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    Cobalt-and sulfur-containing olefin isomerization process catalyst
    1.
    发明授权
    Cobalt-and sulfur-containing olefin isomerization process catalyst 失效
    含钴和含硫烯烃异构化工艺催化剂

    公开(公告)号：US3898179A

    公开(公告)日：1975-08-05

    申请号：US40712573

    申请日：1973-10-17

    申请人： UNIVERSAL OIL PROD CO

    发明人： GERMANAS DALIA ,  POLLITZER ERNEST L

    IPC分类号： B01J23/75 ,  B01J37/20 ,  C07C5/25 ,  B01J11/74

    CPC分类号： B01J37/20 ,  B01J23/75 ,  C07C5/2556 ,  C07C11/08

    摘要： Double bond isomerization of olefins utilizing a catalyst comprising cobalt and sulfur on a porous carrier; the catalyst being prepared by forming an initial composite of the cobalt with the carrier material, sulfiding the initial composite to provide a sulfur/cobalt atomic ratio of at least about 1 in the sulfided composite, and then stripping sufficient sulfur from the sulfided composite with hydrogen to provide a final isomerization catalyst composition having a sulfur/cobalt atomic ratio of less than about 1 and more than about 0.55.

    摘要翻译： 使用包含钴和硫的催化剂在多孔载体上双键异构化烯烃; 催化剂通过将钴与载体材料的初始复合物形成，硫化初始复合材料以在硫化复合材料中提供至少约1的硫/钴原子比，然后用氢气从硫化复合物中提取足够的硫， 以提供硫/钴原子比小于约1且大于约0.55的最终异构化催化剂组合物。

    Catalyst composition and production of 2,2-dichloropropionic acid therewith
    2.
    发明授权
    Catalyst composition and production of 2,2-dichloropropionic acid therewith 失效
    催化剂组成和其中生成2,2-二氯丙酸

    公开(公告)号：US3882045A

    公开(公告)日：1975-05-06

    申请号：US44674574

    申请日：1974-02-28

    申请人： FOOLADI MIKE MEHDI

    发明人： FOOLADI MIKE MEHDI

    IPC分类号： B01J27/06 ,  C07C51/363 ,  B01J11/74 ,  B01J11/78

    CPC分类号： B01J27/06 ,  C07C51/363 ,  C07C53/19

    摘要： A catalyst composition, particularly adapted for use in the production of dichloropropionic acid is provided. The catalyst composition comprises elemental iodine, which may be combined with a phosphorous trihalide or with bis (dimethyl thio carbamoyl) disulfide or with both. The catalyst composition makes possible the production of 2,2-dichloropropionic acid by direct chlorination of propionic acid, with substantially higher yields not heretofore obtainable in the production of 2,2dichloropropionic acid by direct chlorination of propionic acid.

    摘要翻译： 提供了特别适用于制备二氯丙酸的催化剂组合物。 催化剂组合物包含元素碘，其可与三卤化磷或双（二甲基硫代氨基甲酰基）二硫化物或两者结合。 该催化剂组合物可以通过丙酸的直接氯化生产2,2-二氯丙酸，而在通过直接氯化丙酸生产2,2-二氯丙酸时，产率基本上更高。

    Process for manufacturing a catalyst,the resulting catalyst and its use in a process for hydrogenating hydrocarbons
    3.
    发明授权
    Process for manufacturing a catalyst,the resulting catalyst and its use in a process for hydrogenating hydrocarbons 失效
    催化剂制备方法，催化剂及其在氢化氢气加工过程中的应用

    公开(公告)号：US3847835A

    公开(公告)日：1974-11-12

    申请号：US35616973

    申请日：1973-05-01

    申请人： INST FRANCAIS DU PETROLE

    发明人： COSYNS J

    IPC分类号： B01J23/85 ,  B01J37/20 ,  C10G45/38 ,  B01J11/74

    CPC分类号： B01J37/20 ,  B01J23/85 ,  C10G45/38

    摘要： 1. IN A PROCESS FOR MANUFACTURING A CATALYST CONSISTING ESSENTIALLY OF AN ALUMINA CARRIER HAVING A SPECIFIC SURFACE OF 120-500 M2/G. AND A PORE VOLUME OF 0.2-0.9 CC./G. NICKEL SULFIDE OR COBALT SULFIDE, AND A SULFIDE OF A GROUP VIA METAL, SAID SULFIDES BEING PRESENT IN A CATALYTIC AMOUNTS, WHICH PROCESS COMPRISES IMPREGNATING THE ALUMINA CARRIER WITH A SOLUTION OF COMPOUNDS OF SAID METALS WHICH FORM METALLIC OXIDES UPON CALCINING; CALCINING THE IMPREGNATED CARRIER; AND SULFIDING RESULTANT CALCINED CATALYST WITH A GAS CONTAINING HYDROGEN SULFIDE, THE IMPROVEMENT IN SAID IMPREGNATING AND CALCINING STEPS OF: (1) IMPREGNATING SAID CATALYST WITH A SOLUTION CONSISTING ESSENTIALLY OF A NICKEL OR COBALT COMPOUND CAPABLE OF FORMING AN OXIDE UPON CALCINING, DRYING AND THEN CALCINING THE IMPREGNATED PRODUCT IN THE PRESENCE OF AIR AT 700-850*C.; AND (2) IMPREGNATING RESULTANT CALCINED PRODUCT FROM STEP (1) WITH A SOLUTION CONSISTING ESSENTIALLY OF CATALYTIC QUANTITIES OF (A) A NICKEL OF COBALT COMPOUND CAPBALE OF FORMING AN OXIDE UPON CALCINING AND (B) A COMPOUND OF A GROUP VIA METAL CAPABLE OF FORMING AN OXIDE UPON CALCINING, DRYING AND THEN CALCINING THE RESULTANT IMPREGNATED PRODUCT IN AIR AT 400-600*C.; THE AMOUNT OF NICKEL OR COBALT OXIDE INCORPORATED IN THE CARRIER IN THE FIRST STEP BEING SUFFICIENT TO IMPROVE THE STABILITY OF THE CATALYST SO THAT THE COMBINATION OF STEPS (1) AND (2) YIELDS A CATALYST HAVING A HIGHER STABILITY DURING HYDROGENATION OF DIOLEFINS THAN A CORRESPONDING CATALYST PREPARED WITHOUT THE FIRST HIGH TEMPERATURE CALCINING STEP.

    Method of preparing a catalyst
    4.
    发明授权
    Method of preparing a catalyst 失效

    公开(公告)号：US3751380A

    公开(公告)日：1973-08-07

    申请号：US3751380D

    申请日：1971-12-06

    申请人： UNIVERSAL OIL PROD CO

    发明人： O HARA M

    IPC分类号： B01J37/20 ,  C10G45/08 ,  B01J11/40 ,  B01J11/74

    CPC分类号： B01J37/20 ,  C10G45/08

    摘要： A METHOD OF PREPARING A HYDROREFINING CATALYST FOR THE CONVERSION OF C7-INSOLUBLE ASPHALTENES AND SULFUROUS COMPONENTS IN A RESIDUAL OIL. THE CATALYST COMPRISES A REFRACTORY INORGANIC OXIDE CARRIER MATERIAL IMPREGNATED WITH A METAL OR GROUPS VI-B AND VIII. IMPROVED ACTIVITY AND STABILITY RESULTS FROM NOVEL OXIDIZING AND REDUCING PROCEDURES PRIOR TO SULFIDING OF THE CATALYST.

    Slurry processing for black oil conversion
    8.
    发明授权
    Slurry processing for black oil conversion 失效

    公开(公告)号：US3622498A

    公开(公告)日：1971-11-23

    申请号：US3622498D

    申请日：1970-01-22

    申请人： UNIVERSAL OIL PROD CO

    发明人： STOLFA FRANK ,  STINE LAURENCE O

    IPC分类号： C10G45/16 ,  C10G49/22 ,  B01J11/74 ,  C10G13/06 ,  C10G23/16

    CPC分类号： C10G45/16 ,  C10G49/22

    摘要： A catalytic slurry process for effecting the conversion of a hydrocarbonaceous charge stock containing asphaltenes and metallic contaminants. The slurry constitutes the charge stock, hydrogen, a portion of the previously produced product effluent and from about 1.0 to about 25.0 percent by weight of finely divided catalyst particles. Preferred catalysts are the unsupported sulfides of the metals from Groups V-B, VI-B and VIII. A series of product separation steps facilitates catalyst circulation, catalyst withdrawal, and recovery of a substantially catalyst-free product.

    Slurry process for converting hydrocarbonaceous black oils with hydrogen and hydrogen sulfide
    9.
    发明授权
    Slurry process for converting hydrocarbonaceous black oils with hydrogen and hydrogen sulfide 失效
    用氢和硫化氢转化碳氢化合物的油性浆料

    公开(公告)号：US3619410A

    公开(公告)日：1971-11-09

    申请号：US3619410D

    申请日：1970-01-26

    申请人： UNIVERSAL OIL PROD CO

    发明人： GLEIM WILLIAM K T

    IPC分类号： B01J37/20 ,  C10G45/16 ,  C10G49/00 ,  B01J11/74 ,  C10G13/06 ,  C10G23/16

    CPC分类号： C10G49/007 ,  B01J37/20 ,  C10G2300/107

    摘要： A catalytic slurry process for hydrorefining a hydrocarbonaceous charge stock containing hydrocarbon insoluble asphaltenes. The process is effected in slurry fashion with the charge stock being admixed with an aqueous solution of a double salt of the catalytically active metal sulfite and ammonium sulfite. The slurry is reacted at conditions including a temperature above about 225* C. and a pressure greater than about 500 p.s.i.g., and in the presence of hydrogen and hydrogen sulfide. The particularly preferred double salt is vanadyl sulfite-ammonium sulfite, and is employed in an amount of 1.0 percent to about 25.0 percent by weight, computed as elemental vanadium.