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公开(公告)号:US12138962B2
公开(公告)日:2024-11-12
申请号:US18576033
申请日:2022-03-25
Applicant: The Yokohama Rubber Co., Ltd.
Inventor: Hiroki Sugimoto , Rie Nakajima
Abstract: A rubber composition contains 10-50 parts by mass of a thermoplastic resin in 100 parts by mass of a diene rubber containing 60 mass % or more of a styrene-butadiene rubber having a styrene content of 5-30 mass % and a vinyl content of 10-35 mass %. In a mixture containing the diene rubber and the thermoplastic resin in a mass ratio of 1:1, a difference (Tga-Tgm) between a theoretical value (Tga) of a glass transition temperature of the mixture calculated based on an average glass transition temperature (Tg1) of the diene rubber and a glass transition temperature (Tg2) of the thermoplastic resin, and a measurement value (Tgm) of a glass transition temperature of the mixture, is 5-50° C., and a difference (Tg2-Tg1) is 110-150° C. An amount of the thermoplastic resin is 30 mass % or more in 100 mass % total of a plasticizer component contained in the rubber composition.
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公开(公告)号:US12104046B2
公开(公告)日:2024-10-01
申请号:US18576038
申请日:2022-03-25
Applicant: The Yokohama Rubber Co., Ltd.
Inventor: Hiroki Sugimoto , Rie Nakajima
IPC: C08L15/00 , B60C1/00 , C08K3/36 , C08K5/5419
CPC classification number: C08L15/00 , B60C1/0016 , C08K3/36 , C08K5/5419 , C08L2205/03
Abstract: A rubber composition contains 10-50 parts by mass of a thermoplastic resin in 100 parts by mass of a diene rubber containing 60 mass % or more of a styrene-butadiene rubber having a styrene content of 5-30 mass % and a vinyl content of 10-35 mass %. In a mixture containing the diene rubber and the thermoplastic resin in a mass ratio of 1:1, a difference (Tga−Tgm) between a theoretical value (Tga) of a glass transition temperature of the mixture calculated based on an average glass transition temperature (Tg1) of the diene rubber and a glass transition temperature (Tg2) of the thermoplastic resin, and a measurement value (Tgm) of a glass transition temperature of the mixture, is lower than 5° C., and a difference (Tg2−Tg1) is 50-105° C. An amount of the thermoplastic resin is 30 mass % or more in 100 mass % total of a plasticizer component contained in the rubber composition.
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公开(公告)号:US11267954B2
公开(公告)日:2022-03-08
申请号:US16485244
申请日:2018-02-14
Applicant: THE YOKOHAMA RUBBER CO., LTD.
Inventor: Hiroki Sugimoto , Tsuyoshi Nomaguchi
Abstract: A rubber composition including 100 parts by mass of a diene rubber containing natural rubber, and blended with from 40 to 80 parts by mass of carbon black, cobalt neodecanoate borate represented by the following Chemical Formula (1), a phenolic resin, a curing agent, sulfur, and a vulcanization accelerator, wherein the carbon black has DBP oil absorption of from 50×10−5 to 80×10−5 m3/kg, and iodine adsorption of from 100 to 150 g/kg, and a vulcanized rubber has characteristics of a dynamic storage modulus (E′) at a dynamic strain of 2% and at 20° C. of 8 MPa or more, a tangent loss (tan δ) at 60° C. of 0.20 or less, and the number of times of repetition until fracture is caused in a constant strain fatigue test at a strain of 60% and at 400 rpm of 45,000 or more.
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公开(公告)号:US10647833B2
公开(公告)日:2020-05-12
申请号:US15327362
申请日:2015-07-17
Applicant: The Yokohama Rubber Co., LTD.
Inventor: Shin Tsukishima , Miyuki Oka , Keisuke Murase , Hiroki Sugimoto
IPC: C08K13/02 , C08K5/548 , C08L9/00 , C08K3/36 , C08K5/098 , C08K5/5419 , C08L9/06 , C08K5/103 , C08K5/40 , C08K3/04 , B60C1/00
Abstract: The present technology provides a rubber composition containing: (A) a diene rubber, (B) from 5 to 200 parts by mass of silica per 100 parts by mass of the diene rubber, (C) from 1 to 20 mass % of a sulfur-containing silane coupling agent relative to the amount of the silica, (D) for example, from 1 to 20 mass % of n-octyltriethoxysilane relative to the amount of the silica; and (E) from 1 to 20 mass % of a glycerol monofatty acid ester derived from a fatty acid having from 8 to 24 carbons relative to the mass of the silica (B).
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公开(公告)号:US20170158842A1
公开(公告)日:2017-06-08
申请号:US15327362
申请日:2015-07-17
Applicant: The Yokohama Rubber Co., LTD.
Inventor: Shin Tsukishima , Miyuki Oka , Keisuke Murase , Hiroki Sugimoto
CPC classification number: C08K13/02 , B60C1/0016 , C08K3/04 , C08K3/36 , C08K5/098 , C08K5/103 , C08K5/40 , C08K5/5419 , C08K5/548 , C08L9/00 , C08L9/06 , Y02T10/862
Abstract: The present technology provides a rubber composition containing: (A) a diene rubber, (B) from 5 to 200 parts by mass of silica per 100 parts by mass of the diene rubber, (C) from 1 to 20 mass % of a sulfur-containing silane coupling agent relative to the amount of the silica, (D) for example, from 1 to 20 mass % of n-octyltriethoxysilane relative to the amount of the silica; and (E) from 1 to 20 mass % of a glycerol monofatty acid ester derived from a fatty acid having from 8 to 24 carbons relative to the mass of the silica (B).
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公开(公告)号:US11787923B2
公开(公告)日:2023-10-17
申请号:US16077405
申请日:2017-02-08
Applicant: The Yokohama Rubber Co., LTD.
Inventor: Hiroki Sugimoto , Shuichi Nakano , Makoto Ashiura
CPC classification number: C08L9/06 , B60C1/0016 , C08L23/22 , C08L25/00 , C08L83/04 , C08K3/36 , C08K5/40 , C08K2201/006
Abstract: A rubber composition of the present technology contains: diene rubber (A) containing a predetermined amount of specific conjugated diene rubber represented by a predetermined formula; silica having a CTAB adsorption specific surface area in a predetermined range; and a silane coupling agent represented by a predetermined formula.
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公开(公告)号:US20210171746A1
公开(公告)日:2021-06-10
申请号:US16077405
申请日:2017-02-08
Applicant: The Yokohama Rubber Co., LTD.
Inventor: Hiroki Sugimoto , Shuichi Nakano , Makoto Ashiura
Abstract: A rubber composition of the present technology contains: diene rubber (A) containing a predetermined amount of specific conjugated diene rubber represented by a predetermined formula; silica having a CTAB adsorption specific surface area in a predetermined range; and a silane coupling agent represented by a predetermined formula.
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公开(公告)号:US10450454B2
公开(公告)日:2019-10-22
申请号:US15507191
申请日:2015-08-24
Applicant: The Yokohama Rubber Co., LTD.
Inventor: Hiroki Sugimoto , Makoto Ashiura
Abstract: A diene-based rubber contains natural rubber and specific conjugated diene-based rubber. The content of the natural rubber in the diene-based rubber is 30 to 45 mass %. The content of the specific conjugated diene-based rubber in the diene-based rubber is 30 to 70 mass %. The specific conjugated diene-based rubber is conjugated diene-based rubber produced according to a specific production method. In the conjugated diene-based rubber, the aromatic vinyl unit content, the vinyl bond content, and the weight average molecular weight are within a predetermined range. The CTAB adsorption specific surface area of the silica is 180 m2/g or greater. The content of the silica is less than 60 parts by mass per 100 parts by mass of the diene-based rubber.
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公开(公告)号:US10407517B2
公开(公告)日:2019-09-10
申请号:US15507216
申请日:2015-08-24
Applicant: The Yokohama Rubber Co., LTD.
Inventor: Yusuke Iizuka , Hiroki Sugimoto , Makoto Ashiura
IPC: C08K3/36 , C08C19/30 , B60C1/00 , C08K5/098 , C08K5/5419 , C08K5/548 , C08C19/34 , C08C19/36 , C08C19/38 , C08F8/42 , C08F297/04 , C08L53/02
Abstract: A rubber composition for tires of the present technology contains a diene rubber, silica, a silane coupling agent, a fatty acid metal salt, and a predetermined alkyltrialkoxysilane; the diene rubber containing 60 mass % or greater of a modified conjugated diene rubber and 30 mass % or greater of a particular conjugated diene rubber which corresponds to a part or all of the modified conjugated diene rubber; an average glass transition temperature of the diene rubber being from −45 to −20° C.; the particular conjugated diene rubber being a conjugated diene rubber produced by a particular production method and having predetermined ranges of aromatic vinyl unit content, vinyl bond content, and weight average molecular weight.
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公开(公告)号:US20180237631A1
公开(公告)日:2018-08-23
申请号:US15507191
申请日:2015-08-24
Applicant: THE YOKOHAMA RUBBER CO., LTD.
Inventor: Hiroki Sugimoto , Makoto Ashiura
CPC classification number: C08L53/025 , B60C1/0016 , C08K3/36 , C08L7/00 , C08L15/00 , C08L2205/03 , Y02T10/862 , C08L9/06 , C08L91/00 , C08L47/00 , C08K3/04 , C08K3/22 , C08K5/09 , C08K3/06 , C08K5/548 , C08K5/47
Abstract: A diene-based rubber contains natural rubber and specific conjugated diene-based rubber. The content of the natural rubber in the diene-based rubber is 30 to 45 mass %. The content of the specific conjugated diene-based rubber in the diene-based rubber is 30 to 70 mass %. The specific conjugated diene-based rubber is conjugated diene-based rubber produced according to a specific production method. In the conjugated diene-based rubber, the aromatic vinyl unit content, the vinyl bond content, and the weight average molecular weight are within a predetermined range. The CTAB adsorption specific surface area of the silica is 180 m2/g or greater. The content of the silica is less than 60 parts by mass per 100 parts by mass of the diene-based rubber.
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