Method of hydrocarbon reforming and catalyst precursor
    1.
    发明授权
    Method of hydrocarbon reforming and catalyst precursor 失效
    烃重整方法和催化剂前体

    公开(公告)号:US6071433A

    公开(公告)日:2000-06-06

    申请号:US233547

    申请日:1999-01-20

    摘要: Hydrotalcite-like clays, catalysts derived therefrom, and methods of hydrocarbon reforming using the catalyst are disclosed. The hydrotalcite-like clays, which may be calcined to form the catalyst, have the formula [M.sup.2+.sub.(1-x) M.sup.3+.sub.x (OH).sub.2 ].sup.x+ (A.sup.n-.sub.x/n).mH.sub.2 O at an elevated temperature for a time sufficient to decompose A and to dehydrate said compound, wherein M.sup.2+ comprises at least two species of metal ions having a valence of 2+ selected from the group consisting of Cu.sup.2+, Zn.sup.2+, Ni.sup.2+, and Mg.sup.2+, provided that if M.sup.2+ comprises Mg.sup.2+ at least one of Zn.sup.2+ and Ni.sup.2+ is also present, wherein the atomic ratio of the total of Zn.sup.2+ and Mg.sup.2+ to the total of Cu.sup.2+ and Ni.sup.2+ is up to about 9, inclusive, wherein the total of Zn.sup.2+ and Mg.sup.2+ comprises at least about 5 wt. % of said M.sup.2+ metals; M.sup.3+ is at least one metal ion having a valence of 3+ selected from the group consisting of Al.sup.3+, Fe.sup.3+, Cr.sup.3+, La.sup.3+, Ce.sup.3+, and mixtures thereof; x is a number in the range of about 0.1 to about 0.5, inclusive; A is an anion having a charge of -n; n is an integer in the range of 1 to 6, inclusive; and, m is zero or a positive number.

    摘要翻译: 公开了水滑石状粘土,由其衍生的催化剂和使用该催化剂的烃重整方法。 可以煅烧形成催化剂的水滑石样粘土在升高的温度下具有式[M2 +(1-x)M3 + x(OH)2] x +(An-x / n)·mH2O一段时间 足以分解A并使所述化合物脱水,其中M2 +包含至少两种具有选自Cu 2+,Zn 2+,Ni 2+和Mg 2+的化合价的2+的金属离子,条件是如果M2 +包含至少一个Mg 2+ 的Zn2 +和Ni2 +,其中Zn2 +和Mg2 +的总量与Cu2 +和Ni2 +的总量的原子比高达约9,其中Zn 2+和Mg 2+的总量包含至少约5wt。 所述M2 +金属的%; M3 +为至少一种选自Al3 +,Fe3 +,Cr3 +,La3 +,Ce3 +的化合价为3+的金属离子及其混合物; x是约0.1至约0.5的范围内的数字,包括端值; A是电荷为-n的阴离子; n为1〜6的整数,包括1和6; m为零或正数。

    Crystallization of 2,6-dimethylnaphthalene
    4.
    发明授权
    Crystallization of 2,6-dimethylnaphthalene 失效
    2,6-二甲基萘结晶

    公开(公告)号:US5977426A

    公开(公告)日:1999-11-02

    申请号:US957871

    申请日:1997-10-20

    CPC分类号: C07C15/24 C07C7/14

    摘要: A method for recovering crystalline 2,6-dimethylnaphthalene comprising crystallizing in a scraped-wall crystallizer apparatus at crystallization temperature T, a mixture of low melting components, LM, having melting points of 70.degree. F. and below, and high melting components (HM), including 2,6-dimethylnaphthalene, having melting points above 70.degree. F, such that: ##EQU1## where HM is the total weight percent of high melting components, including 2,6-dimethylnaphthalene, in the mixture, and LM is the total weight percent of low melting components in the mixture, and where T is the temperature of the crystallization in degrees Fahrenheit, and where A is at least 1.0.

    摘要翻译: 一种回收结晶的2,6-二甲基萘的方法,包括在结晶温度T下,在熔融结晶器装置中结晶的熔融点为70°F以下的低熔点组分LM和高熔点组分(HM ),包括熔点高于70°F的2,6-二甲基萘,使得:HM是混合物中高熔点组分(包括2,6-二甲基萘)的总重量百分数,LM是总重量百分比 的混合物中的低熔点组分,其中T是以华氏度为单位的结晶温度,其中A至少为1.0。

    Process for synthesis of molybdenum sulfide dimers
    6.
    发明授权
    Process for synthesis of molybdenum sulfide dimers 失效
    硫化钼二聚体合成方法

    公开(公告)号:US5962364A

    公开(公告)日:1999-10-05

    申请号:US903054

    申请日:1997-07-30

    IPC分类号: C07F17/00 B01J31/00 C07F11/00

    CPC分类号: C07F17/00

    摘要: A method for converting �MoCp(CO).sub.3 !.sub.2, in which at least one of the Cp groups has a substitutent having a carbonyl or carboxyl group and the compound has a Mo--Mo single bond, into a resinous supported material having repeating units of the formula (MoCp).sub.2 S.sub.4. The repeating units have four bridging sulfido ligands between the two molybdenum atoms, and the repeating units are joined to each other by bridging-sulfide ligands. The method comprises reacting the molybdenum carbonyl dimer with elemental sulfur in a solvent for the starting material at a temperature between 110-120.degree. C. in the presence of a solid adsorbent support. The resinous material may be further hydrogenated, the hydrogenated material may be further reacted to form a material having a carboxyl-containing methanedithiolate ligand, and this latter material may be further hydrolyzed. The molybdenum sulfide dimers are useful for separation, purification, and recovery of unsaturated hydrocarbons.

    摘要翻译: 将具有羰基或羧基的取代基中的至少一个具有Mo-Mo单键的化合物的MoCp(CO)3] 2转化为具有重复单元的树脂负载材料的方法 的式(MoCp)2S4。 重复单元在两个钼原子之间具有四个桥连硫基配体,并且重复单元通过桥连硫化物配体彼此连接。 该方法包括在固体吸附剂载体存在下,在110-120℃的温度下使钼羰基二聚体与元素硫在起始物质的溶剂中反应。 可以将树脂材料进一步氢化,氢化材料可以进一步反应以形成具有含羧基的甲硫醚硫酸盐配体的材料,并且后一种材料可以进一步水解。 硫化钼二聚体可用于分离,纯化和回收不饱和烃。

    Resid hydroprocessing method utilizing a metal-impregnated, carbonaceous
particle catalyst
    8.
    发明授权
    Resid hydroprocessing method utilizing a metal-impregnated, carbonaceous particle catalyst 失效
    使用金属浸渍的碳质颗粒催化剂的残留加氢处理方法

    公开(公告)号:US5951849A

    公开(公告)日:1999-09-14

    申请号:US761746

    申请日:1996-12-05

    IPC分类号: B01J27/04 C10G47/06 C10G47/26

    CPC分类号: C10G47/26 Y10S977/775

    摘要: A method for converting a hydrocarbonaceous feedstock to a lower boiling product is described which comprises suspending metal-impregnated carbonaceous particles in a reaction zone including hydrogen and the hydrocarbonaceous feedstock at hydrocracking conditions. The metal impregnated on the particles may be sulfided in the reaction zone. The impregnated particles are shown to be surprisingly selective catalysts, and anomalous ranges of particle size and concentration are identified. Methods for preparing the particles are additionally presented.

    摘要翻译: 描述了一种将含烃原料转化为低沸点产物的方法,其包括在加氢裂化条件下将金属浸渍的碳质颗粒悬浮在包含氢和烃原料的反应区中。 浸渍在颗粒上的金属可能在反应区中被硫化。 浸渍的颗粒被证明是令人惊讶的选择性催化剂,并且确定了颗粒尺寸和浓度的异常范围。 另外提供了制备颗粒的方法。

    Method of seismic attribute generation and seismic exploration
    10.
    发明授权
    Method of seismic attribute generation and seismic exploration 失效
    地震属性生成与地震勘探方法

    公开(公告)号:US5940778A

    公开(公告)日:1999-08-17

    申请号:US904040

    申请日:1997-07-31

    IPC分类号: G01V1/28 G06F19/00

    摘要: The present invention relates generally to the field of seismic exploration and, in more particular, to methods of quantifying and visualizing structural and stratigraphic features in three dimensions through the use of eigenvector and eigenvalue analyses of a similarity matrix. This invention also relates to the field of seismic attribute generation and the use of seismic attributes derived from similarity matrices to detect the conditions favorable for the origination, migration, accumulation, and presence of hydrocarbons in the subsurface. Additionally, the methods disclosed herein provide a new means for analyzing unstacked seismic data to uncover AVO effects. The invention disclosed herein will be most fully appreciated by those in the seismic interpretation and seismic processing arts.

    摘要翻译: 本发明一般涉及地震勘探领域,更具体地涉及通过使用相似矩阵的特征向量和特征值分析来量化和可视化三维结构和地层特征的方法。 本发明还涉及地震属性生成领域和从相似性矩阵得到的地震属性的使用,以检测有利于地下烃类的起源,迁移,积累和存在的条件。 此外,本文公开的方法提供了用于分析未爆炸的地震数据以发现AVO效应的新手段。 这里公开的发明将被地震解释和地震处理领域的人最全面地理解。