发明授权
- 专利标题: Process for manufacturing a catalyst,the resulting catalyst and its use in a process for hydrogenating hydrocarbons
- 专利标题(中): 催化剂制备方法,催化剂及其在氢化氢气加工过程中的应用
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申请号: US35616973申请日: 1973-05-01
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公开(公告)号: US3847835A公开(公告)日: 1974-11-12
- 发明人: COSYNS J
- 申请人: INST FRANCAIS DU PETROLE
- 专利权人: Inst Francais Du Petrole
- 当前专利权人: Inst Francais Du Petrole
- 优先权: US35616973 1973-05-01; FR7045509 1970-12-16; US20816771 1971-12-15
- 主分类号: B01J23/85
- IPC分类号: B01J23/85 ; B01J37/20 ; C10G45/38 ; B01J11/74
摘要:
1. IN A PROCESS FOR MANUFACTURING A CATALYST CONSISTING ESSENTIALLY OF AN ALUMINA CARRIER HAVING A SPECIFIC SURFACE OF 120-500 M2/G. AND A PORE VOLUME OF 0.2-0.9 CC./G. NICKEL SULFIDE OR COBALT SULFIDE, AND A SULFIDE OF A GROUP VIA METAL, SAID SULFIDES BEING PRESENT IN A CATALYTIC AMOUNTS, WHICH PROCESS COMPRISES IMPREGNATING THE ALUMINA CARRIER WITH A SOLUTION OF COMPOUNDS OF SAID METALS WHICH FORM METALLIC OXIDES UPON CALCINING; CALCINING THE IMPREGNATED CARRIER; AND SULFIDING RESULTANT CALCINED CATALYST WITH A GAS CONTAINING HYDROGEN SULFIDE, THE IMPROVEMENT IN SAID IMPREGNATING AND CALCINING STEPS OF: (1) IMPREGNATING SAID CATALYST WITH A SOLUTION CONSISTING ESSENTIALLY OF A NICKEL OR COBALT COMPOUND CAPABLE OF FORMING AN OXIDE UPON CALCINING, DRYING AND THEN CALCINING THE IMPREGNATED PRODUCT IN THE PRESENCE OF AIR AT 700-850*C.; AND (2) IMPREGNATING RESULTANT CALCINED PRODUCT FROM STEP (1) WITH A SOLUTION CONSISTING ESSENTIALLY OF CATALYTIC QUANTITIES OF (A) A NICKEL OF COBALT COMPOUND CAPBALE OF FORMING AN OXIDE UPON CALCINING AND (B) A COMPOUND OF A GROUP VIA METAL CAPABLE OF FORMING AN OXIDE UPON CALCINING, DRYING AND THEN CALCINING THE RESULTANT IMPREGNATED PRODUCT IN AIR AT 400-600*C.; THE AMOUNT OF NICKEL OR COBALT OXIDE INCORPORATED IN THE CARRIER IN THE FIRST STEP BEING SUFFICIENT TO IMPROVE THE STABILITY OF THE CATALYST SO THAT THE COMBINATION OF STEPS (1) AND (2) YIELDS A CATALYST HAVING A HIGHER STABILITY DURING HYDROGENATION OF DIOLEFINS THAN A CORRESPONDING CATALYST PREPARED WITHOUT THE FIRST HIGH TEMPERATURE CALCINING STEP.
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