摘要:
This disclosure is directed to mark-forming record material containing two essential color-forming reactants which produce color upon contact with one another in the presence of a mutual liquid solvent wherein (A) one of said color-forming reactants is a phenolic resin containing at least 70 percent, by weight, of oil-soluble, amorphous, free-hydroxy-group-containing, roomtemperature-solid, thermoplastic polymeric condensates of formaldehyde and at least one p-substituted phenol of which at least 10 percent, by weight, is a p-substituted phenol wherein the p-substituent is electron-attracting (for example, a p-halosubstituent), said polymeric condensates containing at least three p-substituted phenol units per molecule, and wherein (B) the other essential color-forming reactant is a basic chromogenic material; for example, Crystal Violet Lactone. The polymeric condensates of (A) may be a mixture of polymer chains, each polymer chain having three or more of the same or different recurring p-substituted phenol units per molecule with methylene bridges between adjacent p-substituted phenol units. Where the polymer resin of (A) is not entirely composed of condensates having recurring phenolic units bearing p-electron-attracting substituents, the remaining recurring phenolic units bear pelectron-donating substituents; for example, p-alkyl substituents. A preferred form of mark-forming record material combines in the same polymeric resin, either in the same molecule or in a mixture of molecules, phenolic units bearing electron-attracting and donating substituents; for example, a phenolic resin having phalo groups as the electron-attracting substituents and p-alkyl groups as the electron donor substituents. By so blending electron-attracting and -donating groups, a ''''balanced'''' condensate (or mixture of condensates) having improved properties as a record material is achieved.
摘要:
Polymers are formed by the condensation of bis(hydroxycarbyl)-aminophenolic compounds with aldehydes. The condensation polymers include one or more repeat units having bis(hydroxycarbyl)amino functionality. The polymers are useful as antifoulants, antipolymerants, rheology modifiers, dehazers, polymerization retardants, surfactants, or a combination of these in one or more industrial process streams.
摘要:
The present invention relates to resins obtained by reacting a compound of formula 1 with an aldehyde and alkoxylating, in any order: wherein X is —OH, Y is ortho-, meta- or para- to X and is a radical of formula 4, wherein R5 is a C1-C30-alkyl, C2-C30-alkenyl, C6-C18-aryl, or C7-C30-alkylaryl. The resin has a molecular mass from 250 to 100,000 and is useful in methods of breaking oil-water emulsions.
摘要:
A resin coated sand for shell-molding foundry operations having improved shake-out properties for molds prepared therefrom is disclosed. Also disclosed are methods of producing said sand. The foundry aggregates or sand are coated with a phenolic resin containing from 0.2 to 40 parts of an aromatic nitro compound per 100 parts of phenolic resin. The resin may be a novolac type, a resole type or a mixture of the two types of phenolic resins. Suggested aromatic nitro compounds are nitrophenols, dinitrophenols and nitronaphthalenes. The process is extremely useful for coating lower melting temperature metals such as aluminum and magnesium.
摘要:
Disclosed herein are polymers formed by the condensation of bis(hydroxycarbyl)-aminophenolic compounds with aldehydes. The condensation polymers include one or more repeat units having bis(hydroxycarbyl)amino functionality. The polymers are useful as antifoulants, antipolymerants, rheology modifiers, dehazers, polymerization retardants, surfactants, or a combination of these in one or more industrial process streams.
摘要:
The present disclosure generally relates to nonylphenol-free alkoxylated 4-(alkyloxy)phenol/aldehyde resins and processes for making alkoxylated 4-(alkyloxy)phenol/aldehyde resins. The disclosure also relates to methods of breaking emulsions of oil and water comprising the dosing of an effective amount of an emulsion breaker composition into a stable emulsion to destabilize the emulsion, wherein the emulsion breaker composition comprises an alkoxylated 4-(alkyloxy)phenol/aldehyde resin.
摘要:
A phenolic chelate resin having a high heavy-metal chelating ability and capable of being reused is produced by polycondensing a phenol containing an iminodiacetic acid group with an aldehyde.
摘要:
Disclosed herein are polymers formed by the condensation of bis(hydroxycarbyl)-aminophenolic compounds with aldehydes. The condensation polymers include one or more repeat units having bis(hydroxycarbyl)amino functionality. The hydroxyl groups of the bis(hydroxycarbyl)amino functionalities are available for further condensation with an epoxide, such as ethylene oxide, to yield a polyalkoxylated polymer. The polymers are useful as antipolymerants, polymerization retardants, surfactants, or a combination of these in one or more industrial systems.
摘要:
The present invention relates to resins obtainable from compounds of the formula 1 1 In which X is nullOH, nullNHR1, nullCOOH or nullCONHR2, in which R1 is H, C1-C30-alkyl C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl or nullCOR2 R2 is H, C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl, Y is in the ortho, meta or para position relative to X, and is a radical of the formulae 2 to 5nullOnullR3nullnull(2) 2 nullin which R3 is H, C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl R4 is nullOR3, nullNR6R7 or nullR5 R5 is C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl R6 has the same meaning as given for R3, or is nullCOR3, but is independent of R3, R7 has the same meaning as given for R3, or is nullCOR3, but is independent of R3, where, for the case X, YnullCOOH in the ortho position, the corresponding acid anhydride is also included, by the steps, which can be carried out in any order, of A) reaction with an aldehyde of the formula 6R8nullCHOnullnull(6),nullwhere R8 is H, C1-C30-alkyl, C2-C30-alkenyl, C6-C16-aryl, C7-C30-alkylaryl, and B) alkoxylation with a C2-C4-alkylene oxide in molar excess, such that the resulting alkoxylate has a degree of alkoxylation of from 1 to 100 alkylene oxide units per-OH or-NH group, and the resin has a molecular mass of from 250 to 100,000 units, with the proviso that X and Y are not OH at the same time, and to their use as emulsion breakers.