ALPHA-PHASE NICKEL HYDROXIDE AND PREPARATION METHOD AND USE THEREOF

    公开(公告)号:US20230339773A1

    公开(公告)日:2023-10-26

    申请号:US17846266

    申请日:2022-06-22

    CPC classification number: C01G53/08 C30B7/14 C01P2002/22 C01P2006/40

    Abstract: Disclosed is an α-phase nickel hydroxide and a preparation method and use thereof. The method for preparing an α-phase nickel hydroxide comprises the following steps: subjecting a biomass calcium source to a calcination to obtain a porous calcium oxide; under a protective atmosphere, mixing the porous calcium oxide with a first methanol-ethanol solvent to obtain a calcium oxide heterogeneous solution; under a protective atmosphere, mixing the calcium oxide heterogeneous solution with a nickel source homogeneous solution to obtain a mixture, and subjecting the mixture to a coprecipitation to obtain a nickel calcium hydroxide precursor, wherein the nickel source homogeneous solution is prepared with a nickel source containing crystal water as a solute and a second methanol-ethanol solvent as a solvent; and subjecting the nickel calcium hydroxide precursor to a calcium hydroxide removal treatment to obtain the α-phase nickel hydroxide.

    Process for the extraction of specific transition metals
    4.
    发明授权
    Process for the extraction of specific transition metals 有权
    提取特定过渡金属的方法

    公开(公告)号:US08268267B2

    公开(公告)日:2012-09-18

    申请号:US12581778

    申请日:2009-10-19

    Inventor: Joseph L. Thomas

    Abstract: A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCl to form volatile chloride-bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCl pressurized with gaseous HCl.

    Abstract translation: 公开了一种用于从氧化铝基材料,哑光,矿石,制造副产物和废物中分离和回收钒,钼,铁,钨,钴和镍的方法。 这些元素被氧化。 氧化物与气态HCl反应以形成随后升华的含有挥发物的化合物。 挥发性化合物以向下阶梯式的热梯度冷凝,其允许收集单个元素的中等至高纯度化合物,不包括镍 - 钴共缩合物。 通过从浓HCl中用氯化氢沉淀氯化镍与气体HCl分离,将镍与钴分离。

    Production of nickel fluoride
    9.
    发明授权
    Production of nickel fluoride 失效
    生产氟化钾

    公开(公告)号:US3607013A

    公开(公告)日:1971-09-21

    申请号:US3607013D

    申请日:1969-02-10

    Applicant: FMC CORP

    Inventor: SALDICK JEROME

    CPC classification number: H01M4/582 C01G53/08

    Abstract: A highly active, anhydrous nickel fluoride which is resistant to pickup of atmospheric water and is superior as a battery element in high energy lithium-nickel fluoride batteries, is produced by passing anhydrous gaseous hydrogen fluoride over amorphous basic nickel carbonate at a temperature of between 150*-300* C. and preferably 225*-250* C.

    Method for forming metal fluoride material
    10.
    发明授权
    Method for forming metal fluoride material 有权
    形成金属氟化物材料的方法

    公开(公告)号:US09446966B2

    公开(公告)日:2016-09-20

    申请号:US14221957

    申请日:2014-03-21

    Inventor: Jon Shan

    Abstract: The present invention is directed to processing techniques and systems of metal fluoride based material, including but not limited to nickel difluoride, copper difluoride, manganese fluoride, chromium fluoride, bismuth fluoride, iron trifluoride, iron difluoride, iron oxyfluoride, metal doped iron fluorides, e.g., FexM1-xFy (M=metals, which can be Co, Ni, Cu, Cr, Mn, Bi and Ti) materials. An exemplary implementation involves mixing a first compound comprising a metal material, nitrogen, and oxygen to a second compound comprising hydrogen fluoride. The mixed compound is milled to form metal fluoride precursor and a certain byproduct. The byproduct is removed, and the metal fluoride precursor is treated to form iron trifluoride product. There are other embodiments as well.

    Abstract translation: 本发明涉及金属氟化物基材料的处理技术和系统,包括但不限于二氟化镍,二氟化铜,氟化锰,氟化铬,氟化铋,三氟化铁,二氟化铁,氟氧化铁,金属掺杂的氟化铁, 例如FexM1-xFy(M =金属,可以是Co,Ni,Cu,Cr,Mn,Bi和Ti)材料。 示例性实施方案包括将包含金属材料,氮和氧的第一化合物混合到包含氟化氢的第二化合物中。 将混合的化合物研磨以形成金属氟化物前体和某种副产物。 除去副产物,并处理金属氟化物前体以形成三氟化铁产物。 还有其它实施例。

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