公开(公告)号：US06554884B1

公开(公告)日：2003-04-29

申请号：US09695512

申请日：2000-10-24

申请人： Terrance B. Tripp ,  Barbara L. Cox

发明人： Terrance B. Tripp ,  Barbara L. Cox

IPC分类号： B22F100

CPC分类号： H01G9/0525 ,  C22C27/02 ,  C22C29/16 ,  C22C32/0068

摘要： A process for producing sintered pellets made from blends of refractory metal and refractory metal nitride powders were found to have a higher fraction of intra-agglomerate pores than those made from the refractory metal or refractory metal nitride alone resulting in improved capacitor grade powders, anodes and finished capacitors therefrom. The pellet porosity and total intrusion volume maximizes when the mixture is in the 50-75 W/W % refractory metal nitride range. The total pellet pore surface area was found to be relatively independent of refractory metal nitride concentration above 50%. A substrate consisting of a 50/50 or 25/75 W/W % refractory metal/refractory metal nitride powder mixture should produce solid capacitors with higher capacitance recovery and lower ESR.

摘要翻译： 发现由难熔金属和难熔金属氮化物粉末的共混物制成的烧结颗粒的方法具有比由难熔金属或难熔金属氮化物单独制成的凝聚细孔更高的部分，导致改进的电容器级粉末，阳极和 成品电容器。 当混合物在50-75W / W％难熔金属氮化物范围内时，颗粒孔隙率和总侵入体积最大化。 发现总颗粒孔表面积相对独立于高于50％的难熔金属氮化物浓度。 由50/50或25/75 W / W％的耐火金属/难熔金属氮化物粉末混合物组成的基体应产生具有较高电容恢复率和较低ESR的固体电容器。

公开(公告)号：US06515846B1

公开(公告)日：2003-02-04

申请号：US09499857

申请日：2000-02-07

申请人： Terrance B. Tripp

发明人： Terrance B. Tripp

IPC分类号： H01G9145

CPC分类号： H01G9/042 ,  C01B21/0617 ,  C01P2006/80 ,  C04B35/58 ,  C04B35/58007 ,  C04B2235/3852 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/5409 ,  C04B2235/608 ,  C04B2235/72 ,  C04B2235/721 ,  C04B2235/726 ,  C04B2235/79 ,  H01G4/12 ,  H01G4/1254 ,  H01G9/0525 ,  Y10T29/417

摘要： Metal nitride compound powder substrate for capacitor anodic oxide film and the substrate interface therebetween, characterized, relative to un-nitrided analogs, by reduced temperature bias and frequency dependencies of capacitance, the substrate-anodic oxide interface being substantially insensitive to heating compared to the un-nitrided analog.

摘要翻译： 用于电容器阳极氧化膜的金属氮化物化合物粉末基板和其间的基板界面，其特征在于相对于未氮化的类似物，通过降低温度偏置和电容的频率依赖性，基板 - 阳极氧化物界面对于加热基本上不敏感，与un 微型模拟

公开(公告)号：US06927967B2

公开(公告)日：2005-08-09

申请号：US10321861

申请日：2002-12-17

申请人： Terrance B. Tripp

发明人： Terrance B. Tripp

IPC分类号： C04B35/58 ,  C01B21/06 ,  H01G4/12 ,  H01G9/04 ,  H01G9/042 ,  H01G9/052 ,  H01G9/145

CPC分类号： H01G9/042 ,  C01B21/0617 ,  C01P2006/80 ,  C04B35/58 ,  C04B35/58007 ,  C04B2235/3852 ,  C04B2235/3886 ,  C04B2235/3895 ,  C04B2235/5409 ,  C04B2235/608 ,  C04B2235/72 ,  C04B2235/721 ,  C04B2235/726 ,  C04B2235/79 ,  H01G4/12 ,  H01G4/1254 ,  H01G9/0525 ,  Y10T29/417

摘要： Electrolytic capacitor powder substrates are provided of refractory metal nitrides to reduce instability at a substrate-oxide (as formed) interface whereby the resultant capacitor sensitivity to hear, bias and frequency is reduced.

摘要翻译： 提供难熔金属氮化物的电解电容器粉末基底，以减少基底氧化物（形成）界面处的不稳定性，从而降低所得到的电容器的听觉，偏压和频率灵敏度。

公开(公告)号：US06716389B2

公开(公告)日：2004-04-06

申请号：US10280295

申请日：2002-10-25

申请人： Terrance B. Tripp ,  Barbara L. Cox

发明人： Terrance B. Tripp ,  Barbara L. Cox

IPC分类号： B22F300

CPC分类号： H01G9/0525 ,  C22C27/02 ,  C22C29/16 ,  C22C32/0068

摘要： A process for producing sintered pellets made from blends of refractory metal and refractory metal nitride powders were found to have a higher fraction of intra-agglomerate pores than those made from the refractory metal or refractory metal nitride alone resulting in improved capacitor grade powders, anodes and finished capacitors therefrom. The pellet porosity and total intrusion volume maximizes when the mixture is in the 50-75 W/W % refractory metal nitride range. The total pellet pore surface area was found to be relatively independent of refractory metal nitride concentration above 50%. A substrate consisting of a 50/50 or 25/75 W/W % refractory metal/refractory metal nitride powder mixture should produce solid capacitors with higher capacitance recovery and lower ESR.

摘要翻译： 发现由难熔金属和难熔金属氮化物粉末的共混物制成的烧结颗粒的方法具有比由难熔金属或难熔金属氮化物单独制成的凝聚细孔更高的部分，导致改进的电容器级粉末，阳极和 成品电容器。 当混合物在50-75W / W％难熔金属氮化物范围内时，颗粒孔隙率和总侵入体积最大化。 发现总颗粒孔表面积相对独立于高于50％的难熔金属氮化物浓度。 由50/50或25/75 W / W％的耐火金属/难熔金属氮化物粉末混合物组成的基体应产生具有较高电容恢复率和较低ESR的固体电容器。

公开(公告)号：US4957541A

公开(公告)日：1990-09-18

申请号：US265498

申请日：1988-11-01

申请人： Terrance B. Tripp ,  Richard W. Hildreth

发明人： Terrance B. Tripp ,  Richard W. Hildreth

IPC分类号： B22F9/24 ,  C22C1/04 ,  H01G9/052

CPC分类号： H01G9/0525 ,  B22F9/24 ,  C22C1/045

摘要： Tantalum powders of capacitor grade are provided, containing interacting silicon and phosphorous dopants to effect low D.C. leakage of electrolytic capacitors having anodes made from such powders, with anodic formation at low temperatures (40.degree.-60.degree. C.), consistent with high capacitance.

公开(公告)号：US07090762B2

公开(公告)日：2006-08-15

申请号：US10634423

申请日：2003-08-05

申请人： Terrance B. Tripp ,  Brian John Melody ,  John Tony Kinard ,  David Alexander Wheeler ,  Duane Earl Stenzinger

发明人： Terrance B. Tripp ,  Brian John Melody ,  John Tony Kinard ,  David Alexander Wheeler ,  Duane Earl Stenzinger

IPC分类号： C25D11/02 ,  C25D9/02

CPC分类号： C25D9/02 ,  C25D5/54 ,  C25D11/26 ,  H01G9/028 ,  H01G9/042

摘要： The metal oxide surface coating of an anodized valve metal may be made conductive under certain conditions so that conductive coatings can be electrolytically deposited on the surface of the oxide. When a dry polar aprotic electrolyte solution is used at a reduced temperature and a relatively high field is applied, the oxide ceases to be insulative. The process is reversible, meaning that there is no permanent change in the oxide.

摘要翻译： 阳极氧化阀金属的金属氧化物表面涂层可以在某些条件下导电，使得导电涂层可以电解沉积在氧化物的表面上。 当干燥的极性非质子电解质溶液在降低的温度下使用并且施加相对较高的场时，氧化物不再是绝缘的。 该过程是可逆的，意味着氧化物没有永久的变化。

公开(公告)号：US06171363B2

公开(公告)日：2001-01-09

申请号：US09073488

申请日：1998-05-06

申请人： Leonid N. Shekhter ,  Terrance B. Tripp ,  Leonid L. Lanin

发明人： Leonid N. Shekhter ,  Terrance B. Tripp ,  Leonid L. Lanin

IPC分类号： B22F922

CPC分类号： H01G9/0525 ,  B22F9/22 ,  C22B5/04 ,  C22B34/24

摘要： Metal powder from the group Ta, Nb, Ti, Mo, W, V, Zr, Hf preferrably Ta or Nb, is made in a fine powder form by reduction of metal oxide by contact with a gaseous reducing agent, preferrably an alkaline earth metal, to near complete reduction, leaching, further deoxidation and agglomeration, the powder so produced being sinterable to capacitor anode form and processable to other usages.

摘要翻译： 来自Ta，Nb，Ti，Mo，W，V，Zr，Hf族优选的Ta或Nb的金属粉末通过与气态还原剂接触而还原金属氧化物而制成细粉末，优选为碱土金属 ，为了接近完全还原，浸出，进一步脱氧和附聚，所生产的粉末可与电容器阳极形式烧结并可加工成其他用途。

公开(公告)号：US5470525A

公开(公告)日：1995-11-28

申请号：US269580

申请日：1994-07-01

申请人： Terrance B. Tripp ,  Malcolm Shaw

发明人： Terrance B. Tripp ,  Malcolm Shaw

IPC分类号： B22F1/00 ,  B22F3/10 ,  H01G9/00 ,  H01G9/15

CPC分类号： H01G9/15 ,  B22F1/0088 ,  B22F3/1025

摘要： Tantalum anode pellets or tantalum powders are treated to remove carbon content (mostly attributable to binders used in pressing the powders to pellet form and/or sintering of the pellets) by an aqueous leach at 50.degree.-200.degree. F. in lieu of the conventional complex distillation/decomposition methods.

摘要翻译： 处理钽阳极丸或钽粉以除去碳含量（主要归因于用于将粉末压制成颗粒形式和/或烧结颗粒的粘合剂）通过在-50°-200°F的水性浸出代替常规 复合蒸馏/分解方法。

公开(公告)号：US07678175B2

公开(公告)日：2010-03-16

申请号：US11591137

申请日：2006-11-01

申请人： Leonid N. Shekhter ,  Terrance B. Tripp ,  Leonid L. Lanin ,  Anastasia M. Conlon ,  Howard V. Goldberg

发明人： Leonid N. Shekhter ,  Terrance B. Tripp ,  Leonid L. Lanin ,  Anastasia M. Conlon ,  Howard V. Goldberg

IPC分类号： C22C27/02

CPC分类号： H01G9/0525 ,  B22F1/0014 ,  B22F9/20 ,  B22F2998/00 ,  C01G23/043 ,  C01G31/02 ,  C01G33/00 ,  C01G37/02 ,  C01G39/02 ,  C01G41/02 ,  C01P2004/03 ,  C01P2004/50 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/17 ,  C01P2006/34 ,  C01P2006/40 ,  C01P2006/80 ,  H01G9/04 ,  H01G9/052 ,  B22F1/0096 ,  B22F2201/40 ,  B22F2201/11

摘要： High purity refractory metals, valve metals, refractory metal oxides, valve metal oxides, or alloys thereof suitable for a variety of electrical, optical and mill product/fabricated parts usages are produced from their respective oxides by metalothermic reduction of a solid or liquid form of such oxide using a reducing agent that establishes (after ignition) a highly exothermic reaction, the reaction preferably taking place in a continuously or step-wise moving oxide such as gravity fall with metal retrievable at the bottom and an oxide of the reducing agent being removable as a gas or in other convenient form and unreacted reducing agent derivatives being removable by leaching or like process.

摘要翻译： 适用于各种电气，光学和制造产品/制造部件的高纯度难熔金属，阀金属，难熔金属氧化物，阀金属氧化物或其合金用途是通过其各自的氧化物通过固体或液体形式的金属热还原 这种氧化物使用建立（点燃后）高度放热反应的还原剂，反应优选在连续或逐步移动的氧化物如重力中发生，金属在底部可回收，还原剂的氧化物是可除去的 作为气体或以其他方便的形式，并且未反应的还原剂衍生物可通过浸出或类似方法除去。

公开(公告)号：US07150776B2

公开(公告)日：2006-12-19

申请号：US10792493

申请日：2004-03-03

申请人： Leonid N. Shekhter ,  Terrance B. Tripp ,  Leonid L. Lanin ,  Anastasia M. Conlon ,  Howard V. Goldberg

发明人： Leonid N. Shekhter ,  Terrance B. Tripp ,  Leonid L. Lanin ,  Anastasia M. Conlon ,  Howard V. Goldberg

IPC分类号： C22C27/02

CPC分类号： H01G9/0525 ,  B22F1/0014 ,  B22F9/20 ,  B22F2998/00 ,  C01G23/043 ,  C01G31/02 ,  C01G33/00 ,  C01G37/02 ,  C01G39/02 ,  C01G41/02 ,  C01P2004/03 ,  C01P2004/50 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/17 ,  C01P2006/34 ,  C01P2006/40 ,  C01P2006/80 ,  H01G9/04 ,  H01G9/052 ,  B22F1/0096 ,  B22F2201/40 ,  B22F2201/11

摘要： High purity refractory metals, valve metals, refractory metal oxides, valve metal oxides, or alloys thereof suitable for a variety of electrical, optical and mill product/fabricated parts usages are produced from their respective oxides by metalothermic reduction of a solid or liquid form of such oxide using a reducing agent that establishes (after ignition) a highly exothermic reaction, the reaction preferably taking place in a continuously or step-wise moving oxide such as gravity fall with metal retrievable at the bottom and an oxide of the reducing agent being removable as a gas or in other convenient form and unreacted reducing agent derivatives being removable by leaching or like process.