公开(公告)号：US3515766A

公开(公告)日：1970-06-02

申请号：US3515766D

申请日：1968-05-21

Applicant: UNIVERSAL OIL PROD CO

Inventor： ROOT WAYNE N ,  UITTI KENNETH D

IPC: C07C5/32 ,  C07C5/333 ,  C07C5/18 ,  C07C15/10

CPC classification number: C07C5/321 ,  C07C5/333 ,  Y10S585/91 ,  C07C15/42 ,  C07C15/46

公开(公告)号：US3474153A

公开(公告)日：1969-10-21

申请号：US3474153D

申请日：1968-07-25

Applicant: UNION CARBIDE CORP

Inventor： HENRY JOSEPH P ,  WILKINSON LOY A

IPC: B01J19/02 ,  C07C5/32 ,  C07C5/18 ,  C07C15/10

CPC classification number: C07C5/32 ,  B01J19/02 ,  B01J2219/0286 ,  C07C5/321 ,  C07C15/42

公开(公告)号：US2993903A

公开(公告)日：1961-07-25

申请号：US81321659

申请日：1959-05-14

Applicant: PHILLIPS PETROLEUM CO

Inventor： GERARD KRAUS

IPC: C07C7/20 ,  C08F2/38

CPC classification number: C07C7/20 ,  C08F2/38 ,  C07C15/42 ,  C07C15/46

公开(公告)号：US2963518A

公开(公告)日：1960-12-06

申请号：US45825554

申请日：1954-09-24

Applicant: DOW CHEMICAL CO

Inventor： AMOS JAMES L ,  SODERQUIST FREDERICK J

IPC: C07C4/20 ,  C07C5/32 ,  C07C5/333

CPC classification number: C07C5/322 ,  C07C4/20 ,  C07C5/3332 ,  C07C2523/04 ,  C07C2523/26 ,  C07C2523/745 ,  C07C15/06 ,  C07C15/04 ,  C07C15/42 ,  C07C15/46

公开(公告)号：US20020183571A1

公开(公告)日：2002-12-05

申请号：US10041422

申请日：2002-01-08

Applicant: Sud-Chemie Inc.

Inventor： David L. Williams ,  Andrzej Rokicki ,  Dennis J. Smith ,  Kyle Mankin

IPC: C07C005/373

CPC classification number: B01J19/2485 ,  B01J8/0411 ,  B01J23/78 ,  B01J23/8946 ,  B01J2208/00522 ,  B01J2208/00707 ,  B01J2208/025 ,  C07C5/32 ,  C07C5/333 ,  C07C2523/04 ,  C07C15/46 ,  C07C15/42 ,  C07C15/40

Abstract: A radial reactor for utilization for catalytic reactions of gaseous or liquid feed streams including an annular catalyst bed, wherein the material contained within the catalyst bed includes an active catalyst material, contained within an outer ring-shaped layer of the catalyst bed, and a generally inert material, contained within an inner ring-shaped layer of the catalyst bed, wherein the generally inert material includes a potassium-containing compound, such as potassium oxide, hydroxide, carbonate or bicarbonate.

Abstract translation: 一种用于气态或液态进料流（包括环形催化剂床）的催化反应的径向反应器，其中包含在催化剂床内的材料包括包含在催化剂床的外环形层内的活性催化剂材料， 惰性材料包含在催化剂床的内环形层中，其中通常为惰性的材料包括含钾化合物，例如氧化钾，氢氧化物，碳酸盐或碳酸氢盐。

公开(公告)号：US4113787A

公开(公告)日：1978-09-12

申请号：US758092

申请日：1977-01-10

Applicant: Dennis J. Ward

Inventor： Dennis J. Ward

IPC: C07C5/32 ,  C07C5/327 ,  C07C7/00 ,  C07C15/42 ,  C07C15/46 ,  C07C15/09 ,  C07C15/10

CPC classification number: C07C15/46 ,  C07C15/42 ,  C07C5/32 ,  C07C5/327 ,  C07C7/005 ,  Y10S585/903

Abstract: Alkylaromatic hydrocarbons including ethylbenzene are dehydrogenated in a vapor phase reactant stream, preferably at subatmospheric conditions. The resultant reaction zone effluent is partially condensed and then separated in a subatmospheric product settler. Hydrocarbons from the product settler are fractionated to yield a styrene bottoms stream, an overhead liquid recycled to the reaction zone and an overhead vapor. This vapor is admixed with vapors from the product settler, compressed to a superatmospheric pressure, and partially condensed to form a liquid which is fractionated to remove the net light aromatic hydrocarbons produced in the process.

Abstract translation: 包括乙苯在内的烷基芳族烃在气相反应物流中脱氢，优选在低于大气压的条件下脱氢。 所得反应区流出物部分冷凝，然后在低于大气压的产物沉降器中分离。 将来自产物沉降器的碳氢化合物分馏以产生苯乙烯塔底物流，再循环至反应区的塔顶液体和塔顶蒸气。 将该蒸气与来自产物沉降器的蒸气混合，压缩至超大气压，并部分冷凝以形成液体，其被分馏以除去在该过程中产生的净光芳烃。

公开(公告)号：US3807963A

公开(公告)日：1974-04-30

申请号：US23305572

申请日：1972-03-09

Applicant: SMITH J

Inventor： SMITH J

IPC: F28D7/16 ,  B01J8/06 ,  B01J19/00 ,  C07C5/32 ,  C07C5/333 ,  B01J9/04 ,  C07C15/10 ,  F28F13/00

CPC classification number: C07C5/321 ,  B01J8/067 ,  B01J19/0013 ,  B01J2208/00221 ,  B01J2208/00371 ,  B01J2219/00094 ,  B01J2219/00777 ,  C07C5/333 ,  Y02P20/582 ,  Y10S585/90 ,  Y10S585/922 ,  Y10S585/924 ,  C07C15/42 ,  C07C15/46

Abstract: Endothermic and exothermic reactions utilizing inert diluents or thermally stable reactants or product components are conducted by employing the inert diluent, etc., initially as a heat exchange medium followed by combining at least a portion thereof with the principal reactant to form the reactant feed stream to the reaction zone. The concept is useful in situations wherein isothermal conditions are desired. Both method and apparatus are described for carrying out the concept with particular application to reactions involving the dehydrogenation of alkylated aromatic hydrocarbons.

Abstract translation: 使用惰性稀释剂或热稳定反应物或产物组分的吸热和放热反应通过使用惰性稀释剂等，最初作为热交换介质进行，然后将其至少一部分与主要反应物组合以形成反应物进料流 反应区。 该概念在需要等温条件的情况下是有用的。 描述了用于实施具有特定应用于涉及烷基化芳烃的脱氢反应的概念的方法和装置。

公开(公告)号：US2241770A

公开(公告)日：1941-05-13

申请号：US14651937

申请日：1937-06-04

Applicant: DOW CHEMICAL CO

Inventor： DREISBACH ROBERT R ,  HANSON ALDEN W

IPC: C07C7/10 ,  C07C7/20

CPC classification number: C07C7/10 ,  C07C7/20 ,  C07C15/42 ,  C07C15/46

公开(公告)号：US07022220B2

公开(公告)日：2006-04-04

申请号：US10703581

申请日：2003-11-10

Applicant: Brigitte Benage ,  Gerald J. Abruscato ,  Andrew J. Eisenstein

Inventor： Brigitte Benage ,  Gerald J. Abruscato ,  Andrew J. Eisenstein

IPC: C07C7/20 ,  C07B63/04 ,  C09K15/00

CPC classification number: B01D3/34 ,  C07C7/04 ,  C07C7/20 ,  C07C51/50 ,  C07C67/62 ,  C07C253/32 ,  Y10S585/95 ,  C07C15/46 ,  C07C15/42 ,  C07C11/167 ,  C07C11/18 ,  C07C255/06 ,  C07C69/54 ,  C07C57/04

Abstract: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine oxime compounds. Also disclosed is a composition of matter comprising: A) an ethylenically unsaturated monomer and B) an effective inhibiting amount, sufficient to prevent premature polymerization during distillation or purification of said ethylenically unsaturated monomer, of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine oxime compounds used together with an effective amount of oxygen or air to enhance the inhibiting activity of said inhibitor.

公开(公告)号：US06899806B2

公开(公告)日：2005-05-31

申请号：US10703592

申请日：2003-11-10

Applicant: Brigitte Benage ,  Gerald J. Abruscato ,  Andrew J. Eisenstein

Inventor： Brigitte Benage ,  Gerald J. Abruscato ,  Andrew J. Eisenstein

IPC: C07B63/04 ,  B01D3/34 ,  C07C7/20 ,  C07D239/52 ,  C08F2/00 ,  C08F2/40 ,  C09K15/20 ,  C09K15/30 ,  C09K15/16

CPC classification number: B01D3/34 ,  C07C7/04 ,  C07C7/20 ,  C07C51/50 ,  C07C67/62 ,  C07C253/32 ,  Y10S585/95 ,  C07C15/46 ,  C07C15/42 ,  C07C11/167 ,  C07C11/18 ,  C07C255/06 ,  C07C69/54 ,  C07C57/04

Abstract: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of:A) at least one first inhibitor selected from the group consisting of C-nitrosoaniline compounds; andB) at least one second inhibitor selected from the group consisting of quinone alkides, nitroaromatic compounds, hydroxylamine compounds, phenylenediamine compounds, quinone compounds, and hydroquinone compounds. Also disclosed is a composition of matter comprising:A) at least one member selected from the group consisting of C-nitrosoaniline compounds; andB) at least one member selected from the group consisting of quinone alkides, nitroaromatic compounds, hydroxylamine compounds, phenylenediamine compounds, quinone compounds, and hydroquinone compounds.

Abstract translation: 本文公开了抑制烯属不饱和单体过早聚合的方法，包括向所述单体中加入有效量的：A）至少一种选自C-亚硝基苯胺化合物的第一抑制剂; 和B）选自由醌类，硝基芳族化合物，羟胺化合物，苯二胺化合物，醌化合物和氢醌化合物组成的组中的至少一种第二抑制剂。 还公开了一种物质组合物，其包含：A）至少一种选自C-亚硝基苯胺化合物; 和B）选自由醌类，硝基芳族化合物，羟胺化合物，苯二胺化合物，醌化合物和氢醌化合物组成的组中的至少一种。