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    Process for the preparation of indigo compounds
    1.
    发明授权
    Process for the preparation of indigo compounds 失效
    制备靛青化合物的方法

    公开(公告)号：US5187283A

    公开(公告)日：1993-02-16

    申请号：US796265

    申请日：1991-11-21

    申请人： Yoshihiro Yamamoto ,  Usaji Takaki ,  Shinobu Aoki ,  Yoshihisa Inoue ,  Isao Hara

    发明人： Yoshihiro Yamamoto ,  Usaji Takaki ,  Shinobu Aoki ,  Yoshihisa Inoue ,  Isao Hara

    IPC分类号： C09B7/02

    CPC分类号： C09B7/02

    摘要： An indigo compound is prepared from a corresponding indole compound which is unsubstituted at the 2- and 3- positions. The indole compound and an organic hydroperoxide are reacted in the presence of a catalyst which is a metal selected from the group consisting of the metals of Groups 4, 5 and 6 of the periodic table or a compound of the metal. The reaction is conducted while taking out water from a reaction system, said water being that introduced in the reaction system or formed during the reaction, or while controlling the amount of water, which is introduced in the reaction system, at a level not greater than 1 mole per mole of the indole compound.

    Preparation process of cinnamate ester
    7.
    发明授权
    Preparation process of cinnamate ester 失效
    肉桂酸酯的制备方法

    公开(公告)号：US5179224A

    公开(公告)日：1993-01-12

    申请号：US769481

    申请日：1991-10-01

    申请人： Usaji Takaki ,  Yoshihiro Yamamoto ,  Toshio Matsuhisa ,  Isamu Sudo ,  Shinobu Aoki

    发明人： Usaji Takaki ,  Yoshihiro Yamamoto ,  Toshio Matsuhisa ,  Isamu Sudo ,  Shinobu Aoki

    IPC分类号： C07C69/618

    CPC分类号： C07C69/618 ,  Y02P20/584

    摘要： Disclosed herein is a process for preparing a corresponding cinnamate ester by reacting a styrene compound, carbon monoxide, an alcohol and oxygen by the use of (1) metallic palladium or a compound thereof, (2) a copper compound, (3) a compound of at least one metal selected from Groups 4A, 5A, 7A, 8A (the iron group only) and 2B in the Periodic Table and (4) a halogen compound as a catalyst which comprises treating the catalyst components recovered from the reaction liquid after completion of the reaction with an oxidizing agent in the presence of an organic acid to regenerate their catalytic activity, using the resulting catalyst components again in the reaction as a catalyst and repeating the foregoing procedure.The regenerated catalyst is recovered in catalytic activity to the extent of that of a fresh catalyst and thus gives a high reaction performance in the subsequent reaction. Thus, the catalyst containing expensive metal can be used circulatively.

    摘要翻译： 本文公开了通过使用（1）金属钯或其化合物使苯乙烯化合物，一氧化碳，醇和氧反应制备相应的肉桂酸酯的方法，（2）铜化合物，（3）化合物 的选自4A，5A，7A，8A（仅铁族）和2B中的至少一种金属，以及（4）作为催化剂的卤素化合物，其包括在完成后处理从反应液中回收的催化剂成分 在有机酸存在下与氧化剂反应以再生其催化活性，在反应中再次使用所得催化剂组分作为催化剂，并重复上述步骤。 再生催化剂的催化活性回收到新鲜催化剂的催化活性，因此在随后的反应中得到高的反应性能。 因此，可以循环使用含有贵金属的催化剂。

    Process for preparing poly(alkylene oxide)
    9.
    发明授权
    Process for preparing poly(alkylene oxide) 有权
    制备聚（环氧烷）的方法

    公开(公告)号：US06255537B1

    公开(公告)日：2001-07-03

    申请号：US09289990

    申请日：1999-04-13

    申请人： Takaomi Hayashi ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Kazumi Mizutani ,  Isao Hara ,  Shinji Kiyono ,  Tadahito Nobori ,  Usaji Takaki

    发明人： Takaomi Hayashi ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Kazumi Mizutani ,  Isao Hara ,  Shinji Kiyono ,  Tadahito Nobori ,  Usaji Takaki

    IPC分类号： C07C4313

    CPC分类号： C08G65/2675 ,  C08G65/10 ,  C08G65/2663

    摘要： There is provided a process for preparing a poly(alkylene oxide) by using a polymerization initiator which does not cause any problem on preparing and handling in the preparation of the polyalkylene oxide by polymerizing an alkylene oxide compound and does not require a special treatment before the initiation of the polymerization. That is, it is a process of polymerizing the alkylene oxide compound in the presence of a phosphine oxide compound represented by the formula (1): wherein R is the same or different and each represents a hydrocarbon group having 1 to 10 carbon atoms, and x represents an amount of water molecules contained in terms of a molar ratio and is within a range from 0 to 5.0, or in the presence of said phosphine oxide compound and an active hydrogen compound selected from water or an organic compound having a partial structural formula —OH or —NH—.

    摘要翻译： 提供了一种通过使用聚合引发剂制备聚（环氧烷）的方法，该聚合引发剂在通过聚合烯化氧化合物制备聚环氧烷的制备和处理中不会引起任何问题，并且不需要在 引发聚合。 也就是说，它是在式（1）表示的氧化膦化合物存在下使烯化氧化合物聚合的方法：其中R相同或不同，各自代表具有1-10个碳原子的烃基，和 x表示以摩尔比表示的水分子的含量，在0〜5.0的范围内，或在所述氧化膦化合物和活性氢化合物存在下，选自水或具有部分结构式的有机化合物 -OH或-NH-。

    Phosphine sulfide, a manufacturing process therefor and use thereof
    10.
    发明授权
    Phosphine sulfide, a manufacturing process therefor and use thereof 有权
    硫化磷，其制造方法及其用途

    公开(公告)号：US6153794A

    公开(公告)日：2000-11-28

    申请号：US348586

    申请日：1999-07-07

    申请人： Katsuhiko Funaki ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Atsushi Shibahara ,  Kazumi Mizutani ,  Tadahito Nobori ,  Usaji Takaki

    发明人： Katsuhiko Funaki ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Atsushi Shibahara ,  Kazumi Mizutani ,  Tadahito Nobori ,  Usaji Takaki

    IPC分类号： C07F9/53 ,  C07F9/06 ,  C07F9/22 ,  C08G65/26 ,  C07C43/11 ,  C07C69/76

    CPC分类号： C07F9/224 ,  C07F9/065 ,  C08G65/2675

    摘要： An organic compound which is basic and soluble in an organic solvent, does not have a problem in preparation or handling and exhibits catalytic activity as a basic compound, i.e., a phosphine sulfide represented by formula (1), and a manufacturing process therefor, i.e., manufacturing a phosphine sulfide represented by formula (1), by reacting one molecule of thiophosphoryl chloride with three molecules of a phosphorane represented by formula (2). The phosphine sulfide can be used in a process for effectively manufacturing a poly(alkylene oxide) by polymerizing an alkylene oxide in the presence of the phosphine sulfide or of the phosphine sulfide and an active hydrogen compound selected from water and organic compounds having a partial structure of --OH or --NH--; and 2) a process for manufacturing a 1,2-dioxyethane derivative from an epoxy compound, i.e, manufacturing a 1,2-dioxyethane derivative by reacting an epoxy compound with a carboxylate, carboxylic anhydride, carbonate or phenol compound, respectively, in the presence of the phosphine sulfide.

    摘要翻译： 碱性且可溶于有机溶剂的有机化合物在制备或处理中没有问题，并且表现出作为碱性化合物的催化活性，即由式（1）表示的硫化膦及其制备方法，即 制备由式（1）表示的硫化膦，通过使一分子的硫代磷酰氯与由式（2）表示的三价分子的三分子反应。 所述硫化膦可用于通过在硫化膦或硫化氢存在下聚合烯化氧和选自水和具有部分结构的有机化合物的活性氢化合物来有效制造聚（环氧烷）的方法 的-OH或-NH-; 和2）由环氧化合物制造1,2-二氧乙烷衍生物的方法，即分别通过使环氧化合物与羧酸酯，羧酸酐，碳酸酯或酚化合物反应制备1,2-二氧乙烷衍生物 硫化磷的存在。