申请人： Edwin Albers , Harry Burkhead
发明人： Edwin Albers , Harry Burkhead
IPC分类号： B01D20060101 , B01D53/04 , B01D53/50 , B01J8/00 , B01J20/08 , B01J20/10 , C01B7/00 , C01B17/56 , C10G11/00 , C10G11/18 , C10J3/00
CPC分类号： B01D53/02 , B01D53/12 , B01D53/508 , B01D2253/106 , B01D2253/112 , B01D2253/304 , B01D2256/24 , B01D2257/302 , B01D2259/40084 , B01J20/08 , B01J20/10 , B01J2220/42 , C10G11/18 , C10J3/00 , C10K1/004
摘要： Chlorite-like phyllosilicate materials are found useful as SOx sorbents. A novel process of sulfur oxide sorption is provided utilizing these layered materials as contact solids. Typical industrial applications include sulfur removal from fluid catalyst cracking process, cold-side combustion gas sulfur abatement and cleaner coal gasification.
摘要翻译： 发现亚氯酸盐状页硅酸盐材料可用作SO 2 x吸附剂。 利用这些层状材料作为接触固体提供了一种新的硫氧化物吸附方法。 典型的工业应用包括从流体催化剂裂解过程中除去硫，冷侧燃烧气体硫减少和清洁煤气化。
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公开(公告)号：US4795619A
公开(公告)日：1989-01-03
申请号：US28572
申请日：1987-03-20
申请人： Bernard J. Lerner
发明人： Bernard J. Lerner
CPC分类号： B01D53/508 , B01D53/501 , B01D53/68
摘要： A method and apparatus for removing acid gases such as halogen acids and sulfur oxides from a hot flue gas by contacting the gas with a finely-divided, pre-moistened and partially-agglomerated, intimate mixture of a solid alkaline reagent and a deliquescent compound. The dry akaline reactang/deliquescent compound mix is pre-conditioned by exposure to a gas of controlled humidity for a time sufficient to cause partial liquefaction of the deliquescent compound. Contact at controlled humidity conditions may be effected in a treating vessel or in a transport duct prior to injection into the hot flue gas. Alternatively, the dispersed deliquescent compound may be separately liquefied prior to mixing with the alkaline solids. Liquefaction of the deliquescent compound is achieved by controlling the partial pressure of water vapor in the conditioning gas mixture at a level higher than the equilibrium vapor pressure of the liquefied deliquescent material or its highest hydrate. In these moistening methods, the ratio of deliquescent to alkaline solids feed rates is so adjusted as to avoid the buildup of wetted material on the duct walls.
摘要翻译： 通过使气体与固体碱性试剂和潮解化合物的细分，预润湿和部分团聚的紧密混合物接触，从热烟道气中除去卤素酸和硫氧化物等酸性气体的方法和装置。 干燥的碱性反应/潮解混合物通过暴露于受控湿度的气体预处理足以引起潮解化合物部分液化的时间。 在受控湿度条件下的接触可以在注入热烟道气之前在处理容器或运输管道中进行。 或者，分散的潮解化合物可以在与碱性固体混合之前单独液化。 潮解化合物的液化是通过将调节气体混合物中的水蒸气的分压控制在高于液化的潮解材料的平衡蒸气压或其最高水合物的水平来实现的。 在这些润湿方法中，潮解剂与碱性固体进料速率的比例进行了如此调整，以避免润湿材料在管道壁上积累。
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5.发明授权Process for purifying a sulfur dioxide containing gas with production of elemental sulfur 失效用生成元素硫来净化含二氧化硫的气体的方法
公开(公告)号：US4174383A
公开(公告)日：1979-11-13
申请号：US717943
申请日：1976-08-26
CPC分类号： C01B17/56 , B01D53/501 , C01B17/05
摘要： Process for purifying SO.sub.2 -containing gas comprising a first step of contacting said gas with an aqueous solution of an ammonium sulfite or an ammonium thiosulfate also containing ammonium sulfate, a second step of contacting the resulting solution with a H.sub.2 S-containing gas at 20.degree.-90.degree. C. to produce sulfur which is separated from the remaining solution, a third step of recyling 90 to 99.99% by volume of said remaining solution to the first step, and a fourth step of introducing 0.01 to 10% by volume of said remaining solution into a molten salt formed of ammonium sulfate and/or bisulfate so as to produce a gas containing SO.sub.2, ammonia, sulfur and steam, which is recycled to the first step.
摘要翻译： 包括用于纯化含SO 2的气体的方法，包括使所述气体与还含有硫酸铵的亚硫酸铵或硫代硫酸铵的水溶液接触的第一步骤，第二步是使所得溶液与含有H 2 S的气体在20℃下接触， 90℃，以产生与剩余溶液分离的硫，第三步骤，将90至99.99体积％的剩余溶液重新循环至第一步骤;第四步骤，将0.01至10体积％的所述剩余溶液 溶液形成由硫酸铵和/或硫酸氢盐形成的熔盐，以产生含有SO 2，氨，硫和蒸汽的气体，其被再循环到第一步。
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公开(公告)号：US3966418A
公开(公告)日：1976-06-29
申请号：US553958
申请日：1975-02-28
CPC分类号： B01D53/501 , C01B17/164 , Y10S261/09
摘要： A gas treatment apparatus suitable for removing sulfur oxides and dust from gas streams is disclosed. The gas to be treated is conveyed through a conduit and past at least one nozzle positioned in fluid communicaton with the interior of the conduit. The nozzle injects an atomized solution, such as an alkali metal carbonate solution, into the gas. Solids formed by contacting the gas with the solution collect on the inner surface of a conical funnel-shaped portion of a hollow body. The hollow body includes a conduit portion in coaxial alignment with the hollow body. The solids are first removed from the hollow body by a screw conveyer positioned on the conical funnel-shaped portion and then withdrawn through a solids exit port. Gases formed by the contact of the gas with the injected solution are removed through a gas exit port in the hollow body and a gas passageway defined by the inner surface of the hollow body and the outer surface of the conduit portion.
摘要翻译： 公开了一种适用于从气流中除去硫氧化物和灰尘的气体处理装置。 待处理的气体通过导管输送并且经过位于与导管内部流体通信的至少一个喷嘴。 喷嘴将诸如碱金属碳酸盐溶液的雾化溶液注入到气体中。 通过使气体与溶液接触而形成的固体聚集在中空体的锥形漏斗形部分的内表面上。 中空体包括与中空体同轴对准的导管部分。 首先通过位于锥形漏斗形部分上的螺旋输送机从中空体中除去固体，然后通过固体出口吸出。 通过气体与注射溶液的接触形成的气体通过中空体中的气体排出口和由中空体的内表面和导管部分的外表面限定的气体通道被去除。
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7.发明授权
公开(公告)号：US3965242A
公开(公告)日：1976-06-22
申请号：US580793
申请日：1975-05-27
CPC分类号： B01D53/501
摘要： Process for through desulfurization of exhaust gas by treating the gas through the steps of absorption, double decomposition, oxidation, and alkali sulfate conversion.
摘要翻译： 通过吸收，双重分解，氧化和碱式硫酸盐转化的步骤处理气体来通过废气的脱硫方法。
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8.发明授权
公开(公告)号：US3962112A
公开(公告)日：1976-06-08
申请号：US500653
申请日：1974-08-26
CPC分类号： B01D53/507
摘要： A process and composition for removing sulfur dioxide from combustion gases particularly those emitted from the burning of high sulfur coal. The gases are treated with a liquid composition comprising 1 to 10 pounds of ClO.sub.2 per hundred pounds of SO.sub.2 to be treated and from 5 to 40 pounds of detergent per pound of ClO.sub.2. The composition is preferably alkaline, and may be injected as an atomized spray into the stack carrying gases, to preferably produce a stack gas of a pH between 7.0 and 7.5. The composition may also include 0.1 to 40 pounds of alkali per pound of ClO.sub.2 and 0.1 to 20 pounds of ammonia per pound of ClO.sub.2. Additionally, 1 to 30 pounds of an organic solvent per pound of ClO.sub.2 may be added.
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9.发明授权
公开(公告)号：US3682593A
公开(公告)日：1972-08-08
申请号：US3682593D
申请日：1969-11-10
申请人： PARSONS CO RALPH M
发明人： BROWDER TIMOTHY J JR
CPC分类号： C01B17/56
摘要： REDUCING THE OXIDES OF NITROGEN FORMED DURING THE OXIDATION OF A SOURCE OF SULFUR WHICH CONTAINS NITROGEN COMPOUNDS TO INERT NITROGEN ALLOWS CONTAMINANT-FREE RECOVERY OF SULFUR DIOXIDE FROM THE PROCESS GAS STREAM OR ALLOWS THE PROCESS GAS STREAM TO BE DIRECTLY UTILIZED FOR THE PRODUCTION OF CONTAMINANT-FREE DERIVATIVES OF SULFUR
DIOXIDE, SUCH AS SULFUR TRIOXIDE, SULFURIC ACID, AND THE SULFATES.-
公开(公告)号：US3627464A
公开(公告)日：1971-12-14
申请号：US3627464D
申请日：1967-11-09
申请人： WELLMAN LORD INC
发明人： TERRANA JACK D , MILLER LEO A
摘要： PROCESS AND APPARATUS FOR THE RECOVERY OF SULFUR DIOXIDE FROM SO2-CONTAINING GASES IN A SYSTEM INVOLVING CONTACTING THE GAS WITH AN AQUEOUS SULFITE SOLUTION TO PRODUCE A SOLUTION OF THE CORRESPONDING BISULFITE WHICH IS A PRECURSOR OF SO2 AND SUBSEQUENTLY SEPARATING THE BISULFITE AND SO2-PARTIAL PRESSURE LOWING MATERIALS TO OBTAIN PURER BISULFITE WHICH IS THEN DECOMPOSED TO REGENERATE SULFUR DIOXIDE. EXAMPLES OF SULFITES INCLUDE POTASSIUM, CESIUM, AND RUBIDIUM SULFITES. IN THE PROCESS SEPARATION OF THE BISULFITE IS ACCOMPLISHED BY VAPORIZATION OF WATER FROM THE BISULFITE-CONTAINING SOLUTION, E.G. IN A FLASH CHAMBER TO SUPERSATURATE THE SOLUTION AND PRECIPITATE THE BISULFITE, E.G. IN AN AMOUNT EQUIVALENT TO THE AMOUNT OF THE SULFUR DIOXIDE REMOVED FROM THE WASTE GASES. CONDITIONS ARE CHOSEN TO PRECIPITATE CRYSTALS HAVING A SIZE SUITABLE FOR VACUUM DRUM FILTERING. THE CRYSTALS ARE ADVANTAGEOUSLY REDISSOLVED PRIOR TO HEATING TO REGENERATE THE SULFUR DIOXIDE AND A PORTION OF THIS SOLUTION IS USED TO WASH THE CRYSTALS ON THE DRUM FILTER AND IMPROVE THE PURITY THEREOF.
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