公开(公告)号：US20160059212A1

公开(公告)日：2016-03-03

申请号：US14842490

申请日：2015-09-01

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA ,  Japan Advanced Institute of Science and Technology

发明人： Masaki WATANABE ,  Mamoru ISHIKIRIYAMA ,  Noriyoshi MATSUMI ,  Vedarajan RAMAN ,  Surabhi GUPTA ,  Jain KAMIYA

IPC分类号： B01J20/28 ,  G01N27/02 ,  B01J20/22

CPC分类号： B01J20/2805 ,  B01D53/02 ,  B01D53/261 ,  B01D53/28 ,  B01D2252/30 ,  B01D2253/106 ,  B01D2253/20 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2253/308 ,  B01D2257/80 ,  B01D2259/40088 ,  B01J20/22 ,  B01J20/28011 ,  B01J20/28083 ,  B01J20/28097 ,  B01J20/3255 ,  B01J20/3287 ,  F24F3/1411

摘要： Provided is a water vapor adsorption-desorption material in which a substance having a LCST is uniformly retained inside pores of a mesoporous body, which can reduce energy required for regeneration, and a method for measuring LCST behavior capable of measuring LCST behavior of an ionic liquid used in the water vapor adsorption-desorption material without errors. The water vapor adsorption-desorption material includes a mesoporous body and an ionic liquid retained inside pores of the mesoporous body, the ionic liquid exhibiting LCST behavior, and the method for measuring LCST behavior of an ionic liquid used for a water vapor adsorption-desorption material, the method including detecting a change of hydration/dehydration state of a mixture of the ionic liquid and water as electric signals, by means of AC impedance measurement.

摘要翻译： 提供一种水蒸汽吸附 - 解吸材料，其中具有LCST的物质被均匀地保留在介孔体的孔内，这可以降低再生所需的能量，以及用于测量能够测量离子液体的LCST行为的LCST行为的方法 用于水蒸气吸附 - 解吸材料无误差。 水蒸气吸附 - 解吸材料包括介孔体和保留在介孔体的孔内的离子液体，表现出LCST行为的离子液体，以及用于测量用于水蒸汽吸附 - 解吸材料的离子液体的LCST行为的方法 该方法包括通过AC阻抗测量来检测作为电信号的离子液体和水的混合物的水合/脱水状态的变化。

公开(公告)号：US20160144342A1

公开(公告)日：2016-05-26

申请号：US14943572

申请日：2015-11-17

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA

发明人： Masaki WATANABE ,  Mamoru ISHIKIRIYAMA

IPC分类号： B01J20/28 ,  B01J20/32

CPC分类号： B01J20/28097 ,  B01J20/28011 ,  B01J20/28083 ,  B01J20/3204 ,  B01J20/3217 ,  B01J20/3219 ,  B01J20/3248 ,  B01J20/3272 ,  B01J20/3291

摘要： Provided is a temperature-responsive hygroscopic material having a hygroscopic property that varies widely according to temperature variation and a method for producing the temperature-responsive hygroscopic material. The temperature-responsive hygroscopic material includes a mesoporous body having an average pore diameter of 2 nm to less than 50 nm and a temperature sensitive molecule chemically bonded with the mesoporous body inside a pore of the mesoporous body. The method includes a step of causing, in a solvent including an activator and a coupling agent, a coupling reaction of: a mesoporous body having an average diameter of 2 nm to less than 50 nm and having a functional group on a surface thereof; and a temperature sensitive molecule having a functional group which can undergo a coupling reaction with the functional group on the surface of the mesoporous body.

摘要翻译： 提供一种具有根据温度变化而广泛变化的吸湿性的温度敏感性吸湿材料和用于制备温度响应性吸湿材料的方法。 温度敏感性吸湿材料包括平均孔径为2nm以上且小于50nm的介孔体，以及与介孔体的孔内部的介孔体化学键合的温度敏感性分子。 该方法包括在包含活化剂和偶联剂的溶剂中引入平均直径为2nm至小于50nm并在其表面具有官能团的介孔体的偶联反应的步骤; 以及具有可与介孔体的表面上的官能团发生偶联反应的官能团的温度敏感性分子。

公开(公告)号：US20150224483A1

公开(公告)日：2015-08-13

申请号：US14614738

申请日：2015-02-05

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA ,  National University Corporation Nagoya University

发明人： Masao WATANABE ,  Mamoru ISHIKIRIYAMA ,  Youhei KINOSHITA ,  Nagahiro SAITO ,  Tomohito SUDARE

IPC分类号： B01J23/89 ,  B01J19/08 ,  B01J35/00 ,  H01L35/16 ,  B01J37/34

CPC分类号： B01J23/8926 ,  B01J19/088 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/349 ,  B01J2219/0813 ,  B01J2219/089 ,  B01J2219/0894 ,  B22F1/0018 ,  B22F1/025 ,  B22F9/24 ,  B22F2999/00 ,  H01L35/16 ,  B22F2202/13

摘要： A method and apparatus for producing core-shell type metal nanoparticles which are excellent in productivity are provided, in particular, the present invention provides a method of production of core-shell type metal nanoparticles including (a) a step of introducing a solution of a salt of a first metal to a first flow path of a flow type reaction apparatus and applying plasma to the solution of the salt of the first metal in the first flow path to obtain a solution which contains metal nanoparticles of the first metal and (b) a step of introducing a solution of a salt of a second metal to a second flow path of the flow type reaction apparatus, making it merge with the solution which contains metal nanoparticles of the first metal to obtain a mixed solution, and applying plasma to the mixed solution to cover the metal nanoparticles of the first metal by the second metal.

摘要翻译： 本发明提供一种制造生产率优异的核 - 壳型金属纳米粒子的方法和装置，特别是本发明提供一种核 - 壳型金属纳米粒子的制造方法，其包括（a）引入 将第一金属的盐转移到流动式反应装置的第一流路，并将等离子体施加到第一流路中的第一金属的盐溶液中，以获得含有第一金属的金属纳米颗粒的溶液，和（b） 将第二金属的盐溶液引入到流动型反应装置的第二流路的步骤，使其与含有第一金属的金属纳米颗粒的溶液合并，得到混合溶液，并将等离子体施加到 混合溶液以通过第二金属覆盖第一金属的金属纳米颗粒。

公开(公告)号：US20150221850A1

公开(公告)日：2015-08-06

申请号：US14608351

申请日：2015-01-29

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA ,  NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITY

发明人： Masao WATANABE ,  Mamoru ISHIKIRIYAMA ,  Youhei KINOSHITA ,  Nagahiro SAITO ,  Tomohito SUDARE ,  Tomoki KODAMA

IPC分类号： H01L35/34 ,  B22F3/10 ,  B22F1/02 ,  H01L35/20 ,  C22C12/00 ,  H01L35/16 ,  H01L35/18 ,  B22F9/24 ,  B22F1/00

CPC分类号： H01L35/34 ,  B22F1/0003 ,  B22F1/0018 ,  B22F1/025 ,  B22F3/10 ,  B22F9/24 ,  B22F2998/10 ,  B22F2999/00 ,  C22C12/00 ,  H01L35/16 ,  H01L35/18 ,  H01L35/20 ,  B22F2202/13

摘要： A method of production of core/shell type nanoparticles includes the following steps: a first step of applying a first power to cause the generation of the plasma so as to selectively cause the precipitation of a first metal so as to form nanoparticles as cores and a second step of applying a second power which is larger than the first power to cause the generation of the plasma so as to cause the precipitation of a second metal which has a smaller oxidation reduction potential than the first metal on the core surface so as to form shells which are comprised of the second metal which cover the cores which are comprised of the first metal.

摘要翻译： 核/壳型纳米颗粒的制造方法包括以下步骤：施加第一功率以产生等离子体以选择性地引起第一金属的沉淀以形成纳米颗粒作为芯的第一步骤和 第二步骤，施加大于第一功率的第二功率以产生等离子体，从而使具有比第一金属更小的氧化还原电位的第二金属沉淀在芯表面上，以形成 壳体由覆盖由第一金属构成的芯的第二金属构成。