公开(公告)号：US3065126A

公开(公告)日：1962-11-20

申请号：US1583960

申请日：1960-03-18

Applicant: MONSANTO CHEMICALS

Inventor： NEWALLIS PETER E ,  BAKER JOSEPH W ,  CHUPP JOHN P

IPC: C07F9/24 ,  C07F9/32

CPC classification number: C07F9/245 ,  C07F9/3247

公开(公告)号：US20100305336A1

公开(公告)日：2010-12-02

申请号：US12744966

申请日：2008-11-27

Applicant: Johan Loccufier

Inventor： Johan Loccufier

IPC: C07D335/16 ,  C07C69/63 ,  C07C69/54 ,  C07C67/30 ,  C07F9/32

CPC classification number: C07C69/63 ,  C07C67/14 ,  C07C67/317 ,  C07C69/54 ,  C07D335/16 ,  C07F9/3247 ,  C07F9/5337

Abstract: An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group including at least one photoinitiating moiety; L represents a n+o-valent linking group including at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to 0 or 1; X represents a group selected from the group consisting of Cl, Br, I, and R2SO3; and R2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group-, an aralkyl group, an aryl group and a heteroaryl group. Also, a method for the preparation of (meth)acrylated photoinitiators by β-elimination of HX from the intermediate according to Formula (I).

Abstract translation: 用于制备根据式（I）的（甲基）丙烯酸酯化光引发剂的中间体：其中：R1选自氢和甲基; A表示包含至少一个光引发部分的基团; L表示包含至少一个碳原子的n + O价连接基团; n和o各自独立地表示1至4的整数; p等于0或1; X表示选自Cl，Br，I和R 2 SO 3的基团; 并且R 2表示选自烷基，烯基，炔基，烷芳基 - ，芳烷基，芳基和杂芳基中的任选取代的基团。 另外，通过根据式（I）的中间体将HX还原并制备（甲基）丙烯酸酯化光引发剂的方法。

公开(公告)号：US20090105361A1

公开(公告)日：2009-04-23

申请号：US12225070

申请日：2006-03-13

Applicant: Kunio Ikemura ,  Kensuke Ichizawa ,  Yoshiyuki Jogetsu

Inventor： Kunio Ikemura ,  Kensuke Ichizawa ,  Yoshiyuki Jogetsu

IPC: C08F2/46 ,  C07F9/28

CPC classification number: C08F2/50 ,  A61K6/0052 ,  A61K6/083 ,  C07F9/307 ,  C07F9/3247 ,  C07F9/5337 ,  C08L33/00

Abstract: A compound that exhibits excellent color tone stability and physical properties as well as excellent photopolymerization activity over a wide region from near-ultraviolet to visible region, permitting relaxed operation under ambient light, so that wide application can be found in the dental field and photopolymerization industry; and a relevant photopolymerization initiator and hardenable composition. In particular, there is provided a novel camphorquinone derivative having an acylphosphine oxide group [—(C═O)—(P═O)

Abstract translation: 具有优异的色调稳定性和物理性能以及在从近紫外到可见光区域的广泛区域的优异的光聚合活性的化合物，允许在环境光下轻松操作，从而可以在牙科领域和光聚合行业中广泛应用 ; 和相关的光聚合引发剂和可硬化组合物。 特别地，提供了在每个分子中具有酰基氧化膦基团[ - （C-O） - （P-O）]]的新型樟脑醌衍生物。 此外，提供了包含在每个分子中具有丙烯基氧化膦基团[ - （CO） - （PO）]]的樟脑醌衍生物作为不可或缺的组分的光聚合引发剂，其负载有至少一种选自聚合促进剂， 光致酸产生剂，光敏剂和（双）酰基氧化膦，并提供包含引发剂的可硬化组合物。 由此提供的光聚合引发剂和可硬化组合物在紫外线和可见光波长范围内表现出优异的色调稳定性和物理性能以及优异的光聚合活度，允许在环境光下轻松操作，从而可以在牙科领域和 光聚合行业。

公开(公告)号：US20140024840A1

公开(公告)日：2014-01-23

申请号：US14023494

申请日：2013-09-11

Applicant: Agfa Graphics NV

Inventor： Johan LOCCUFIER

IPC: C07C67/317 ,  C07C69/54 ,  C07D335/16

CPC classification number: C07C69/63 ,  C07C67/14 ,  C07C67/317 ,  C07C69/54 ,  C07D335/16 ,  C07F9/3247 ,  C07F9/5337

Abstract: An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group including at least one photoinitiating moiety; L represents a n+o-valent linking group including at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to 0 or 1; X represents a group selected from the group consisting of Cl, Br, I, and R2SO3; and R2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group, an aralkyl group, an aryl group and a heteroaryl group. Also, a method for the preparation of (meth)acrylated photoinitiators by β-elimination of HX from the intermediate according to Formula (I).

Abstract translation: 用于制备根据式（I）的（甲基）丙烯酸酯化光引发剂的中间体：其中：R1选自氢和甲基; A表示包含至少一个光引发部分的基团; L表示包含至少一个碳原子的n + O价连接基团; n和o各自独立地表示1至4的整数; p等于0或1; X表示选自Cl，Br，I和R 2 SO 3的基团; R2表示选自烷基，烯基，炔基，烷芳基，芳烷基，芳基和杂芳基中的任意取代的基团。 此外，通过根据式（I）的中间体β-去除HX制备（甲基）丙烯酸酯化光引发剂的方法。

公开(公告)号：US07803850B2

公开(公告)日：2010-09-28

申请号：US12225070

申请日：2006-03-13

Applicant: Kunio Ikemura ,  Kensuke Ichizawa ,  Yoshiyuki Jogetsu

Inventor： Kunio Ikemura ,  Kensuke Ichizawa ,  Yoshiyuki Jogetsu

IPC: C08F2/50 ,  C07F9/02

CPC classification number: C08F2/50 ,  A61K6/0052 ,  A61K6/083 ,  C07F9/307 ,  C07F9/3247 ,  C07F9/5337 ,  C08L33/00

Abstract: A compound that exhibits excellent color tone stability and physical properties as well as excellent photopolymerization activity over a wide region from near-ultraviolet to visible region, permitting relaxed operation under ambient light, so that wide application can be found in the dental field and photopolymerization industry; and a relevant photopolymerization initiator and hardenable composition. In particular, there is provided a novel camphorquinone derivative having an acylphosphine oxide group [—(C═O)—(P═O)

Abstract translation: 具有优异的色调稳定性和物理性能以及在从近紫外到可见光区域的广泛区域的优异的光聚合活性的化合物，允许在环境光下轻松操作，从而可以在牙科领域和光聚合行业中广泛应用 ; 和相关的光聚合引发剂和可硬化组合物。 特别地，提供了在每个分子中具有酰基氧化膦基团[ - （C = O） - （P = O）]]的新型樟脑醌衍生物。 另外，提供了包含在每个分子中具有丙烯基氧化膦基团[ - （C = O） - （P = O）]]的樟脑醌衍生物作为不可或缺的成分的光聚合引发剂，其负载有至少一种选自 聚合促进剂，光酸产生剂，光敏剂和（双）酰基氧化膦，并提供包含引发剂的可硬化组合物。 由此提供的光聚合引发剂和可硬化组合物在紫外线和可见光波长范围内表现出优异的色调稳定性和物理性能以及优异的光聚合活度，允许在环境光下轻松操作，从而可以在牙科领域和 光聚合行业。

公开(公告)号：US08791289B2

公开(公告)日：2014-07-29

申请号：US14023494

申请日：2013-09-11

Applicant: Agfa Graphics NV

Inventor： Johan Loccufier

IPC: C07C69/63

CPC classification number: C07C69/63 ,  C07C67/14 ,  C07C67/317 ,  C07C69/54 ,  C07D335/16 ,  C07F9/3247 ,  C07F9/5337

Abstract: An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group including at least one photoinitiating moiety; L represents a n+o-valent linking group including at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to 0 or 1; X represents a group selected from the group consisting of Cl, Br, I, and R2SO3; and R2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group, an aralkyl group, an aryl group and a heteroaryl group. Also, a method for the preparation of (meth)acrylated photoinitiators by β-elimination of HX from the intermediate according to Formula (I).

Abstract translation: 用于制备根据式（I）的（甲基）丙烯酸酯化光引发剂的中间体：其中：R1选自氢和甲基; A表示包含至少一个光引发部分的基团; L表示包含至少一个碳原子的n + O价连接基团; n和o各自独立地表示1至4的整数; p等于0或1; X表示选自Cl，Br，I和R 2 SO 3的基团; R2表示选自烷基，烯基，炔基，烷芳基，芳烷基，芳基和杂芳基中的任意取代的基团。 另外，通过根据式（I）的中间体将HX还原并制备（甲基）丙烯酸酯化光引发剂的方法。

公开(公告)号：US2668823A

公开(公告)日：1954-02-09

申请号：US35023653

申请日：1953-04-21

Applicant: DOW CHEMICAL CO

Inventor： HENRY TOLKMITH

IPC: A01N57/20 ,  C07F9/32 ,  C07F9/42

CPC classification number: A01N57/20 ,  C07F9/3247 ,  C07F9/3294 ,  C07F9/425

公开(公告)号：US08664431B2

公开(公告)日：2014-03-04

申请号：US12744966

申请日：2008-11-27

Applicant: Johan Loccufier

Inventor： Johan Loccufier

IPC: C07C69/63

CPC classification number: C07C69/63 ,  C07C67/14 ,  C07C67/317 ,  C07C69/54 ,  C07D335/16 ,  C07F9/3247 ,  C07F9/5337

Abstract: An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group including at least one photoinitiating moiety; L represents a n+o-valent linking group including at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to 0 or 1; X represents a group selected from the group consisting of CI, Br, I, and R2SO3; and R2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group-, an aralkyl group, an aryl group and a heteroaryl group. Also, a method for the preparation of (meth)acrylated photoinitiators by β-elimination of HX from the intermediate according to Formula (I).

Abstract translation: 用于制备根据式（I）的（甲基）丙烯酸酯化光引发剂的中间体：其中：R1选自氢和甲基; A表示包含至少一个光引发部分的基团; L表示包含至少一个碳原子的n + O价连接基团; n和o各自独立地表示1至4的整数; p等于0或1; X表示选自由Cl，Br，I和R 2 SO 3组成的组中的基团; 并且R 2表示选自烷基，烯基，炔基，烷芳基 - ，芳烷基，芳基和杂芳基中的任选取代的基团。 此外，通过根据式（I）的中间体β-去除HX制备（甲基）丙烯酸酯化光引发剂的方法。

公开(公告)号：US4324744A

公开(公告)日：1982-04-13

申请号：US148221

申请日：1980-05-09

Applicant: Peter Lechtken ,  Ingolf Buethe ,  Anton Hesse

Inventor： Peter Lechtken ,  Ingolf Buethe ,  Anton Hesse

IPC: C08F2/00 ,  C07F9/32 ,  C07F9/40 ,  C07F9/46 ,  C07F9/48 ,  C07F9/53 ,  C07F9/547 ,  C08F2/50 ,  C09D4/00 ,  C09D11/10 ,  G03F7/029 ,  C07F9/30 ,  C07F9/38

CPC classification number: C07F9/4065 ,  C07F9/3247 ,  C07F9/46 ,  C07F9/48 ,  C07F9/5337 ,  G03F7/029

Abstract: Acylphosphine oxide compounds of the general formula ##STR1## where R.sup.1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical,R.sup.2 has one of the meanings of R.sup.1 (but R.sup.1 and R.sup.2 may be identical or different), or is alkoxy, aryloxy or aralkoxy, or R.sup.1 and R.sup.2 together from a ring, andR.sup.3 is straight-chain or branched alkyl of 2 to 18 carbon atoms, a cycloaliphatic radical of 3 to 12 carbon atoms, phenyl or naphthyl which are alkyl-, alkoxy- or thioalkoxy-substituted, or an S-containing or N-containing five-membered or six-membered heterocyclic radical, and may contain additional functional groups, or is the group ##STR2## where R.sup.1 and R.sup.2 have the above meanings and X is phenyl or an aliphatic or cycloaliphatic divalent radical of 2 to 6 carbon atoms,and one or more of the radicals R.sup.1 to R.sup.3 may be olefinically unsaturated, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula ##STR3## where X is chlorine or bromine, and a phosphine of the general formula ##STR4## and the use of the acylphosphine oxides as photoinitiators in photopolymerizable compositions.

Abstract translation: 其中R1是烷基，环己基，环戊基，未被取代或被卤素，烷基或烷氧基取代的芳基，或含S或N的五元或六元杂环基的酰基氧化膦化合物 ，R 2具有R 1的含义（但R 1和R 2可以相同或不同），或者是烷氧基，芳氧基或芳烷氧基，或者R 1和R 2一起来自环，R 3是直链或支链烷基， 具有3至12个碳原子的脂环族基团，烷基 - ，烷氧基 - 或硫代烷氧基取代的苯基或萘基，或含S或N的五元或六元杂环基， 或者是其中R 1和R 2具有上述含义并且X是苯基或2至6个碳原子的脂族或脂环族二价基团的基团，并且基团R 1至R 3中的一个或多个可以是 烯属不饱和的，一种制备t的方法 其中X是氯或溴的通式为“IMAGE”的酰卤的酰基氧化膦化合物，以及通式为“IMAGE”的膦以及可光聚合组合物中酰基氧化膦作为光引发剂的用途。

公开(公告)号：US3621083A

公开(公告)日：1971-11-16

申请号：US3621083D

申请日：1968-04-30

Applicant: STAUFFER CHEMICAL CO

Inventor： PRICE GLENN R

IPC: C07F9/22 ,  C07F9/24 ,  C07F9/32 ,  C07F9/36 ,  C07F9/42 ,  C07F9/44 ,  H01F41/10 ,  C07F9/08 ,  C07F9/16

CPC classification number: C07F9/4492 ,  C07F9/22 ,  C07F9/2487 ,  C07F9/3247 ,  C07F9/36 ,  C07F9/425 ,  H01F41/10

Abstract: A process for preparing organophosphorus compounds of the formula:

R, X, n and n'' are as previously defined and hal is a halogen having an atomic weight between about 30 and 85; with a salt of pseudohalide in the presence of a catalytic amount of a tertiary amine.

R is a radical substantially hydrocarbon in nature but which can contain relatively inert substituents, X is a chalcogen having an atomic weight less than about 35, W is a pseudohalide selected from CN, NCO, and NCS groups, and n and n'' are integers of from one to two, the sum of which is not greater than three. The process comprises reacting an organophosphorus halide of the formula: