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    Polyester resin, a method of preparing the polyester resin, and a coating composition thereof
    2.
    发明申请
    Polyester resin, a method of preparing the polyester resin, and a coating composition thereof 审中-公开
    聚酯树脂，聚酯树脂的制备方法及其涂料组合物

    公开(公告)号：US20040171748A1

    公开(公告)日：2004-09-02

    申请号：US10793529

    申请日：2004-03-04

    发明人： Swaminathan Ramesh ,  Marvin L. Green

    IPC分类号： C08K003/00

    CPC分类号： C09D167/00 ,  B01F17/005 ,  C01P2004/61 ,  C01P2006/22 ,  C08G63/20 ,  C08G63/42 ,  C08G63/58 ,  C08G63/6854 ,  C08G63/78 ,  C08G63/914 ,  C08L61/32 ,  C09B67/009 ,  C09C1/3676 ,  C09C3/08 ,  C09C3/10 ,  C08L2666/16

    摘要： A polyester resin is the reaction product of plurality of a first compound and a plurality of a carboxylic acid anhydride. The first compound has hydroxyl groups. The carboxylic acid anhydrides react with the hydroxyl groups of the first compounds to form a plurality of first intermediate compounds. These first intermediate compounds have at least one hydroxyl group and carboxylic acid groups. A temperature of the first intermediate compounds is increased until the hydroxyl group of one first intermediate compound condenses with one of the carboxylic acid groups of another first intermediate compound. This condensing, or condensation, forms the polyester resin having an ester linkage and carboxylic acid groups. A second compound having at least one epoxy group and a carbamate compound can be subsequently reacted with the polyester resin. A coating composition includes the polyester resin and a cross-linking agent reactive with the polyester resin.

    摘要翻译： 聚酯树脂是多个第一化合物和多个羧酸酐的反应产物。 第一种化合物具有羟基。 羧酸酐与第一化合物的羟基反应形成多个第一中间体化合物。 这些第一中间体化合物具有至少一个羟基和羧酸基团。 第一中间体化合物的温度升高，直到一个第一中间体化合物的羟基与另一个第一中间体化合物的一个羧酸基团缩合。 这种冷凝或冷凝形成具有酯键和羧酸基团的聚酯树脂。 可以随后与聚酯树脂反应具有至少一个环氧基和氨基甲酸酯化合物的第二化合物。 涂料组合物包括聚酯树脂和与聚酯树脂反应的交联剂。

    Low molecular weight hydroxy functional polyesters for coatings
    4.
    发明授权
    Low molecular weight hydroxy functional polyesters for coatings 失效
    用于涂料的低分子量羟基官能聚酯

    公开(公告)号：US5852162A

    公开(公告)日：1998-12-22

    申请号：US883984

    申请日：1997-06-27

    申请人： Marc L. Smith ,  Ronald J. Lewarchik ,  Joseph J. Zupancic ,  Donald J. Algrim

    发明人： Marc L. Smith ,  Ronald J. Lewarchik ,  Joseph J. Zupancic ,  Donald J. Algrim

    IPC分类号： C08G63/52 ,  C08G63/58 ,  C08G63/02

    CPC分类号： C08G63/58 ,  C08G63/52

    摘要： A polyester composition has a number average molecular weight M.sub.n of between about 500 and about 1000, a weight average molecular weight M.sub.w of between about 600 and about 2000, a polydispersity below about 2, preferably below about 1.8, hydroxyl functionality between 2 and 3, a hydroxyl value of between about 160 and about 260, and an acid number below about 10. Less than about 5% of the OH groups of the polyester are pendent, the rest being terminal. Between about 10 and about 50 wt % of the monomers used to form the polyester composition are anhydrides having the formula: ##STR1## where R.sup.1 is a non-aromatic, saturated or unsaturated hydrocarbon chain having between 6 and 30 carbon atoms, R.sup.2 is hydrogen or a non-aromatic saturated or unsaturated hydrocarbon having between 1 and 8 carbon atoms, and R.sup.1 and R.sup.2 have, in total, between 8 and 30 carbon atoms. The polyester in conjunction with a hydroxyl-reactive curative provides a coating composition.

    摘要翻译： 聚酯组合物的数均分子量Mn为约500至约1000，重均分子量Mw为约600至约2000，多分散度低于约2，优选低于约1.8，羟基官能度为2至3， 约160至约260的羟基值，低于约10的酸值。少于约5％的聚酯的OH基团是侧面的，其余的是末端。 用于形成聚酯组合物的单体约10至约50重量％是具有下式的酸酐：其中R 1是具有6至30个碳原子的非芳族，饱和或不饱和的烃链， R2是氢或具有1至8个碳原子的非芳族饱和或不饱和烃，R1和R2总共具有8至30个碳原子。 聚酯与羟基反应性固化剂结合提供涂料组合物。

    Photosensitive compositions
    6.
    发明授权
    Photosensitive compositions 失效
    感光组合物

    公开(公告)号：US5487966A

    公开(公告)日：1996-01-30

    申请号：US231953

    申请日：1994-04-21

    申请人： Bettina Steinmann ,  Adrian Schulthess ,  Max Hunziker

    发明人： Bettina Steinmann ,  Adrian Schulthess ,  Max Hunziker

    IPC分类号： C08G63/00 ,  B29C67/00 ,  C08G63/52 ,  C08G63/58 ,  C08J5/00 ,  G03F7/00 ,  G03F7/027 ,  G03F7/029 ,  G03F7/032 ,  G03C5/00 ,  G03C1/492 ,  G03C1/725

    CPC分类号： C08G63/52 ,  C08G63/58 ,  G03F7/0037 ,  G03F7/032

    摘要： Photosensitive compositions comprisinga) 5-95% by weight of a polyester of formula I, II or III ##STR1## wherein R.sub.1 is the radical of a cyclic anhydride of a dicarboxylic acid after removal of the --O--CO--O-- grouping, which radical may be substituted by C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.6 -C.sub.10 aryl, halogen or C.sub.1 -C.sub.22 alkyl which is interrupted by --O-- or --CO--O--,R.sub.2 is hydrogen, unsubstituted or halogen-substituted C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.7 -C.sub.22 aralkyl, C.sub.6 -C.sub.10 aryl or a radical --CH.sub.2 --O--R.sub.5 or --CH.sub.2 --O--CO--R.sub.5, wherein R.sub.5 is C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.6 cycloalkyl or C.sub.6 -C.sub.10 aryl,R.sub.3 is hydrogen, orR.sub.2 and R.sub.3, together with the linking carbon atoms, are a cyclopentylene or cyclohexylene radical,R.sub.4 is a radical of 4 to 12 carbon atoms which carries an unsaturated end group and carboxyl or ether groups,A is a mono- or polyfunctional low molecular or high molecular carboxylate or alcoholate,x is an integer from 0-100,n is an integer from 2-150, andz is an integer from 1-4,b) 10-90% by weight of a liquid polyfunctional aliphatic, cycloaliphatic or aromatic (meth)acrylate,c) 0-70% of a mono(meth)acrylate or mono-N-vinyl compound with a molecular weight of not more than 500,d) 0.1-10% by weight of a photoinitiator, ande) 0-10% by weight of optional customary additives.

    摘要翻译： 包含a）5-95重量％的式I，II或III的聚酯的方法，其中R 1是基团（R 1） 的C 1 -C 22烷基，C 5 -C 10环烷基，C 3 -C 6烯基，C 6 -C 10芳基，卤素或C 1 -C 22烷基取代的-O-CO-O-基团后的二羧酸的环状酸酐，其为 被-O-或-CO-O-中断，R 2是氢，未取代的或被卤素取代的C 1 -C 22烷基，C 5 -C 10环烷基，C 7 -C 22烷基，C 6 -C 10芳基或基团-CH 2 -O-R 5或-CH 2 -O -CO-R 5，其中R 5是C 1 -C 22烷基，C 5 -C 6环烷基或C 6 -C 10芳基，R 3是氢，或者R 2和R 3与连接碳原子一起是亚环戊基或亚环己基，R4是4- 带有不饱和端基和羧基或醚基团的12个碳原子，A是单官能或多官能低分子或高分子量羧酸盐或醇化物，x是0-100的整数，n是2-150的整数， dz是1-4的整数，b）10-90重量％的液体多官能脂族，脂环族或芳族（甲基）丙烯酸酯，c）0-70％的单（甲基）丙烯酸酯或单-N-乙烯基 分子量不超过500的化合物，d）0.1-10重量％的光引发剂，和e）0-10重量％的任选的常规添加剂。

    Narrow molecular weight polyester oligomers and method of preparation
    8.
    发明授权
    Narrow molecular weight polyester oligomers and method of preparation 失效
    窄分子量聚酯低聚物及其制备方法

    公开(公告)号：US4659778A

    公开(公告)日：1987-04-21

    申请号：US854105

    申请日：1986-04-21

    申请人： Roy C. Williams

    发明人： Roy C. Williams

    IPC分类号： C08G63/12 ,  C08G63/16 ,  C08G63/42 ,  C08G63/58 ,  C09D167/00 ,  C08F8/00 ,  C08L63/00

    CPC分类号： C08G63/58 ,  C08G63/16 ,  C08G63/42

    摘要： A polyester composition having an average molecular weight of greater than 500 comprising a most prevalent compound having a main polyester chain containing at least 17 and fewer than 52 carbon atoms and at least 6 and fewer than 18 oxygen atoms, at least 52 weight percent of the molecules of said composition having a molecular weight within 50% of the average molecular weight of the composition. The polyester composition desirably contains at least 1.6 equivalents of unreacted hydroxy groups or at least 1.6 equivalents of unreacted carboxy groups per mole. The composition contains at least four equivalents of ester links in the main chains of the molecules per mole.The composition of the present invention is obtained by the method of the invention wherein alternating series of reactions are each driven essentially to completion where the final molecule of each reaction provides the only available reaction site for the next alternate monomer reaction. The reactions used are the reaction of an anhydride with a hydroxyl to give an ester and a carboxyl group and the reaction of an oxirane group with a carboxyl to give an ester and a hydroxyl group. To start the alternating reaction sequence either a polyol (to react with anhydride) or a polycarboxylic acid (to react with an oxirane) is used.

    摘要翻译： 平均分子量大于500的聚酯组合物，其包含具有至少17个且少于52个碳原子和至少6个且少于18个氧原子的主聚酯链的最普遍的化合物，至少52重量％的 所述组合物的分子的分子量在组合物的平均分子量的50％以内。 聚酯组合物理想地每摩尔含有至少1.6当量的未反应羟基或至少1.6当量的未反应羧基。 组合物在每分子的主链中含有至少四当量的酯键。 本发明的组合物通过本发明的方法获得，其中交替的一系列反应各自被驱动到完全，其中每个反应的最终分子为下一次备选的单体反应提供唯一可用的反应位点。 使用的反应是酸酐与羟基反应得到酯和羧基，以及环氧乙烷基团与羧基的反应，得到酯和羟基。 为了开始交替的反应顺序，可以使用多元醇（与酸酐反应）或多元羧酸（与环氧乙烷反应）。

    Polyester process
    10.
    发明授权
    Polyester process 失效
    聚酯工艺

    公开(公告)号：US4116944A

    公开(公告)日：1978-09-26

    申请号：US874309

    申请日：1978-02-02

    申请人： James C. Hill ,  Walter R. Knox

    发明人： James C. Hill ,  Walter R. Knox

    IPC分类号： C08G63/00 ,  C08G63/42 ,  C08G63/52 ,  C08G63/58 ,  C08F18/14

    CPC分类号： C08G63/58 ,  C08G63/42

    摘要： The present invention provides a process for the production of a polyester having an acid number which is not greater than 65 which comprises reacting an acid anhydride with a monoterminal epoxide in the presence of a solvent for the polyester in such a way that a self-sustaining reaction is initiated within 200 seconds of the reactants being mixed together and said reaction results in the attainment of a maximum peak temperature within 200 seconds of initiation.

    摘要翻译： 本发明提供一种生产酸值不大于65的聚酯的方法，该方法包括使酸酐与单末端环氧化物反应，使得在反应物的200秒内开始自持反应 混合在一起，所述反应在200秒内达到最高温度超过200℃。