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    Silane-modified dispersion powders
    4.
    发明授权
    Silane-modified dispersion powders 失效
    硅烷改性分散体粉末

    公开(公告)号：US08470120B2

    公开(公告)日：2013-06-25

    申请号：US12091145

    申请日：2006-10-13

    申请人： Marion Killat ,  Stefan Killat

    发明人： Marion Killat ,  Stefan Killat

    IPC分类号： C04B37/00 ,  B32B27/00 ,  B60C1/00 ,  C08K5/24 ,  C08K5/54 ,  H01B3/44

    CPC分类号： C08F8/42 ,  C04B24/2641 ,  C04B24/42 ,  C04B28/02 ,  C04B28/14 ,  C04B28/26 ,  C04B2103/0057 ,  C04B2111/00146 ,  C04B2111/00672 ,  C04B2111/00724 ,  C08F2/18 ,  C08F2/22 ,  C08F6/006 ,  C08K5/54 ,  C04B14/06 ,  C04B24/383 ,  C08F18/08

    摘要： Water-redispersible polymer powder compositions are obtained by means of free-radical-initiated polymerization in aqueous medium of one or more monomers of vinyl esters of unbranched or branched alkylcarboxylic acids having from 1 to 15 carbon atoms, methacrylic esters and acrylic esters of alcohols having from 1 to 15 carbon atoms, vinylaromatics, olefins, dienes and vinyl halides and subsequent drying of the polymer dispersion, wherein one or more silanes of the general formula (RO)3−nR1nSiR2X (1) where X is an amino- or epoxy-containing radical are added before drying of the polymer dispersion. The powders are especially useful in tile adhesives for tiles having low water absorbtion capacity.

    摘要翻译： 水可再分散聚合物粉末组合物通过在具有1至15个碳原子的无支链或支链烷基羧酸的乙烯基酯的一种或多种单体的水性介质中的自由基引发聚合获得，甲基丙烯酸酯和醇的丙烯酸酯具有 1至15个碳原子，乙烯基芳烃，烯烃，二烯和乙烯基卤化物，随后干燥聚合物分散体，其中一个或多个通式（RO）3-nR1nSiR2X（1）的硅烷，其中X是氨基或环氧基 - 在聚合物分散体干燥之前加入含有自由基。 该粉末特别适用于具有低吸水能力的瓷砖的瓷砖粘合剂。

    Process For Producing Polyvinyl Alcohol Or A Copolymer Thereof
    5.
    发明申请
    Process For Producing Polyvinyl Alcohol Or A Copolymer Thereof 失效
    生产聚乙烯醇或其共聚物的方法

    公开(公告)号：US20130137820A1

    公开(公告)日：2013-05-30

    申请号：US13305203

    申请日：2011-11-28

    申请人： Mark O. Scates

    发明人： Mark O. Scates

    IPC分类号： C08F16/06

    CPC分类号： C08F16/06 ,  C08F8/12 ,  C08F18/08

    摘要： Acetic acid is converted to vinyl acetate monomer by a reaction with oxygen and ethylene. The vinyl acetate is polymerized to form a vinyl acetate polymer or copolymer, which is then reacted in a methanolysis reaction with methanol and base to form a polymer or copolymer of vinyl alcohol and a methyl acetate byproduct. Ethanol is produced from methyl acetate by a hydrogenolysis reaction. The hydrogenolysis reaction also produces methanol. At least a portion of this ethanol is converted to ethylene by a dehydration reaction. At least a portion of the ethylene produced in this dehydration reaction is recycled to react with acetic acid and oxygen to form vinyl acetate. By converting a byproduct and by recycle of compositions, a polymer or copolymer of vinyl alcohol is efficiently produced with minimal waste.

    摘要翻译： 乙酸通过与氧和乙烯的反应转化为乙酸乙烯酯单体。 乙酸乙烯酯聚合形成乙酸乙烯酯聚合物或共聚物，然后在甲醇分解反应中与甲醇和碱反应形成乙烯醇和乙酸甲酯副产物的聚合物或共聚物。 通过氢解反应由乙酸甲酯生产乙醇。 氢解反应也产生甲醇。 通过脱水反应将至少一部分该乙醇转化为乙烯。 在该脱水反应中产生的乙烯的至少一部分被再循环以与乙酸和氧反应以形成乙酸乙烯酯。 通过转化副产物和通过组合物的再循环，乙烯醇的聚合物或共聚物可有效地以最少的浪费产生。

    Polyvinyl Acetate Solid Resins Functionalised with Acid Groups
    8.
    发明申请
    Polyvinyl Acetate Solid Resins Functionalised with Acid Groups 审中-公开
    聚乙酸乙烯酯固体树脂与酸组官能化

    公开(公告)号：US20070265394A1

    公开(公告)日：2007-11-15

    申请号：US11570606

    申请日：2005-06-23

    申请人： Rene Grawe ,  Andreas Lumpp

    发明人： Rene Grawe ,  Andreas Lumpp

    IPC分类号： C08L53/00

    CPC分类号： C08F218/08 ,  C08F8/00 ,  C08F220/04 ,  C08F18/08

    摘要： Solid polyvinyl acetate resins functionalized by acid groups which also contain terminal carboxy groups besides carboxy-functional comonomer units display superior properties as low profile additives for unsaturated polyester resins.

    摘要翻译： 除了羧基官能的共聚单体单元之外，还含有末端羧基的酸基官能化的固体聚乙酸乙烯酯树脂表现出作为不饱和聚酯树脂的低轮廓添加剂的优异性能。

    Method for preparing a water-containing vinyl acetate polymer dispersion, dispersion thus prepared and protective colloid used thereby
    9.
    发明授权
    Method for preparing a water-containing vinyl acetate polymer dispersion, dispersion thus prepared and protective colloid used thereby 失效
    制备含水乙酸乙烯酯聚合物分散体的方法，由此制备的分散体和由此使用的保护胶体

    公开(公告)号：US4322322A

    公开(公告)日：1982-03-30

    申请号：US161360

    申请日：1980-06-20

    申请人： Peter F. T. Lambrechts ,  Jozef H. R. Van Der Meeren

    发明人： Peter F. T. Lambrechts ,  Jozef H. R. Van Der Meeren

    IPC分类号： C08F2/22 ,  C08F18/08 ,  C08L3/04

    CPC分类号： C08F18/08

    摘要： For preparing a water-containing vinyl acetate polymer dispersion, vinyl acetate monomer and initiator are added to a water solution from an emulsifier and hydroxypropyl starch and/or hydroxyethyl starch. The emulsifier amount is equal to 0,5 to 5 weight % from the monomer amount. The degree of substitution of the starch is higher than 0,8 substituted glucose hydroxyl groups per anhydroglucose unit and lies more specially between 0,8 and 1,8 substituted glucose hydroxyl groups per anhydroglucose unit, when the starch is hydroxypropyl starch or between 0,8 and 2,75 substituted glucose hydroxyl groups per anhydroglucose unit, when the starch is hydroxyethyl starch.

    摘要翻译： 为了制备含水乙酸乙烯酯聚合物分散体，将乙酸乙烯酯单体和引发剂加入到来自乳化剂和羟丙基淀粉和/或羟乙基淀粉的水溶液中。 乳化剂量等于单体量的0.5-5重量％。 当淀粉为羟丙基淀粉时，淀粉的羟基取代度高于每个脱水葡萄糖单元的0,8取代葡萄糖羟基，更特别地是每个脱水葡萄糖单元在0.8和18个取代的葡萄糖羟基之间， 当淀粉为羟乙基淀粉时，每个脱水葡萄糖单元取代葡萄糖羟基8和2,75。