Method for producing composite sol, coating composition, and optical element
    1.
    发明授权
    Method for producing composite sol, coating composition, and optical element 有权
    复合溶胶,涂料组合物和光学元件的制备方法

    公开(公告)号:US06296943B1

    公开(公告)日:2001-10-02

    申请号:US09380403

    申请日:1999-09-01

    IPC分类号: B32B904

    摘要: The present invention relates to a method for producing titanium oxide (TiO2)-tin oxide (SnO2) composite sol, a titanium oxide (TiO2)-zirconium oxide (ZrO2)-tin oxide (SnO2) composite sol, and a titanium oxide (TiO2)-cerium oxide (CeO2)-tin oxide (SnO2) composite sol. Further, the present invention relates to a coating composition containing any of the above-mentioned composite sols for forming coating films that are excellent in marring resistance, surface hardness, wearing resistance, transparency, heat resistance, light-resistant, weatherability, or water resistance on optical elements such as lenses for glasses and cameras, automotive windowpane, or optical filters attached to liquid-crystal displays, plasma displays, etc. and to optical elements having a cured film of the coating composition on the surfaces.

    摘要翻译: 本发明涉及氧化钛(TiO 2) - 氧化锡(SnO 2)复合溶胶,氧化钛(TiO 2) - 氧化锆(ZrO 2) - 氧化锡(SnO 2)复合溶胶和氧化钛(TiO 2)的制造方法 ) - 氧化铈(CeO2) - 氧化锡(SnO2)复合溶胶。 此外,本发明涉及一种涂料组合物,其含有上述用于形成耐损伤性,表面硬度,耐磨性,透明性,耐热性,耐光性,耐候性或耐水性优异的涂膜的上述复合溶胶 在诸如用于眼镜和相机的透镜,汽车窗玻璃或附着到液晶显示器的光学滤光器,等离子体显示器等的光学元件上,以及具有表面上的涂层组合物的固化膜的光学元件。

    Silica-magnesium fluoride hydrate composite sols and process for their preparation
    4.
    发明授权
    Silica-magnesium fluoride hydrate composite sols and process for their preparation 失效
    二氧化硅 - 氟化镁水合物复合溶胶及其制备方法

    公开(公告)号:US06291535B1

    公开(公告)日:2001-09-18

    申请号:US09455928

    申请日:1999-12-07

    IPC分类号: B01F312

    摘要: A sol comprising silica-magnesium fluoride hydrate composite colloidal particles used in an anti-reflection coating material for forming an anti-reflection coating and a process for its preparation are provided. A sol comprising silica-magnesium fluoride hydrate composite colloidal particles having a ratio of silica to magnesium fluoride hydrate MgF2.nH2O, n being in the range between 0.25 and 0.5, in terms of a SiO2/MgF2 weight ratio of from 0.01 to 5 and a primary particle size of 5 to 50 nm. A process for the preparation of an aqueous sol comprising silica-magnesium fluoride hydrate composite colloidal particles which comprises the steps of adding an aqueous fluoride solution to a mixture liquid of a silica sol and an aqueous magnesium salt solution to produce a slurry of an agglomerate comprising silica-magnesium fluoride hydrate composite colloidal particles and removing the salts formed as by-products. A process for the preparation of an organosol further comprising the step of replacing water in the aqueous sol with an organic solvent.

    摘要翻译: 提供一种包含用于形成抗反射涂层的防反射涂层材料中的二氧化硅 - 氟化镁水合物复合胶体颗粒及其制备方法。 包含二氧化硅 - 氟化镁水合物复合胶体粒子的溶胶,SiO 2 / MgF 2重量比为0.01〜5,二氧化硅与氟化镁水合物的比例为MgF 2·nH 2 O,n为0.25〜0.5的范围, 一次粒径为5〜50nm。 一种制备包含二氧化硅 - 氟化镁水合物复合胶体颗粒的水性溶胶的方法,包括以下步骤:向二氧化硅溶胶和镁盐水溶液的混合液中加入氟化钠水溶液,以产生附聚物的浆料,其包含 二氧化硅 - 氟化镁水合物复合胶体颗粒并除去作为副产物形成的盐。 一种制备有机溶胶的方法,还包括用有机溶剂代替水溶胶中的水的步骤。

    Coating compositions employing zinc antimonate anhydride particles
    5.
    发明授权
    Coating compositions employing zinc antimonate anhydride particles 失效
    使用锑酸锌酸酐颗粒的涂料组合物

    公开(公告)号:US5906679A

    公开(公告)日:1999-05-25

    申请号:US939202

    申请日:1997-09-29

    摘要: The invention relates to coating compositions employing zinc antimonate anhydride comprising zinc antimonate anhydride particles and a liquid of a part-hydrolyzed silane coupling agent, a liquid of hydrolyzed ethylsilicate, a liquid of hydrolyzed methylsilicate, or a resin emulsion. The zinc antimonate anhydride particle having a ZnO/Sb.sub.2 O.sub.5 molar ratio in a range of from 0.8 to 1.2, a crystal structure of zinc antimonate anhydride (Zn Sb.sub.2 0.sub.5), and a primary particle size in a range of from 5 to 500 nm. The particle production method comprises the steps of mixing a zinc compound with a colloidal antimony oxide at a ZnO/Sb.sub.2 O.sub.5 molar rate in a range of from 0.8 to 1.2, followed by calcining the mixture within a temperature range of from 500 to 1100.degree. C. The particles are applicable as a flame retardant for plastics, a smoke suppressant, antistatic agent for plastics and glasses, and resistor.

    摘要翻译: 本发明涉及使用包含锑酸锌酸酐颗粒和部分水解的硅烷偶联剂的液体,水解的硅酸乙酯的液体,水解的甲基硅酸的液体或树脂乳液的锑酸锌酸酐的涂料组合物。 ZnO / Sb 2 O 5摩尔比为0.8〜1.2的锑酸锌酸酐粒子,锑酸锌酸酐(Zn Sb 2 O 5)的结晶结构,一次粒径为5〜500nm。 粒子的制造方法包括以0.5〜1.2的ZnO / Sb 2 O 5摩尔比混合锌化合物和胶态氧化锑,然后在500〜1100℃的温度范围内煅烧。 该颗粒可用作塑料阻燃剂,防烟剂,塑料和眼镜用抗静电剂和电阻剂。