公开(公告)号：US07473802B2

公开(公告)日：2009-01-06

申请号：US11514181

申请日：2006-09-01

Applicant: Keizo Kimura ,  Tomohito Masaki ,  Osamu Uchida ,  Katsuyoshi Yamakawa

Inventor： Keizo Kimura ,  Tomohito Masaki ,  Osamu Uchida ,  Katsuyoshi Yamakawa

IPC: C07C55/06 ,  C07C249/00

CPC classification number: C09B53/02 ,  C07C249/02 ,  G11B7/246 ,  C07C251/30

Abstract: A method of producing a near-infrared absorbing dye compound, useful for image forming materials, infrared heat-sensitive recording devices, optical film materials, and the like, containing a process of reacting a compound represented by formula (I) with peroxomonosulfuric acid or its salt. wherein R111, R112, R121, R122, R131, R132, R141 and R142 each independently represent a hydrogen atom, an aliphatic group or an aromatic group; R103, R113, R123, R133 and R143 each independently represent a substituent; and n103, n113, n123, n133 and n143 each independently denote an integer from 0 to 4.

Abstract translation: 一种制造用于成像材料的红外吸收染料化合物的方法，红外热敏记录装置，光学膜材料等，其包含使式（I）表示的化合物与碳酸二氢酸反应的方法或 它的盐 其中R111，R112，R121，R122，R131，R132，R141和R142各自独立地表示氢原子，脂族基团或芳香族基团; R103，R113，R123，R133和R143各自独立地表示取代基; n103，n113，n123，n133和n143各自独立地表示0〜4的整数。

公开(公告)号：US20080221355A1

公开(公告)日：2008-09-11

申请号：US11514181

申请日：2006-09-01

Applicant: Keizo Kimura ,  Tomohito Masaki ,  Osamu Uchida ,  Katsuyoshi Yamakawa

Inventor： Keizo Kimura ,  Tomohito Masaki ,  Osamu Uchida ,  Katsuyoshi Yamakawa

IPC: C07C211/54

CPC classification number: C09B53/02 ,  C07C249/02 ,  G11B7/246 ,  C07C251/30

Abstract: A method of producing a near-infrared absorbing dye compound, useful for image forming materials, infrared heat-sensitive recording devices, optical film materials, and the like, containing a process of reacting a compound represented by formula (I) with peroxomonosulfuric acid or its salt. wherein R111, R112, R121, R122, R131, R132, R141 and R142 each independently represent a hydrogen atom, an aliphatic group or an aromatic group; R103, R113, R123, R133 and R143 each independently represent a substituent; and n103, n113, n123, n133 and n143 each independently denote an integer from 0 to 4.

Abstract translation: 一种制造用于成像材料的红外吸收染料化合物的方法，红外热敏记录装置，光学膜材料等，其包含使式（I）表示的化合物与碳酸二氢酸反应的方法或 它的盐 其中R 111，R 112，R 121，R 122，R 131， R 132，R 141和R 142各自独立地表示氢原子，脂族基团或芳族基团; R 103，R 123，R 123，R 123，R 123和/或每个 独立地表示取代基; 和n 103，n 113，n 123，n 133和n 143， 各自独立地表示0〜4的整数。

公开(公告)号：US20100249461A1

公开(公告)日：2010-09-30

申请号：US12796433

申请日：2010-06-08

Applicant: Tomohito MASAKI ,  Keizo Kimura ,  Osamu Uchida

Inventor： Tomohito MASAKI ,  Keizo Kimura ,  Osamu Uchida

IPC: C07C211/26

CPC classification number: C07C251/30 ,  C07C251/22

Abstract: A triarylamine derivative is represented by the following Formula (I). In Formula (I): R111, R112, R121, R122, R131 and R132 each independently represent a hydrogen atom, an aliphatic group or an aromatic group, provided that R131 and R132 are not both phenyl groups having a group represented by —NR141R142 at a fourth position; R141 and R142 each independently represent a hydrogen atom, an aliphatic group, or an aromatic group; R113, R123 and R133 each independently represent a substituent; n113, n123 and n133 each independently represent an integer of from 0 to 4; and X− represents a counteranion represented by any of the following Formulae (II) to (IV). In Formulae (II) to (IV), R211, R212, R311, R312, R411, R412 and R413 each independently represent an aliphatic group, an aromatic group or a heterocyclic group.

Abstract translation: 三芳基胺衍生物由下式（I）表示。 在式（I）中：R 111，R 112，R 121，R 112，R 131和R 13 2各自独立地表示氢原子，脂族基团或芳基，条件是R 13 1和R 13 2不是具有由-NR 14 R 14 2表示的基团的苯基 第四名; R141和R142各自独立地表示氢原子，脂族基团或芳香族基团; R113，R123和R133各自独立地表示取代基; n113，n123和n133各自独立地表示0〜4的整数， X表示由下述式（II）〜（IV）中的任何一种表示的抗衡阴离子。 在式（II）〜（IV）中，R211，R212，R311，R312，R411，R412和R413各自独立地表示脂族基团，芳香族基团或杂环基。

公开(公告)号：US20080255388A1

公开(公告)日：2008-10-16

申请号：US12100946

申请日：2008-04-10

Applicant: Tomohito MASAKI ,  Keizo Kimura ,  Osamu Uchida

Inventor： Tomohito MASAKI ,  Keizo Kimura ,  Osamu Uchida

IPC: C07C251/24

CPC classification number: C07C251/30 ,  C07C251/22

Abstract: A triarylamine derivative is represented by the following Foimula (I). In Formula (I): R111, R112, R121, R122, R131 and R132 each independently represent a hydrogen atom, an aliphatic group or an aromatic group, provided that R131 and R132 are not both phenyl groups having a group represented by —NR141R142 at a fourth position; R141 and R142 each independently represent a hydrogen atom, an aliphatic group, or an aromatic group; R113, R123 and R133 each independently represent a substituent; n113, n123 and n133 each independently represent an integer of from 0 to 4; and X− represents a counteranion represented by any of the following Formulae (II) to (IV). In Formulae (II) to (IV), R211, R212, R311, R312, R411, R412 and R413 each independently represent an aliphatic group, an aromatic group or a heterocyclic group.

Abstract translation: 三芳基胺衍生物由下列Foimula（I）表示。 在式（I）中：R 111，R 112，R 121，R 122，R 12， 131和R 132各自独立地表示氢原子，脂族基团或芳族基团，条件是R 131和R 132不超过 >不是在第四位置具有由-NR 141 R 141所代表的基团的两个苯基; R 141和R 142各自独立地表示氢原子，脂族基团或芳族基团; R 123，R 123和R 133各自独立地表示取代基; n 123，n 123和n 133各自独立地表示0〜4的整数， 和X-O表示由以下任何式（II）至（IV）表示的抗衡阴离子。 在式（II）至（IV）中，R 211，R 212，R 311，R 312， R 412，R 412和R 412各自独立地表示脂族基团，芳族基团或杂环基团。

公开(公告)号：US20080255387A1

公开(公告)日：2008-10-16

申请号：US12100940

申请日：2008-04-10

Applicant: Tomohito MASAKI ,  Keizo Kimura ,  Osamu Uchida

Inventor： Tomohito MASAKI ,  Keizo Kimura ,  Osamu Uchida

IPC: C07C251/24

CPC classification number: C07C251/22 ,  C07C251/30 ,  C07D207/06 ,  C07D209/08 ,  C07D209/88 ,  C07D215/04 ,  C07D215/10 ,  C07D215/38

Abstract: A triarylamine derivative is represented by the following Formula (I). In Formula (I): R111, R112, R121 and R122 each independently represent a hydrogen atom, an aliphatic group or an aromatic group, R113, R114, R115, R116, R123, R124, R125 and R126 each independently represent a hydrogen atom or a substituent, provided that at least one pair among R111 and R121, R112 and R122, R113 and R123, R114 and R124, R115 and R125 and R116 and R126 includes two different groups; at least one ring may be formed by mutual bonding in at least one pair among R111 and R112, R111 and R114, R113 and R114, R113 and R123, R123 and R124, R121 and R124, R121 and R122, and two R116s which are respectively bound to different phenyl groups; Xm− represents an m-valent anion; m and n represent 1 or 2; and a product of in and n is 2.

Abstract translation: 三芳基胺衍生物由下式（I）表示。 在式（I）中：R 111，R 112，R 121和R 122各自独立地表示氢 原子，脂族基团或芳族基团，R 111，R 114，R 115，R 116， R 124，R 124，R 125和R 126各自独立地表示氢原子或取代基，提供 R 111和R 121之间的至少一对，R 112和R 122，R 12， 113和R 123，R 114和R 124，R 115和R 124， 125和R 116和R 126包括两个不同的基团; 至少一个环可以通过在R 111和R 112中的至少一对中相互键合形成，R 111和/ 114，R 113和R 114，R 113和/或R 12，R 12， 123和R 124，R 121和R 124，R 121和R 124， 122和两个分别与不同苯基结合的R 116; X-m - 表示m价阴离子; m和n表示1或2; 而n和n的乘积为2。

公开(公告)号：US07759504B2

公开(公告)日：2010-07-20

申请号：US12100940

申请日：2008-04-10

Applicant: Tomohito Masaki ,  Keizo Kimura ,  Osamu Uchida

Inventor： Tomohito Masaki ,  Keizo Kimura ,  Osamu Uchida

IPC: C07C50/04 ,  C07C257/00 ,  G03C1/00

CPC classification number: C07C251/22 ,  C07C251/30 ,  C07D207/06 ,  C07D209/08 ,  C07D209/88 ,  C07D215/04 ,  C07D215/10 ,  C07D215/38

Abstract: A triarylamine derivative is represented by the following Formula (I). In Formula (I): R111, R112, R121 and R122 each independently represent a hydrogen atom, an aliphatic group or an aromatic group, R113, R114, R115, R116, R123, R124, R125 and R126 each independently represent a hydrogen atom or a substituent, provided that at least one pair among R111 and R121, R112 and R122, R113 and R123, R114 and R124, R115 and R125 and R116 and R126 includes two different groups; at least one ring may be formed by mutual bonding in at least one pair among R111 and R112, R111 and R114, R113 and R114, R113 and R123, R123 and R124, R121 and R124, R121 and R122, and two R116s which are respectively bound to different phenyl groups; Xm− represents an m-valent anion; m and n represent 1 or 2; and a product of in and n is 2.

Abstract translation: 三芳基胺衍生物由下式（I）表示。 在式（I）中：R 111，R 112，R 121和R 122各自独立地表示氢原子，脂族基或芳基，R 11 3，R 11 4，R 15，R 16，R 123，R 12 4，R 125和R 126各自独立地表示氢原子或 取代基，条件是R111和R121，R112和R122，R113和R123，R114和R124，R115和R125以及R116和R126中至少有一对包括两个不同的基团; 可以通过R111和R112，R111和R114，R113和R114，R113和R123，R123和R124，R121和R124，R121和R122中的至少一对中相互键合形成至少一个环，以及两个R116 结合不同的苯基; Xm-表示m价阴离子; m和n表示1或2; 而n和n的乘积为2。

公开(公告)号：US20100224839A1

公开(公告)日：2010-09-09

申请号：US12295281

申请日：2007-03-12

Applicant: Keizo Kimura ,  Osamu Uchida ,  Katsuyoshi Yamakawa

Inventor： Keizo Kimura ,  Osamu Uchida ,  Katsuyoshi Yamakawa

IPC: F21V9/04

CPC classification number: C09B53/02 ,  C09B57/008 ,  G02B5/208 ,  G02B5/223

Abstract: The invention provides a near-infrared absorbing material, including: at least one of at least one singlet oxygen scavengers, at least one radical scavenger, and at least one antioxidant; and at least one near-infrared absorbing compound obtained by oxidation of a compound represented by the following Formula (II). In the formula, R211, R212, R221, R222, R231, R232, R241 and R242 independently represent a hydrogen atom or an aliphatic or aromatic group; R203, R213, R223, R233 and R243 independently represent a substituent; and n203, n213, n223, n233 and n243 independently represent an integer of 0 to 4.

Abstract translation: 本发明提供近红外吸收材料，其包括：至少一种单线态氧清除剂，至少一种自由基清除剂和至少一种抗氧化剂中的至少一种; 和通过氧化由下式（II）表示的化合物获得的至少一种近红外吸收化合物。 在该式中，R211，R212，R221，R222，R231，R232，R241和R242独立地表示氢原子或脂族或芳族基团; R203，R213，R223，R233和R243独立地表示取代基; n203，n213，n223，n233和n243独立地表示0〜4的整数。

公开(公告)号：US08304538B2

公开(公告)日：2012-11-06

申请号：US12680377

申请日：2008-09-25

Applicant: Keizo Kimura ,  Takashi Kitagawa ,  Osamu Uchida

Inventor： Keizo Kimura ,  Takashi Kitagawa ,  Osamu Uchida

IPC: C07D265/22 ,  C07D413/04

CPC classification number: C07D265/18 ,  C07D265/12 ,  C07D265/36 ,  C07D413/04 ,  C07D413/14

Abstract: A method of producing a compound represented by Formula (I), which comprises a step A of reacting an anthranilic acid compound with a carboxylic halide in the absence of a base, but does not comprise a step of isolating of an amide intermediate compound represented by Formula (II): wherein R1 represents a substituent; n1 is an integer of 0 to 4; R2 represents an n2-valent substituent or a linking group; and n2 is an integer of 1 to 4.

Abstract translation: 一种制备由式（I）表示的化合物的方法，其包括在不存在碱的情况下使邻氨基苯甲酸化合物与羧酰卤反应的步骤A，但不包括以下步骤：分离由 式（II）：其中R1表示取代基; n1为0〜4的整数， R2代表n2价取代基或连接基团; n2为1〜4的整数。

公开(公告)号：US08021573B2

公开(公告)日：2011-09-20

申请号：US11845130

申请日：2007-08-27

Applicant: Keizo Kimura ,  Katsuyoshi Yamakawa ,  Osamu Uchida

Inventor： Keizo Kimura ,  Katsuyoshi Yamakawa ,  Osamu Uchida

IPC: G02B5/22 ,  C09K11/06 ,  C07C251/30

CPC classification number: G02B5/223 ,  C09B23/145 ,  C09B57/00 ,  C09B57/008 ,  C09B57/02 ,  G02B5/208

Abstract: The present invention provides a near-infrared-absorbing material including: a luminescent agent, and a near-infrared-absorbing compound obtained by oxidizing a compound represented by the following formula (II): wherein R211, R212, R221, R222, R231, R232, R241 and R242 each independently represent a hydrogen atom, an aliphatic group or an aromatic group; R203, R213, R223, R233 and R243 each independently represent a substituent group; and n203, n213, n223, n233 and n243 each independently represent an integer from 0 to 4.

Abstract translation: 本发明提供了一种近红外吸收材料，其包括：发光剂和通过氧化由下式（II）表示的化合物获得的近红外吸收化合物：其中R211，R212，R221，R222，R231， R232，R241和R242各自独立地表示氢原子，脂族基团或芳香族基团; R203，R213，R223，R233和R243各自独立地表示取代基; n203，n213，n223，n233和n243各自独立地表示0〜4的整数。

公开(公告)号：US20080067479A1

公开(公告)日：2008-03-20

申请号：US11845130

申请日：2007-08-27

Applicant: Keizo KIMURA ,  Katsuyoshi Yamakawa ,  Osamu Uchida

Inventor： Keizo KIMURA ,  Katsuyoshi Yamakawa ,  Osamu Uchida

IPC: G03C1/00

CPC classification number: G02B5/223 ,  C09B23/145 ,  C09B57/00 ,  C09B57/008 ,  C09B57/02 ,  G02B5/208

Abstract: The present invention provides a near-infrared-absorbing material including: a luminescent agent, and a near-infrared-absorbing compound obtained by oxidizing a compound represented by the following formula (II): wherein R211, R212, R221, R222, R231, R232, R241 and R242 each independently represent a hydrogen atom, an aliphatic group or an aromatic group; R203, R213, R223, R233 and R243 each independently represent a substituent group; and n203, n213, n223, n233 and n243 each independently represent an integer from 0 to 4.

Abstract translation: 本发明提供一种近红外吸收材料，其包括：发光剂和通过氧化由下式（II）表示的化合物获得的近红外吸收化合物：其中R 211， R 212，R 221，R 222，R 23，R 23，R 22， R 241和R 242各自独立地表示氢原子，脂族基团或芳族基团; R 203，R 213，R 223，R 223和R 243各自独立地选自 独立地表示取代基; 和n 203，n 213，n 223，n 233和n 23 23， 各自独立地表示0〜4的整数。