Mark-forming record material
    1.
    发明授权
    Mark-forming record material 失效
    标记记录材料

    公开(公告)号:US3663256A

    公开(公告)日:1972-05-16

    申请号:US3663256D

    申请日:1969-05-26

    申请人: NCR CO

    摘要: This disclosure is directed to mark-forming record material containing two essential color-forming reactants which produce color upon contact with one another in the presence of a mutual liquid solvent wherein (A) one of said color-forming reactants is a phenolic resin containing at least 70 percent, by weight, of oil-soluble, amorphous, free-hydroxy-group-containing, roomtemperature-solid, thermoplastic polymeric condensates of formaldehyde and at least one p-substituted phenol of which at least 10 percent, by weight, is a p-substituted phenol wherein the p-substituent is electron-attracting (for example, a p-halosubstituent), said polymeric condensates containing at least three p-substituted phenol units per molecule, and wherein (B) the other essential color-forming reactant is a basic chromogenic material; for example, Crystal Violet Lactone. The polymeric condensates of (A) may be a mixture of polymer chains, each polymer chain having three or more of the same or different recurring p-substituted phenol units per molecule with methylene bridges between adjacent p-substituted phenol units. Where the polymer resin of (A) is not entirely composed of condensates having recurring phenolic units bearing p-electron-attracting substituents, the remaining recurring phenolic units bear pelectron-donating substituents; for example, p-alkyl substituents. A preferred form of mark-forming record material combines in the same polymeric resin, either in the same molecule or in a mixture of molecules, phenolic units bearing electron-attracting and donating substituents; for example, a phenolic resin having phalo groups as the electron-attracting substituents and p-alkyl groups as the electron donor substituents. By so blending electron-attracting and -donating groups, a ''''balanced'''' condensate (or mixture of condensates) having improved properties as a record material is achieved.

    摘要翻译: 本公开涉及标记形成记录材料,其含有两种必需成色反应物,其在相互液体溶剂存在下彼此接触时产生颜色,其中(A)一种所述着色反应物是含有 至少70重量%的含有至少10重量%的甲醛和至少一种对取代的苯酚的油溶性无定形含游离羟基的室温固体热塑性聚合物缩合物 是对位取代的苯酚,其中p取代基是吸电子的(例如,对卤代基取代基),所述聚合物缩合物每分子含有至少三个对取代的苯酚单元,并且其中(B)另一个 基本成色反应物是基本的显色材料; 例如,结晶紫内酯。 (A)的聚合物缩合物可以是聚合物链的混合物,每个聚合物链每分子具有三个或更多个相同或不同的重复的取代的苯酚单元,在相邻的取代的酚单元之间具有亚甲基桥。 当(A)的聚合物树脂不完全由具有带有p电子吸引取代基的重复酚单元的缩合物构成时,剩余的重复酚单元具有p-电子给予取代基; 例如,对烷基取代基。

    Resin coated sand composition and method of producing same
    5.
    发明授权
    Resin coated sand composition and method of producing same 失效
    树脂涂层砂组合物及其制备方法

    公开(公告)号:US4460717A

    公开(公告)日:1984-07-17

    申请号:US504912

    申请日:1983-06-16

    摘要: A resin coated sand for shell-molding foundry operations having improved shake-out properties for molds prepared therefrom is disclosed. Also disclosed are methods of producing said sand. The foundry aggregates or sand are coated with a phenolic resin containing from 0.2 to 40 parts of an aromatic nitro compound per 100 parts of phenolic resin. The resin may be a novolac type, a resole type or a mixture of the two types of phenolic resins. Suggested aromatic nitro compounds are nitrophenols, dinitrophenols and nitronaphthalenes. The process is extremely useful for coating lower melting temperature metals such as aluminum and magnesium.

    摘要翻译: 公开了一种用于壳模铸造操作的树脂涂层砂,其具有改进的模具的脱模性能。 还公开了生产所述砂的方法。 用每100份酚醛树脂含有0.2至40份芳族硝基化合物的酚醛树脂涂覆铸造聚集体或砂。 树脂可以是酚醛清漆型,酚醛树脂型或两种类型的酚醛树脂的混合物。 建议的芳族硝基化合物是硝基酚,二硝基苯酚和硝基萘。 该方法对于涂覆较低熔点的金属如铝和镁非常有用。

    Aromatic aldehyde resins and their use as emulsion breakers
    10.
    发明申请
    Aromatic aldehyde resins and their use as emulsion breakers 有权
    芳香醛树脂及其用作乳液破乳剂

    公开(公告)号:US20020156136A1

    公开(公告)日:2002-10-24

    申请号:US10144951

    申请日:2002-05-14

    IPC分类号: C09K003/00

    摘要: The present invention relates to resins obtainable from compounds of the formula 1 1 In which X is nullOH, nullNHR1, nullCOOH or nullCONHR2, in which R1 is H, C1-C30-alkyl C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl or nullCOR2 R2 is H, C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl, Y is in the ortho, meta or para position relative to X, and is a radical of the formulae 2 to 5nullOnullR3nullnull(2) 2 nullin which R3 is H, C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl R4 is nullOR3, nullNR6R7 or nullR5 R5 is C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl R6 has the same meaning as given for R3, or is nullCOR3, but is independent of R3, R7 has the same meaning as given for R3, or is nullCOR3, but is independent of R3, where, for the case X, YnullCOOH in the ortho position, the corresponding acid anhydride is also included, by the steps, which can be carried out in any order, of A) reaction with an aldehyde of the formula 6R8nullCHOnullnull(6),nullwhere R8 is H, C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl, and B) alkoxylation with a C2-C4-alkylene oxide in molar excess, such that the resulting alkoxylate has a degree of alkoxylation of from 1 to 100 alkylene oxide units per-OH or-NH group, and the resin has a molecular mass of from 250 to 100,000 units, with the proviso that X and Y are not OH at the same time, and to their use as emulsion breakers.

    摘要翻译: 本发明涉及可由式1化合物获得的树脂,其中X是-OH,-NHR 1,-COOH或-CONHR 2,其中R 1是H,C 1 -C 30 - 烷基C 2 -C 30烯基,C 6 -C 16 - 芳基,C 7 -C 30 - 烷基芳基或-COR 2 R 2是H,C 1 -C 30 - 烷基,C 2 -C 30 - 烯基,C 6 -C 16 - 芳基,C 7 -C 30 - 烷基芳基,Y相对于邻位,间位或对位 X,并且是式2至5的部分,其中R 3是H,C 1 -C 4烷基, C30-烷基,C2-C30-烯基,C6-C16-芳基,C7-C30-烷基芳基R4是-OR3,-NR6R7或-R5R5是C1-C30-烷基,C2-C30-烯基,C6-C16-芳基 ,C 7 -C 30 - 烷基芳基R 6具有与R 3相同的含义,或者是-COR 3,但与R 3不相同,R 7具有与R 3相同的含义,或者是-COR 3,但与R 3无关, 对于情况X,在邻位的Y = COOH,也包括相应的酸酐,通过以下步骤可以以任何顺序进行:A)与式6的醛反应(段落lvl =“ 0“> R8-CHO(6),其中R8是H,C1-C30 - 烷基,C2-C30-烯基,C6-C16 -