Silver halide photographic light-sensitive material
    2.
    发明授权
    Silver halide photographic light-sensitive material 失效
    卤化银照相感光材料

    公开(公告)号:US06171774B2

    公开(公告)日:2001-01-09

    申请号:US09189194

    申请日:1998-11-09

    CPC classification number: G03C7/3013 G03C1/385 G03C7/367 G03C7/39216 G03C7/396

    Abstract: A silver halide photographic light sensitive material is disclosed. The light-sensitive material comprises a support having thereon a yellow dye image-forming emulsion layer, a magenta dye image-forming emulsion layer, and a cyan dye image-forming emulsion layer and optionally a light-insensitive layer, in which said yellow image-forming emulsion layer contains a yellow dye-forming coupler represented by Formula I and an organic solvent-soluble polymer, and a light-sensitive or light-insensitive layer each adjoined to the yellow image forming emulsion layer contains a polymer which have a constituting unit represented by Formula II; wherein RA is an alkyl group or a cycloalkyl group, RB is a halogen atom or an alkoxy group, RC is a group capable of being a substituent of the benzene group, m is an integer of from 0 to 40, and Z is a releasing group;

    Abstract translation: 公开了一种卤化银照相感光材料。 感光材料包括其上具有黄色染料影像形成乳剂层,品红染料影像形成乳剂层和青色染料影像形成乳剂层以及可选的不透光层的支持体,其中所述黄色图像 形成乳剂层含有由式I表示的黄色染料成色剂和有机溶剂可溶性聚合物,并且与黄色图像形成乳剂层相邻的感光或光不敏感层含有具有构成单元的聚合物 由式II表示;其中RA是烷基或环烷基,RB是卤素原子或烷氧基,RC是能够作为苯基的取代基的基团,m是0-40的整数, Z是释放组;

    Silver halide photographic element containing improved yellow
dye-forming coupler
    3.
    发明授权
    Silver halide photographic element containing improved yellow dye-forming coupler 失效
    含有改进的黄色染料成色剂的卤化银照相元件

    公开(公告)号:US6162598A

    公开(公告)日:2000-12-19

    申请号:US217588

    申请日:1998-12-22

    CPC classification number: G03C7/30535 G03C7/3212 G03C7/367

    Abstract: A color photographic element includes a support, a silver halide emulsion layer, and associated therewith a yellow dye-forming coupler having the formula ##STR1## wherein R.sup.1 represents a tertiary alkyl group containing 4 to about 20 carbon atoms; R.sup.2 represents an alkyl, aryl, or heterocyclic group; X represents hydrogen or a substituent; Y and Z each independently represent a group consisting of those substituents having a Hammett sigma.sub.para constant greater than zero; and m and n is each 1 to 4.

    Abstract translation: 彩色照相元件包括载体,卤化银乳剂层,并与其结合,具有下式的黄色染料形成成色剂:其中R 1表示含有4至约20个碳原子的叔烷基; R 2表示烷基,芳基或杂环基; X表示氢或取代基; Y和Z各自独立地表示由具有大于零的Hammett sigmapara常数的那些取代基组成的组; m和n分别为1〜4。

    Photographic element having a blue light sensitive layer containing a
particular yellow dye-forming coupler and a magenta image dye-forming
coupler
    4.
    发明授权
    Photographic element having a blue light sensitive layer containing a particular yellow dye-forming coupler and a magenta image dye-forming coupler 失效
    具有含有特定的黄色染料成色剂和品红色成像剂的蓝色感光层的照相元件

    公开(公告)号:US5462842A

    公开(公告)日:1995-10-31

    申请号:US180252

    申请日:1994-01-12

    Abstract: The invention provides a photographic element and process of forming an image where the element is a multicolor photographic element comprising at least one light sensitive photographic silver halide emulsion layer sensitive to blue light and containing a yellow image dye-forming coupler, at least one light sensitive photographic silver halide emulsion layer sensitive to green light: and containing a magenta image dye-forming coupler, and at least one light sensitive photographic silver halide emulsion layer sensitive to red light and containing a cyan dye-forming coupler,wherein the yellow image dye-forming coupler has the formula I: ##STR1## wherein t-Bu is a tertiary butyl group, Ph is an unsubstituted phenyl ring or one containing up to 5 substituents, and Y is a heterocyclic ring, substituted or non, which is capable of leaving upon reaction if the coupler with oxidized developer; andwherein said at least one light sensitive photographic silver halide emulsion layer sensitive to blue light and containing the yellow image dye-forming coupler, or another light sensitive photographic silver halide emulsion layer sensitive to blue light and containing a yellow image dye-forming coupler has associated therewith a magenta image dye-forming coupler.

    Abstract translation: 本发明提供了一种照相元件和形成图像的方法,其中元件是多色照相元件,其包含至少一种对蓝光敏感的感光照相卤化银乳剂层,并含有黄色成像染料的成色剂,至少一种光敏 对绿光敏感的照相卤化银乳剂层,并含有品红色影像染料形成成色剂,和至少一种对红光敏感并含有青色染料成色剂的感光性感光卤化银乳剂层,其中黄色图像染料 - 其中t-Bu是叔丁基,Ph是未取代的苯环或含有至多5个取代基的一个,Y是一个被取代或非取代的杂环,其能够 如果耦合剂与氧化显影剂反应,则反应; 并且其中所述至少一个对蓝光敏感并含有黄色成像成色剂的感光感光照相卤化银乳剂层或对蓝色光敏感且含有黄色成像成色剂的另一感光性照相卤化银乳剂层具有 与其相关联的品红色图像染料形成耦合器。

    Colour photographic copying material
    5.
    发明申请
    Colour photographic copying material 审中-公开
    彩色照相复印材料

    公开(公告)号:US20050112513A1

    公开(公告)日:2005-05-26

    申请号:US10950134

    申请日:2004-09-24

    Abstract: A colour-photographic copying material comprising at least one red-sensitive silver halide emulsion layer containing at least two cyan couplers, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler, and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that at least one cyan coupler corresponds to formula (I) and at least one cyan coupler corresponds to formula (II) wherein R1, R1′ represent, independently of one another, a hydrogen atom or an alkyl group, R2, R2′ represent, independently of one another, an alkyl or an aryl group, R3, R3′ represent, independently of one another an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulphonyloxy, sulphamoylamino, sulphonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom, Z, Z′ represent, independently of one another, a hydrogen atom or a group that may be cleaved under the conditions of chromogenic development, X, X′ represent, independently of one another, S, NH or NR4, and R4 represents an alkyl or an aryl group, and wherein at least 20% by weight of each of the cyan couplers of formulae (I) and (II), based on the total quantity of cyan coupler, are contained in the red-sensitive layer, is characterised by good colour reproduction, good dye stability, a smooth surface, a high cyan colour density, and in that it may be produced economically.

    Abstract translation: 包含至少一种包含至少两个青色成色剂的至少一种感红卤化银乳剂层,含有至少一种品红色成色剂的至少一种感绿卤化银乳剂层和至少一种感蓝卤化银的彩色照相复印材料 乳液层,其含有至少一种黄色成色剂,其特征在于至少一种青色成色剂对应于式(I),并且至少一种青色成色剂对应于式(II),其中R 1,R 2, 1''彼此独立地表示氢原子或烷基,R 2,R 2'彼此独立地表示烷基 或芳基,R 3,R 3'彼此独立地表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,磺酰氨基, 脲基,羟基羰基,羟基羰基氨基,氨基甲酰基,烷硫基,芳硫基,烷基氨基或芳基氨基或氢原子,Z,Z' 彼此独立地是氢原子或在显色发展条件下可被切割的基团,X,X'彼此独立地表示S,NH或NR 4,以及 R 4表示烷基或芳基,并且其中式(I)和(II)的青色成色剂中的至少20重量%,基于青色成色剂的总量, 被包含在红色敏感层中,其特征在于良好的色彩再现性,良好的染料稳定性,光滑的表面,高的青色浓度,并且可以经济地制造。

    Photographic element
    6.
    发明授权
    Photographic element 失效
    摄影元素

    公开(公告)号:US06420103B1

    公开(公告)日:2002-07-16

    申请号:US09266178

    申请日:1999-03-10

    CPC classification number: G03C7/3885 G03C7/362 G03C7/367 G03C7/38

    Abstract: Silver halide light sensitive photographic elements are disclosed comprising a support bearing at least one yellow image forming hydrophilic colloid layer comprising a yellow dye-forming coupler and a trialkyl citrate coupler solvent of the formula C3H4(OH)(CO2R)3, where each R independently represents an alkyl group and the total number of carbon atoms for the three R groups combined is greater than 6. The combination of such citrate ester solvents with yellow dye forming couplers in photographic elements leads to both good reactivity and good image-dye light stability. The advantages of the invention are particularly useful for photographic color paper elements on reflective supports.

    Abstract translation: 公开了卤化银光敏感照相材料,其包括载体,该载体承载至少一个黄色图像形成亲水胶体层,其包含黄色染料形成成色剂和式C 3 H 4(OH)(CO 2 R)3的三烷基柠檬酸酯偶联剂溶剂,其中每个R独立地 代表烷基,并且三个R基团的总碳原子数大于6.这些柠檬酸酯溶剂与形成成色剂的黄色染料在照相元件中的组合导致良好的反应性和良好的图像染料光稳定性。 本发明的优点对于反射支撑件上的照相彩色纸元件特别有用。

    Low contrast film
    7.
    发明授权
    Low contrast film 失效
    低对比度胶片

    公开(公告)号:US5674665A

    公开(公告)日:1997-10-07

    申请号:US560134

    申请日:1995-11-17

    Abstract: A color negative photographic film wherein on the curve of density versus log E for each color sensitive record: (1) a straight line, which connects the point at density Dmin+0.1 and the point at 1.5log E above the exposure required for density Dmin+0.2, has a mathematical slope .ltoreq. 0.50; and (2) the difference in log E is .gtoreq.1.7 between the point 0.9log E above the exposure required for density Dmin+0.2 and the point where the density difference is 0.1 between the curve and the straight line which results from a linear regression of the three density points at exposures 0.3log E, 0.9log E, and 1.5log E above the exposure required for the density Dmin+0.2; and (3) the difference in log E is .gtoreq.1.20 between the exposure needed for density Dmin+0.1 and the point that corresponds to the exposure, in lux-seconds, of 9.2/(Film Speed). The exposure of the foregoing gray card is a typical normal exposure based on the film speed rating (i.e. the film is not overexposed or underexposed).

    Abstract translation: 一种彩色负片照相胶片,其中对于每种色彩敏感记录,其密度对logE的曲线:(1)将密度Dmin + 0.1的点和在密度Dmin所需曝光以上1.5log E的点连接的直线 +0.2,数学斜率 / = 1.7 回归三个密度点在曝光时0.3log E,0.9log E和1.5log E以上所需的曝光浓度Dmin + 0.2; 和(3)在密度Dmin + 0.1所需的曝光与对应于曝光的点之间的log E的差为> / = 1.20(勒克斯秒)为9.2 /(胶片速度)。 上述灰卡的曝光是基于胶片速度等级的典型的正常曝光(即胶片不曝光不足或曝光不足)。

    Absorption of dye made from
    8.
    再颁专利

    公开(公告)号:USRE28055E

    公开(公告)日:1974-06-25

    申请号:US28055D

    申请日:1972-08-09

    CPC classification number: C07D271/113 C07D295/192 G03C7/30535 G03C7/367

    Abstract: ACETOACETAMIDE COUPLERS IN WHICH THE NON-OXO CARBON ATOM OF THE ACETO GROUP IS A TERTIARY CARBON ATOM ARE ADVANTAGEOUSLY USED AS YELLOW DYE-FORMING COUPLERS IN PHOTOGRAPHY; THE COUPLERS ARE CHARACTERIZED BY PRODUCING DYES UPON COLOR DEVELOPMENT THAT HAVE VERY DESIRABLE ABSORPTION CHARACTERISTICS WITH RELATIVELY LOW ABSORPTION IN THE GREEN AND RED AREAS OF THE SPECTRUM, EXCEPTIONALLY GOOD STABILITY TO PROLONGED EXPOSURE TO LIGHT AND THE COUPLERS WHEN INCORPORATED IN PHOTOGRAPHIC EMULSION LAYERS EXHIBIT CONSIDERABLY LESS "PRINT OUT" ON PROLONGED EXPOSURE TO LIGHT AND LESS "YELLOWING" THAN PRIOR ART COUPLERS SUCH AS THE ALPHA-BENZOLYL ANALOGUES.

    Silver halide photosensitive material and method of forming image
    9.
    发明申请
    Silver halide photosensitive material and method of forming image 审中-公开
    卤化银感光材料和形成图像的方法

    公开(公告)号:US20050227188A1

    公开(公告)日:2005-10-13

    申请号:US10521229

    申请日:2002-07-18

    Abstract: The present invention provides a method of forming a digital images exhibiting superior clearness in line images and superior visual whiteness. An image forming method of the invention comprises exposing a silver halide photographic material and processing the photographic material, wherein the photographic material contains a compound represented by the following formula (1) and a white area of the processed photographic material exhibits perception chromaticity indexes a and b of from 0.0 to +2.0 and from −2.2 to −4.0, respectively, in which the foregoing a and b are defined in JIS-Z-8730 and measured in accordance with a method defined in JIS-Z-8722:

    Abstract translation: 本发明提供了一种形成在线图像中具有优异清晰度和优异的视觉白度的数字图像的方法。 本发明的图像形成方法包括曝光卤化银照相材料并处理照相材料,其中照相材料含有由下式(1)表示的化合物,并且经处理的感光材料的白色区域表现出感知色度指数a和 b分别为0.0〜+ 2.0和-2.2〜-4.0,其中上述a和b在JIS-Z-8730中定义,并按照JIS-Z-8722:

    Color photographic silver halide material
    10.
    发明授权
    Color photographic silver halide material 失效
    彩色照相卤化银材料

    公开(公告)号:US06171776B2

    公开(公告)日:2001-01-09

    申请号:US09209404

    申请日:1998-12-10

    CPC classification number: G03C1/29 G03C1/16 G03C7/367

    Abstract: A colour photographic silver halide material in which at least one of the blue-sensitive silver halide emulsions is spectrally sensitised with a mixture of at least one seansitising dye of the formula (I) and at least one sensitising dye of the formula (II): in which R1 means an optionally substituted thienyl, pyrroly, indolyl, furamyl or phenyl, in which R5, R6, R7, mean H or R5 and R6 together or R6 and R7 together mean the remaining members of a fused benzo ring and the residual substituent means H and R2, R3, R4, R8, R9, R10 and M have the meaning stated in the description, is distinguished by elevated sensitivity and improved latent image stabilitity.

    Abstract translation: 一种彩色照相卤化银材料,其中至少一种感蓝卤化银乳剂用式(I)的至少一种海藻染料和至少一种式(II)的敏化染料的混合物进行光谱增感: 其中R 1表示任选取代的噻吩基,吡咯基,吲哚基,呋喃基或苯基,其中R 5,R 6,R 7,平均H或R 5和R 6一起或R 6和R 7一起表示稠合的苯并环的剩余成员,残基取代基表示H 和R2,R3,R4,R8,R9,R10和M具有描述中所述的含义,其特征在于提高的灵敏度和改善的潜像稳定性。

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