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1.发明授权Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking 有权使用加氢裂化从天然油共生产烷基苯和生物燃料的方法公开(公告)号：US08865956B2
公开(公告)日：2014-10-21
申请号：US13954476
申请日：2013-07-30
Applicant: UOP LLC
Inventor： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Sllva Ferreira Alves , Andrea G. Bozzano
IPC: C07C1/207 , C07C2/64 , C07C5/22 , C10G3/00 , C07C5/333 , C07C2/68 , C07C2/70 , C01B3/32 , C07C7/163
CPC classification number: C10G3/50 , C01B3/32 , C07C2/68 , C07C2/70 , C07C5/333 , C07C7/163 , C07C2527/1206 , C07C2527/126 , C10G3/00 , C10G29/205 , C10G69/06 , C10G69/123 , C10G2300/1014 , Y02P30/20 , C07C15/107 , C07C11/02
Abstract: Embodiments of methods for the production of linear alkylbenzene and optionally biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form paraffins. A first portion of the paraffins is hydrocracked to form a first stream of normal and lightly branched paraffins in the C9 to C14 range and a second stream of isoparaffins. The first stream is dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. Optionally a second portion of the paraffins and the isoparaffins are processed to form biofuel.
Abstract translation: 提供了用于生产直链烷基苯和任选的天然油生物燃料的方法的实施方案。 一种方法包括使天然油脱氧以形成链烷烃的步骤。 将第一部分石蜡加氢裂化以形成C9至C14范围内的第一流和正链和轻度支化的烷烃，第二股异链烷烃流。 将第一流脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 任选地，将第二部分石蜡和异链烷烃加工形成生物燃料。
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2.发明申请METHODS FOR CO-PRODUCTION OF ALKYLBENZENE AND BIOFUEL FROM NATURAL OILS USING HYDROCRACKING 有权使用水解法从天然油中生产烷基苯酚和生物油的方法公开(公告)号：US20130317267A1
公开(公告)日：2013-11-28
申请号：US13954476
申请日：2013-07-30
Applicant: UOP LLC
Inventor： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da SIlva Ferreira Alves , Andrea G. Bozzano
IPC: C10G3/00
CPC classification number: C10G3/50 , C01B3/32 , C07C2/68 , C07C2/70 , C07C5/333 , C07C7/163 , C07C2527/1206 , C07C2527/126 , C10G3/00 , C10G29/205 , C10G69/06 , C10G69/123 , C10G2300/1014 , Y02P30/20 , C07C15/107 , C07C11/02
Abstract: Embodiments of methods for the production of linear alkylbenzene and optionally biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form paraffins. A first portion of the paraffins is hydrocracked to form a first stream of normal and lightly branched paraffins in the C9 to C14 range and a second stream of isoparaffins. The first stream is dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. Optionally a second portion of the paraffins and the isoparaffins are processed to form biofuel.
Abstract translation: 提供了用于生产直链烷基苯和任选的天然油生物燃料的方法的实施方案。 一种方法包括使天然油脱氧以形成链烷烃的步骤。 将第一部分石蜡加氢裂化以形成C9至C14范围内的第一流和正链和轻度支化的烷烃，第二股异链烷烃流。 将第一流脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 任选地，将第二部分石蜡和异链烷烃加工形成生物燃料。
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3.发明申请公开(公告)号：US20130317268A1
公开(公告)日：2013-11-28
申请号：US13954496
申请日：2013-07-30
Applicant: UOP LLC
Inventor： Andrea G. Bozzano , Matthew J. Griffiths , Amarendra Anumakonda
IPC: C10G3/00
CPC classification number: C10G3/50 , C01B3/00 , C01B3/26 , C01B2203/06 , C07C2/68 , C07C2/70 , C07C5/333 , C10G3/00 , C10G9/00 , C10G29/205 , C10G45/32 , C10G55/04 , C10G69/123 , C10G2300/1014 , C10G2400/30 , Y02E50/13 , Y02P30/20 , C07C11/02 , C07C15/107
Abstract: Embodiments of methods for production of linear alkylbenzene and optionally biofuel from natural oil are provided. Natural oils are deoxygenated to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. Optionally, a second portion of the paraffins may be processed to form biofuel.
Abstract translation: 提供了用于生产直链烷基苯和任选的天然油生物燃料的方法的实施方案。 天然油被脱氧以形成包含石蜡的料流。 将第一部分链烷烃脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 任选地，第二部分石蜡可以被加工以形成生物燃料。
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4.发明授权公开(公告)号：US08853479B2
公开(公告)日：2014-10-07
申请号：US13954496
申请日：2013-07-30
Applicant: UOP LLC
Inventor： Andrea G. Bozzano , Matthew J. Griffiths , Amarendra Anumakonda
CPC classification number: C10G3/50 , C01B3/00 , C01B3/26 , C01B2203/06 , C07C2/68 , C07C2/70 , C07C5/333 , C10G3/00 , C10G9/00 , C10G29/205 , C10G45/32 , C10G55/04 , C10G69/123 , C10G2300/1014 , C10G2400/30 , Y02E50/13 , Y02P30/20 , C07C11/02 , C07C15/107
Abstract: Embodiments of methods for production of linear alkylbenzene and optionally biofuel from natural oil are provided. Natural oils are deoxygenated to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. Optionally, a second portion of the paraffins may be processed to form biofuel.
Abstract translation: 提供了用于生产直链烷基苯和任选的天然油生物燃料的方法的实施方案。 天然油被脱氧以形成包含石蜡的料流。 将第一部分链烷烃脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 任选地，第二部分石蜡可以被加工以形成生物燃料。
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