摘要:
An increase in the cutting hardness of a shaped body comprising a crystalline aluminosilicate is achieved by treating the shaped body with a gas comprising water vapor at from 100 to 600° C. and an absolute pressure of from 0.1 to 10 bar for a period of at least 20 hours, and this shaped body having an increased cutting hardness can be used in processes for chemical synthesis, in particular in a process for preparing triethylenediamine (TEDA) by reaction of ethylenediamine (EDA) and/or piperazine (PIP).
摘要:
The invention relates to a process for producing flexible polyurethane foams, in particular molded flexible polyurethane foams, by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein at least one polyether alcohol bi) which has been prepared by means of a DMC catalyst and has a hydroxyl number in the range from 15 to 35 mg KOH/g, and ethylene oxide content in the range from 5 to 18% by weight, based on the total weight of the polyether alcohol and an end block of ethylene oxide and propylene oxide having an ethylene oxide content of from 25 to 75% by weight, based on the amount of alkylene oxide in the end block, is used as compound b) having at least two hydrogen atoms which are reactive toward isocyanate groups.
摘要:
An increase in the cutting hardness of a shaped body comprising a crystalline aluminosilicate is achieved by treating the shaped body with a gas comprising water vapor at from 100 to 600° C. and an absolute pressure of from 0.1 to 10 bar for a period of at least 20 hours, and this shaped body having an increased cutting hardness can be used in processes for chemical synthesis, in particular in a process for preparing triethylenediamine (TEDA) by reaction of ethylenediamine (EDA) and/or piperazine (PIP).
摘要:
A process for brightening textile materials by treatment with optical brighteners in an aqueous liquor, which comprises using from 20 to 80% by weight, each percentage being based on the sum total of all brightening compounds, of the compound I of which up to 40 mol % can be present as cis isomer, and also from 80 to 20% by weight of at least one compound II selected from and also from 0 to 30% by weight of at least one compound of the general formula III
摘要:
The invention relates to a process for preparing polyisocyanates by reacting primary amines with phosgene in the presence of a solvent, wherein ionic liquids are used as solvents.
摘要:
The use of compounds of the general formula I where A is ═N— or ═CH—; X when A is ═N— is methyl or a radical of the formula IIa or when A is ═CH— is an R radical; Y is an R radical or a radical of the formula IIb with either X being a radical of the formula IIa or Y being a radical of the formula IIb; R is hydrogen, halogen, C1-C4-alkyl, —SO3H, —SO3−Me+, —SO3−N+R1R2R3R4, —SO2NR1R2, —CH2NR1R2, —CH2R5, —COOH, —COO−N+R1R2R3R4, —COOR6 or —COR6; R1, R2, R3 and R4 are each independently hydrogen; C1-C22-alkyl or C2-C22-alkenyl whose carbon chain may in either case be interrupted by one or more —O—, —S—, —NR7—, —CO— or —SO2− moieties and/or which may be substituted by one or more of hydroxyl, halogen, aryl, C1-C4-alkoxy and acetyl; C3-C8-cycloalkyl whose carbon skeleton may be interrupted by one or more —O—, —S—, —NR7— or —CO— moieties and/or which may be substituted by one or more of hydroxyl, halogen, aryl, C1-C4-alkoxy and acetyl; hydroabietyl, abietyl or aryl; R1 and R2 or R1, R2 and R3 may combine to form a 5- to 7-membered cyclic radical which contains the nitrogen atom and may contain further hetero atoms; R5 is a radical of the formula IIb′ R6 is one of the R1 alkyl radicals; R7 is hydrogen or C1-C4-alkyl; Me is an alkali metal ion; Z and Z′ are each independently arylene which may be substituted by one or more of halogen, —SO3H, —SO3−Me+, —SO3−N+R1R2R3R4, and C1-C12-alkyl, and the rings B1 and B2 may each be independently additionally substituted by one or more identical or different R radicals other than hydrogen, as crystallization modifiers for organic pigments.
摘要:
Process for the emulsion polymerization of one or more olefins by reacting a quinoid compound with a metal compound and a phosphine compound which is substituted by at least one polar radical and subsequently using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture which contains at least 50% by weight of water and at least one emulsifier.
摘要:
This invention relates to composite elements comprising a polyurethane foam (i), a nonwoven of thermoplastic polyurethane (ii) and if appropriate a covering layer (iii), and also to a process for their production and to the use of this invention's composite elements as seats or carpets.
摘要:
The invention relates to the use of an apparatus for adding at least one solid or viscous liquid additive, or an additive dispersed in solvent, to a reactor interior of a reactor for preparing crosslinked, finely divided polymers by copolymerizing (a) water-soluble, monoethylenically unsaturated monomers and (b) from 0.001 to 5 mol %, based on the monomers (a), of monomers comprising at least two polymerizable groups, (c) from 0 to 20 mol %, based on the monomers (a), of water-insoluble monoethylenically unsaturated monomers, where the apparatus comprises at least one screw for conveying the at least one additive and the at least one screw ends in an addition orifice substantially flush with the inner wall of the reactor interior.