Process for producing a shaped silicon carbide-based ceramic article
    2.
    发明授权
    Process for producing a shaped silicon carbide-based ceramic article 失效
    用于制造成形碳化硅基陶瓷制品的方法

    公开(公告)号:US4897229A

    公开(公告)日:1990-01-30

    申请号:US254370

    申请日:1988-10-05

    IPC分类号: C04B35/571 C04B35/622

    CPC分类号: C04B35/62227 C04B35/571

    摘要: A shaped silicon carbide-based ceramic article having an improved mechanical strength is produced at a high efficiency by a process comprising the step of: forming an organic silicon polymer, for example, polycarbosilastyrene copolymer, into a predetermined shape, for example, a filament or film; doping the shaped polymer with a doping material consisting of at least one type of halogen, for example, bromine or iodine, in an amount of 0.01% to 150% based on the weight of the shaped polymer, to render the shaped polymer infusible; and pyrolyzing the infusible shaped polymer into a shaped SiC-based ceramic article at a temperature of 800.degree. C. to 1400.degree. C. in an inert gas atmosphere, optionally the halogen-doped shaped polymer being treated with a basic material, for example, ammonia, before the pyrolyzing step, to make the filament uniformly infusible.

    Shaped silion carbide-eased ceramic article
    4.
    发明授权
    Shaped silion carbide-eased ceramic article 失效
    形状的碳化硅硬化陶瓷制品

    公开(公告)号:US5091271A

    公开(公告)日:1992-02-25

    申请号:US420560

    申请日:1989-10-12

    IPC分类号: C04B35/571 C04B35/622

    摘要: A shaped silicon carbide-based ceramic article having an improved mechanical strength is produced at a high efficiency by a process comprising the step of: forming an organic silicone polymer, for example, polycarbosilastyrene copolymer, into a predetermined shape, for example, a filament or film; doping the shaped polymer with a doping material consisting of at least one type of halogen, for example, bromine or iodine, in an amount of 0.01% to 150% based on the weight of the shaped polymer, to render the shaped polymer infusible; and pyrolyzing the infusible shaped polymer into a shaped SiC-based ceramic article at a temperature of 800.degree. C. to 1400.degree. C. in an inert gas atmosphere, optionally the halogen-doped shaped polymer being treated with a basic material, for example, ammonia, before the pyrolyzing step, to make the filament uniformly infusible.

    摘要翻译: 通过包括以下步骤的方法以高效率生产具有改善的机械强度的成形碳化硅基陶瓷制品:将有机硅氧烷聚合物,例如聚碳硅烷基苯乙烯共聚物形成预定形状,例如长丝或 电影; 使用由至少一种类型的卤素(例如溴或碘)组成的掺杂材料,以成形聚合物的重量计为0.01%至150%的量掺杂成型聚合物,以使成形聚合物不熔化; 并在惰性气体气氛中,在800℃至1400℃的温度下将可熔成形聚合物热解成成型的SiC基陶瓷制品,任选地,用碱性材料处理的掺杂卤素的聚合物,例如, 氨,在热解步骤之前,使细丝均匀地不熔融。