-
公开(公告)号:US3821123A
公开(公告)日:1974-06-28
申请号:US33308973
申请日:1973-02-16
发明人: GERMANAS D , POLLITZER E
IPC分类号: B01J23/755 , B01J37/20 , C07C5/25 , B01J11/74
CPC分类号: B01J37/20 , B01J23/755 , C07C5/2556 , C07C2523/755 , Y10S585/906 , C07C11/08
摘要: Double bond isomerization of olefins utilizing a catalyst comprising nickel and sulfur on a porous carrier; the catalyst being prepared by forming an initial composite of the nickel with the carrier material, sulfiding the initial composite to provide a sulfur/nickel atomic ratio of at least about 0.9 in the sulfided composite, and then stripping sufficient sulfur from the sulfided composite with hydrogen to provide a final isomerization catalyst composition having a sulfur/nickel atomic ratio of less than about 0.9 and more than about 0.55.