Solid oxide fuel cell and method for producing the same
    1.
    发明授权
    Solid oxide fuel cell and method for producing the same 有权
    固体氧化物燃料电池及其制造方法

    公开(公告)号:US08765325B2

    公开(公告)日:2014-07-01

    申请号:US14026430

    申请日:2013-09-13

    申请人: Toto Ltd.

    摘要: An object of the present invention is to provide a fuel cell preventing formation of a diffusion layer containing Ca and other elements, and having an excellent power generation performance at low temperature by preventing breakdown of a crystal structure of an electrolyte by firing. Disclosed is a solid oxide fuel cell which includes an inner electrode, a solid electrolyte, and an outer electrode, each sequentially laminated on the surface of a porous support. The porous support contains forsterite, and has a Ca element content of 0.2 mass % or less in terms of CaO in a surface region at the inner electrode side.

    摘要翻译: 本发明的目的在于提供一种防止含有Ca等元素的扩散层的形成的燃料电池,并且通过烧结来防止电解液的晶体结构的破坏,在低温下具有优异的发电性能。 公开了一种固体氧化物燃料电池,其包括内电极,固体电解质和外电极,各自依次层压在多孔载体的表面上。 多孔质载体含有镁橄榄石,并且在内电极侧的表面区域中,Ca元素含量以CaO计为0.2质量%以下。

    Composite structure formation method using pre-formed controlled particles formed of fine particles non-chemically bonded together

    公开(公告)号:US10046344B2

    公开(公告)日:2018-08-14

    申请号:US15403582

    申请日:2017-01-11

    申请人: TOTO LTD.

    摘要: A composite structure formation method includes the steps of storing a plurality of pre-formed controlled particles in a storage mechanism, supplying the controlled particles from the storage mechanism to an aerosolation mechanism constantly, disaggregating the supplied controlled particles into a plurality of the fine particles in the aerosolation mechanism to form an aerosol in which an entire contents of the controlled particles including the fine particles are dispersed in the gas; and spraying all of the fine particles in the aerosol toward the substrate to form a composite structure of the structure and the substrate. The controlled particles are controlled so that bonding strength between the fine particles includes a mean compressive fracture strength sufficient to substantially avoid disaggregation during the supply step, but which permits the controlled particles to be substantially completely disaggregated in the disaggregation step.

    Composite structure formation method, pre-formed controlled particles formed of fine particles non-chemically bonded together, and composite structure formation system involving controlled particles
    4.
    发明授权
    Composite structure formation method, pre-formed controlled particles formed of fine particles non-chemically bonded together, and composite structure formation system involving controlled particles 有权
    复合结构形成方法,由未化学结合的细颗粒形成的预制控制颗粒,以及涉及可控颗粒的复合结构形成系统

    公开(公告)号:US09573149B2

    公开(公告)日:2017-02-21

    申请号:US15195096

    申请日:2016-06-28

    申请人: TOTO LTD.

    摘要: A composite structure formation method includes the steps of storing a plurality of pre-formed controlled particles in a storage mechanism, supplying the controlled particles from the storage mechanism to an aerosolation mechanism constantly, disaggregating the supplied controlled particles into a plurality of the fine particles in the aerosolation mechanism to form an aerosol in which an entire contents of the controlled particles including the fine particles are dispersed in the gas; and spraying all of the fine particles in the aerosol toward the substrate to form a composite structure of the structure and the substrate. The controlled particles are controlled so that bonding strength between the fine particles includes a mean compressive fracture strength sufficient to substantially avoid disaggregation during the supply step, but which permits the controlled particles to be substantially completely disaggregated in the disaggregation step.

    摘要翻译: 复合结构形成方法包括以下步骤:将多个预成形的受控粒子存储在存储机构中,将受控粒子从储存机构恒定地供给到气溶胶机构中,将供给的受控粒子分解成多个微粒, 形成气溶胶的气溶胶机构,其中包含微粒的受控颗粒的全部内容物分散在气体中; 并将气溶胶中的所有细颗粒喷射到基底上以形成该结构和基底的复合结构。 控制的颗粒被控制,使得细颗粒之间的结合强度包括足以基本上避免在供应步骤期间分解的平均压缩断裂强度,但这允许受控颗粒在解聚步骤中基本上完全分解。

    Solid oxide fuel cell and manufacturing method and manufacturing apparatus for same
    5.
    发明授权
    Solid oxide fuel cell and manufacturing method and manufacturing apparatus for same 有权
    固体氧化物燃料电池及其制造方法和制造装置

    公开(公告)号:US09543608B2

    公开(公告)日:2017-01-10

    申请号:US14311875

    申请日:2014-06-23

    申请人: TOTO LTD.

    IPC分类号: H01M8/24 H01M8/12

    摘要: The present invention provides a novel manufacturing method for a solid oxide fuel cell apparatus in which members of the apparatus are joined together with an adhesive, such as a ceramic adhesive. The method implements first and second types of drying and hardening steps. The first type of step may be called a workable hardening step and gives an assembly of members in the solid oxide fuel cell apparatus structural rigidity to go through assembling of the solid oxide fuel cell apparatus. The second type of step may be called a solvent elimination and hardening step and gives the assembled members property to withstand the operation temperature of the solid fuel oxide cell apparatus. The first type of step is performed at a first temperature lower than a second temperature at which the second type of step is performed. The second type of step is performed only after the first type of step is performed at multiple times.

    摘要翻译: 本发明提供了一种固体氧化物燃料电池装置的新型制造方法,其中装置的构件用诸如陶瓷粘合剂的粘合剂接合在一起。 该方法实施第一和第二类干燥和硬化步骤。 第一类型的步骤可以称为可加工的硬化步骤,并且通过固体氧化物燃料电池装置的组装,提供固体氧化物燃料电池装置中的部件的结构刚度的组件。 第二类型的步骤可以被称为消除溶剂和硬化步骤,并且使组装的构件的性能能够承受固体燃料氧化物电池装置的操作温度。 第一类型的步骤在低于执行第二类型步骤的第二温度的第一温度下进行。 第二类型的步骤仅在第一类型的步骤被多次执行之后执行。

    Solid oxide fuel cell device
    9.
    发明授权
    Solid oxide fuel cell device 有权
    固体氧化物燃料电池装置

    公开(公告)号:US09070920B2

    公开(公告)日:2015-06-30

    申请号:US14039833

    申请日:2013-09-27

    申请人: TOTO LTD.

    摘要: The present invention is a solid oxide fuel cell 1 including a reforming section 94, disposed inside a fuel gas supply flow path 20 above a vaporizing section 86 to surround the upper portion of a fuel cell stack 14, for steam reforming raw fuel gas F introduced from a fuel gas introducing portion 90a using steam S produced in a vaporizing section; and a circulating flow path portion 156 disposed in a fuel gas supply flow path between the vaporizing section and the reforming section for circulating rising raw fuel gas introduced from a fuel gas introducing section into a fuel gas supply flow path and rising steam produced in the vaporizing section along the circumferential direction of the fuel gas supply flow path so as to form a flow supplying mixed raw fuel gas and steam uniformly over the entire circumference of the reforming section.

    摘要翻译: 本发明是一种固体氧化物燃料电池1,其包括重整部分94,其设置在蒸发部分86上方的燃料气体供应流路20内,以围绕燃料电池堆14的上部,用于引入蒸汽重整原燃料气体F 使用在蒸发部中产生的蒸汽S从燃料气体导入部90a进行喷射; 以及设置在蒸发部和重整部之间的燃料气体供给流路中的循环流路部156,用于将从燃料气体导入部导入的燃料气体导入部的升高的原料燃料气体循环到燃料气体供给流路中, 沿着燃料气体供给流路的圆周方向截面,以便在整个重整部分的整个圆周上形成均匀地供应混合的原料燃料气体和蒸汽的流量。