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    Solid electrolyte sensor for monitoring the concentration of an element in a fluid particularly molten metal
    4.
    发明授权
    Solid electrolyte sensor for monitoring the concentration of an element in a fluid particularly molten metal 失效
    用于监测流体中元素浓度特别是熔融金属的固体电解质传感器

    公开(公告)号：US07335287B2

    公开(公告)日：2008-02-26

    申请号：US10472935

    申请日：2002-03-25

    申请人： Ivor W Jones ,  Glyn Atherton ,  Francis M Stackpool

    发明人： Ivor W Jones ,  Glyn Atherton ,  Francis M Stackpool

    IPC分类号： G01N27/406

    CPC分类号： G01N33/206 ,  G01N27/411 ,  G01N27/4117

    摘要： The present invention relates to an electrochemical sensor for determining the concentration of a group IA metal in a fluid such as molten metal. The sensor comprises a substantially pure quantity of the group 1A metal as a reference electrode (13) contained in a sensor housing (3), and a solid electrolyte constituting at least part of the sensor housing (3). The electrolyte is in electrical contact with the reference electrode (13) and the sensor is capable of operating at temperatures in excess of 973K. In a preferred arrangement, the sensor comprises a two part elongate conductor (15), a first part (17) of which extends from the reference electrode (13) into a refractory seal (11a), and a second part (19) of which extends from within the refractory seal (11a) externally of the sensor, the two parts (17, 19) being welded together.

    摘要翻译： 本发明涉及一种用于确定诸如熔融金属的流体中IA族金属的浓度的电化学传感器。 传感器包括基本上纯的作为包含在传感器壳体（3）中的参考电极（13）的组1A金属和构成传感器壳体（3）的至少一部分的固体电解质。 电解液与参考电极（13）电接触，传感器能够在超过973K的温度下工作。 在优选的布置中，传感器包括两部分细长导体（15），第一部分（17）从参考电极（13）延伸到耐火密封件（11a）中，第二部分（19） 其从所述传感器外部的所述耐火密封件（11a）内延伸，所述两个部件（17,19）被焊接在一起。

    Solid electrolyte sensor for monitoring the concentration of an element in a fluid particularly molten metal
    5.
    发明申请
    Solid electrolyte sensor for monitoring the concentration of an element in a fluid particularly molten metal 失效
    用于监测流体中元素浓度特别是熔融金属的固体电解质传感器

    公开(公告)号：US20040084328A1

    公开(公告)日：2004-05-06

    申请号：US10472935

    申请日：2003-12-04

    发明人： Ivor W Jones ,  Glyn Arherton ,  Francis M Stackpool

    IPC分类号： G01N027/26

    CPC分类号： G01N27/4117 ,  G01N27/411 ,  G01N33/205

    摘要： The present invention relates to an electrochemical sensor for determining the concentration of a group IA metal in a fluid such as molten metal. The sensor comprises a substantially pure quantity of the group 1A metal as a reference electrode (13) contained in a sensor housing (3), and a solid electrolyte constituting at least part of the sensor housing (3). The electrolyte is in electrical contact with the reference electrode (13) and the sensor is capable of operating at temperatures in excess of 973K. In a preferred arrangement, the sensor comprises a two part elongate conductor (15), a first part (17) of which extends from the reference electrode (13) into a refractory seal (11a), and a second part (19) of which extends from within the refractory seal (11a) externally of the sensor, the two parts (17, 19) being welded together.

    摘要翻译： 本发明涉及一种用于确定诸如熔融金属的流体中IA族金属的浓度的电化学传感器。 传感器包括基本上纯的作为包含在传感器壳体（3）中的参考电极（13）的组1A金属和构成传感器壳体（3）的至少一部分的固体电解质。 电解液与参考电极（13）电接触，传感器能够在超过973K的温度下工作。 在优选的布置中，传感器包括两部分细长导体（15），其第一部分（17）从参考电极（13）延伸到耐火密封件（11a）中，并且其第二部分（19） 从传感器外部的耐火密封件（11a）内延伸，两部分（17,19）焊接在一起。

    Reference electrode for electrochemical determination of oxygen partial pressure in an ionic melt
    7.
    发明授权
    Reference electrode for electrochemical determination of oxygen partial pressure in an ionic melt 失效
    用于离子熔体中氧分压的电化学测定的参比电极

    公开(公告)号：US5580439A

    公开(公告)日：1996-12-03

    申请号：US528949

    申请日：1995-09-15

    申请人： Friedrich Baucke ,  Thomas Pfeiffer ,  Sylvia Biedenbender ,  Gernot Roth ,  Ralf-Dieter Werner

    发明人： Friedrich Baucke ,  Thomas Pfeiffer ,  Sylvia Biedenbender ,  Gernot Roth ,  Ralf-Dieter Werner

    IPC分类号： G01N33/38 ,  C03B5/00 ,  C03B5/24 ,  G01N27/30 ,  G01N27/411 ,  G01N27/26

    CPC分类号： G01N27/4117

    摘要： The method of electrochemical determination of oxygen partial pressure in ionic melts includes providing a metal/metal oxide reference electrode consisting of an electrode body made of a metal selected from the group consisting of Mo, W, Hf, Nb and Ta and alloys thereof and a layer of an oxide of that metal on the electrode body; immersing a pure platinum electrode and the metal/metal oxide reference electrode in a glass melt; measuring a potential across the metal/metal oxide reference electrode and the pure platinum electrode immersed in the glass melt to obtain a measured potential characteristic of the oxygen partial pressure in the glass melt; obtaining a calibration curve relating the potential across said reference electrode and the pure platinum electrode to the oxygen partial pressure in the glass melt as a function of temperature; and obtaining the oxygen partial pressure in the glass melt from the measured potential and the calibration curve. Either the calibration curve is obtained experimentally by immersing a Zirconium dioxide electrode in the glass melt and measuring a potential difference between the metal/metal oxide reference electrode and the Zirconium dioxide electrode at a plurality of temperatures or theoretically from thermodynamic data for the metal/metal oxide reference electrode.

    摘要翻译： 离子熔体中氧分压的电化学测定方法包括提供金属/金属氧化物参比电极，其由选自Mo，W，Hf，Nb和Ta的金属及其合金构成的电极体和 该金属的氧化物层在电极体上; 将纯铂电极和金属/金属氧化物参比电极浸入玻璃熔体中; 测量金属/金属氧化物参比电极和浸入玻璃熔体中的纯铂电极的电位，以获得测量的玻璃熔体中的氧分压的电位特性; 获得将所述参考电极和纯铂电极之间的电位与玻璃熔体中的氧分压相关的校准曲线作为温度的函数; 并从测量的电位和校准曲线获得玻璃熔体中的氧分压。 通过将二氧化锆电极浸入玻璃熔体中并且在多个温度下测量金属/金属氧化物参比电极和二氧化锆电极之间的电位差，或者理论上来自金属/金属的热力学数据，可以通过实验获得校准曲线 氧化物参比电极。

    Oxygen sensor
    8.
    发明授权
    Oxygen sensor 失效
    氧传感器

    公开(公告)号：US4717463A

    公开(公告)日：1988-01-05

    申请号：US6302

    申请日：1987-01-15

    申请人： Harry G. Clauss

    发明人： Harry G. Clauss

    IPC分类号： G01N27/411 ,  G01N27/413 ,  G01N27/58

    CPC分类号： G01N27/4117

    摘要： An expandable immersion oxygen sensor for molten metal is provided with an improved oxygen reference electrode including Cr, Cr.sub.2 O.sub.3, NiO, and Fe and the oxygen electrode and thermocouple are secured in the face of the sensor by resin-sand to reduce initial overshoot and failure due to thermal shock.

    摘要翻译： 提供了一种用于熔融金属的可膨胀浸入式氧传感器，其具有包括Cr，Cr 2 O 3，NiO和Fe的改进的氧参比电极，并且氧电极和热电偶通过树脂砂固定在传感器的表面以减少初始过冲和故障 热冲击。

    Solid electrolyte probe for determining the oxygen content of molten materials
    10.
    发明授权
    Solid electrolyte probe for determining the oxygen content of molten materials 失效
    固体电解质探针，用于测定材料的含氧量

    公开(公告)号：US3642599A

    公开(公告)日：1972-02-15

    申请号：US3642599D

    申请日：1969-05-12

    申请人： KENNECOTT COPPER CORP

    发明人： FRANZ HENRY W

    IPC分类号： G01N27/30 ,  G01N27/407 ,  G01N27/411 ,  G01N33/20

    CPC分类号： G01N27/4117 ,  G01N27/4118

    摘要： A solid electrolyte probe for direct immersion into a molten material, such as molten copper, to determine the oxygen content thereof. A tubular receptacle fabricated from a solid electrolyte, such as stabilized zirconia, and adapted to hold an oxygen-containing material, has its open upper end protectively closed by a vertically elongate, relatively massive, refractory cap which has a longitudinal passage therethrough to accommodate the electrical lead for the probe electrode and is long enough to protect the tubular receptacle against both unrepresentative, high-oxygen molten material and the molten material-air interface, and to protect both the tubular receptacle and the electrical conductor against splash of the molten material that could otherwise lead to short circuiting of the electrical signals.

    摘要翻译： 一种固体电解质探针，用于直接浸入诸如熔融铜的熔融材料中，以确定其含氧量。 由固体电解质（例如稳定的氧化锆）制成并且适于保持含氧材料的管状容器具有通过垂直细长的相对大块的耐火盖保护性地闭合的敞开的上端，其具有穿过其中的纵向通道以适应 用于探针电极的电引线并且足够长以保护管状插座免受代表性不高的高氧熔融材料和熔融材料 - 空气界面的影响，并且保护管状插座和电导体免受熔融材料飞溅， 否则可能导致电信号短路。