摘要:
Aqueous foam compositions comprising water and a mixture of ammonium lauryl sulfate, methyl polyoxyethylene cocoamine chloride, dimethyl cocoamine oxide and polyvinyl alcohol are used to suppress the formation of fumes from fumable materials by covering the material with said compositions in the form of foam, thereby causing the material to react with the water to prevent fume release.
摘要:
A PROCESS FOR REACTIVATION, INCLUDING CHLORINATION, OF A FIXED BED OF CARBON-FOULED, PLATINUM GROUP METAL- AND RHENIUM-CONTAINING, ALUMINA-SUPPORTED CATALYST IS DISCLOSED WHICH INVOLVES CONTACTING THE CATALYST WITH AN OXYGEN-CONTAINING GAS, THEN WITH A GASEOUS STREAM CONTAINING INERT GAS, OXYGEN AND VAPOROUS CHLORINE-CONTAINING AGENT UNTIL AT LEAST ABOUT 0.2% CHLORINE HAS BEEN ADDED TO THE CATALYST BASED ON THE TOTAL WEIGHT OF CATALYST IN THE BED. CONTACT OF THE CATALYST IS THEN CONTINUED WITH A GASEOUS STREAM CONTAINING INERT GAS, OXYGEN AND A MINOR AMOUNT OF WATER VAPOR TO DISTRIBUTE CHLORINE IN THE CATALYST BED.
摘要:
A PROCESS FOR THE REGENERATION OF SULFUR DEACTIVATED CATALYSTS BY CONTACT, OR REACTION, OF THE SAID CATALYST WITH METHANE. A CATALYST, OR CATALYST COMPOSITE, WHICH HAS BEEN POISONED, AND THEREBY DEACTIVATED, BY CONTACT WITH SULFUR IN SUFFICIENT CONCENTRATION AND EXPOSED TO OXYGEN TO FORM THE SULFATE, CAN BE REGENERATED BY CONTACT WITH METHANE. SUCH CATALYST REGENERATION TECHNIQUE FINDS PARTICULAR UTILITY IN SEMIREGENERATIVE TYPE REFORMING PROCESSES. REFORMING CATALYSTS, PARTICULARLY CATALYST COMPOSITES WHICH CONTAIN ALUMINA, E.G. NOBLE METAL ON AN ALUMINA BASE SUCH AS PLATINUM-ON-ALUMINA, WHICH HAS BEEN DEACTIVATED BY SULFUR COMPOUNDS CAN BE REGENERATED BY CONTACT WITH METHANE AT TEMPERATURES RANGING GENERALLY FROM ABOUT 700*F. TO ABOUT 1050*F., AND AT PRESSURES RANGING FROM ABOUT 15 P.S.I. TO ABOUT 300 P.S.I.
摘要:
Deactivated catalysts containing Group VIII metal contact agents are regenerated by a process comprising impregnating the deactivated composite material with tin or a tin compound. Preferably, the tin-impregnated composite is thereafter calcined. The process is particularly suitable for the regeneration of deactivated reforming and dehydrogenation catalysts.
摘要:
AQUEOUS WASH SOLUTIONS, PARTICULARLY THE ALKALINE WASH SOLUTIONS USED IN THE TREATMENT AND REACTIVATION OF CATALYSTS FOR UNSTURATED ESTER PRODUCTION ARE REGENERATED AND GENERALLY RECONSTITUTED FOR REUSE BY ADDITION OF AN ACID THERETO TO ADJUST THE PH TO THE OPTIMUM LEVEL AT WHICH PRECIPITATION OF IMPURIRITES AND DECREASE IN COLOR OCCURS. AS AN ADDITIONAL FEATURE, AFTER FILTERING, THE ALKALINE SOLUTION OBATINED CAN BE TREATED WITH ACTIVATED CARBON. ADDITION OF ALKALI, WITH OR WITHOUT WATER DILUTION, AS REQUIRED, RESTORES THE WASH SOLUTION TO ITS ORIGINAL COMPOSITION.
摘要:
The invention relates to a not as yet considered kind of corrosion of products made of silicon carbide working in elevated temperatures and discloses a method of preventing this kind of corrosion which begins already at the moderate temperature of about 550.degree. C. and is caused by the formation of carbon monoxide in the pores of the interior of the silicon carbide products in conditions of limited penetration of oxygen into these pores. The disclosed method of preventing this kind of corrosion consists in shielding part of the surface of the mentioned silicon carbide products by perfectly gastight shields or by a protective atmosphere or inversely in enhancing the access of oxygen into the pores of the mentioned product thus diluting the carbon monoxide being formed, by enlarging the number of open pores so that an open porosity of the product exceeding about 40 percent is reached or by providing uniformly distributed channels in the silicon carbide product the total volume of channels being at least about 10 percent of the outer volume of the product.
摘要:
Supported iridium-containing hydrocarbon conversion catalysts which are at least partially deactivated due to the deposition of carbonaceous residues thereon during contact with hydrocarbons are regenerated by contacting the catalyst, prior to contact with oxygen at elevated temperature, with a chlorine-containing reagent to increase the catalyst chlorine content to at least 1.0 wt. %., based on anhydrous catalyst, and thereafter contacting the catalyst with a gaseous mixture containing oxygen, a chlorine containing reagent, and water at a temperature of about 750* to 1000*F. for a time sufficient to burn at least a portion of the carbonaceous residues from the catalyst.
摘要:
A HALOGENATED REFORMING CATALYST COMPRISING PLATINUM WHICH HAS BECOME DEACTIVATED WITH CARBONACEOUS DEPOSITS DURING ON-STREAM REFORMING IS REGENERATED BY THE COMBINATION OF (1) REMOVING CARBONACEOUS MATERIAL BY BURNING WITH AN OXYGEN CONTAINING GAS UNDER CONDITIONS TO AVOID HEAT DAMAGE TO THE CATALYST, (2) HEATING THE CATALYST ITH AIR TO A TEMPERATURE OF ABOUT 900*F, (3) SELECTIVELY CHLORINATING EACH CATALYST BED WITH A MOISTURE SATURATED AIR STREAM TO A PREDETERMINED CHLORIDE LEVEL, (4) REDUCING THE CHLORIDED CATALYST WITH HYDROGEN RICH GAS FOR A PERIOD OF TIME IN THE RANGE OF 1 TO 4 HOURS, (5) ADDING SULFUR TO EACH CATALYST BED THEROETICALLY SUFFICIENT TO SULFIDE THE PLATINUM COMPONENT OF THE CATALYST AND (6) INITIATING ON-STREAM REFORMING OF NAPHTHA IN THE PRESENCE OF ADDED HYDROGEN SULFIDE.
摘要:
A PROCESS IS DISCLOSED FOR REACTIVATING ALUMINA SUPPORTED HYDROGENATION BY TREATING THE CATALYST WITH EITHER AN ALKALI METAL HYDROXIDE OR ALKALINE EARTH METAL HYDROXIDE IN DILUTE AQUEOUS SOLUTION TO THORROUGHLY WET THE CATALYST THEN HEATING THE TREATED CATALYST TO A TEMPERAURE OF BETWEEN ABOUT 100*C. AND ABOUT 500*C., AND ALLOWING THE CATALYST TO COOL.
摘要:
HYDROGENATION CATALYSTS POISONED BY LEAD, PARTICULARLY PALLADIUM ALUMINA CATALYSTS, ARE REGENERATED WITH DILUTE NITRIC OR ORTHOPHOSPHORIC ACID AT AMBIENT OR SLIGHTLY RAISED TEMPERATURES.