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公开(公告)号:US20210154634A1
公开(公告)日:2021-05-27
申请号:US17047862
申请日:2019-04-17
Applicant: Siemens Aktiengesellschaft
Inventor: Manfred Baldauf , Lukas Glöser , Katharina Meltzer , Alexander Tremel
Abstract: A reactor for performing equilibrium-reduced reactions, includes a tubular reactor housing in which a first zone is arranged, through which a liquid absorbent flows, and which extends in the longitudinal direction of the tube. Aa second zone is arranged for receiving a catalyst material and also extends in the longitudinal direction of the tube. The first zone and the second zone are separated by a gas-permeable separation zone. The separation zone has a mechanically self-supporting structure and the aspect ratio of the tubular reactor housing along a reaction zone is greater than 6.
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公开(公告)号:US20210146296A1
公开(公告)日:2021-05-20
申请号:US17047853
申请日:2019-04-08
Applicant: Siemens Aktiengesellschaft
Inventor: Manfred Baldauf , Lukas Glöser , Katharina Meltzer , Alexander Tremel
Abstract: A method for operating a reactor facility for equilibrium-limited reactions, includes: converting starting materials to a product in a reaction chamber under a pressure p1, wherein an absorbent is loaded with the product and absorbs starting materials; discharging the loaded absorbent from the reaction chamber; lowering the pressure of the absorbent to a pressure p2 which is lower than pressure p1 and the product and starting materials are discharged in the gaseous state from the liquid absorbent; separating the gaseous products by condensation from the gaseous starting materials at the same time as a pressure p3 higher than pressure p1 is applied to the liquid absorbent, under pressure p3 into a liquid jet gas compressor in which the gaseous starting materials separated from the products are aspirated and dissolved in the liquid absorbent; and then introduced under pressure p4, which is lower than pressure p3, into the reaction chamber.
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公开(公告)号:US10441931B2
公开(公告)日:2019-10-15
申请号:US16307932
申请日:2017-06-09
Applicant: Siemens Aktiengesellschaft
Inventor: Jakob Albert , Manfred Baldauf , Katharina Meltzer , Jenny Reichert , Alexander Tremel , Peter Wasserscheid
Abstract: Various embodiments include a reactor for implementation of equilibrium-limited reactions comprising: a reaction space; a reactant feed; an outlet for reaction products; a device for accommodating catalyst material; and a stirrer device comprising: a hollow shaft with a gas inlet opening at one end of the hollow shaft; a first stirrer paddle with gas exit orifices mounted on the hollow shaft; and a second stirrer paddle mounted on the hollow shaft proximate the device for accommodating the catalyst material.
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公开(公告)号:US20200031748A1
公开(公告)日:2020-01-30
申请号:US16493989
申请日:2018-03-12
Applicant: Siemens Aktiengesellschaft
Inventor: Manfred Baldauf , Alexander Tremel , Jakob Albert , Katharina Meltzer , Jenny Reichert , Peter Wasserscheid
IPC: C07C29/94 , C07C317/28
Abstract: Some embodiments include a mixture for use as liquid sorbent for methanol or methanol and water in methanol synthesis using carbon monoxide and hydrogen, carbon dioxide and hydrogen or a mixture of hydrogen, carbon monoxide and carbon dioxide as synthesis reactants. The mixture comprises I) a component A) in the form of at least one salt and at least one component B) selected from the group consisting of: B1) a salt of an anion and one, two, or three of the cations of salt A), wherein the number of cations corresponds to an absolute value of a charge number of the respective anion; B2) a salt comprising one or more bis(trifluoromethylsulfonyl)imide anions and another component, wherein a number of bis(trifluoromethylsulfonyl)imide anions corresponds to an absolute value of a charge number of the respective metal cation; and B3) a zwitterionic compound.
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公开(公告)号:US20210238116A1
公开(公告)日:2021-08-05
申请号:US17219043
申请日:2021-03-31
Applicant: Siemens Aktiengesellschaft
Inventor: Manfred Baldauf , Alexander Tremel , Jakob Albert , Katharina Meltzer , Jenny Reichert , Peter Wasserscheid
IPC: C07C29/94 , C07C317/28
Abstract: Some embodiments include a mixture for use as liquid sorbent for methanol or methanol and water in methanol synthesis using carbon monoxide and hydrogen, carbon dioxide and hydrogen or a mixture of hydrogen, carbon monoxide and carbon dioxide as synthesis reactants. The mixture comprises I) a component A) in the form of at least one salt and at least one component B) selected from the group consisting of: B1) a salt of an anion and one, two, or three of the cations of salt A), wherein the number of cations corresponds to an absolute value of a charge number of the respective anion; B2) a salt comprising one or more bis(trifluoromethylsulfonyl)imide anions and another component, wherein a number of bis(trifluoromethylsulfonyl)imide anions corresponds to an absolute value of a charge number of the respective metal cation; and B3) a zwitterionic compound.
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公开(公告)号:US20200377435A1
公开(公告)日:2020-12-03
申请号:US16606806
申请日:2018-04-18
Applicant: Siemens Aktiengesellschaft
Inventor: Katharina Meltzer , Manfred Baldauf , Alexander Tremel
IPC: C07C29/152 , C07C29/151 , B01J8/00
Abstract: Various embodiments include a process for converting a starting material mixture comprising carbon dioxide and hydrogen into methanol and water. The method may include: providing a catalyst to a reactor; feeding carbon dioxide and hydrogen into the reactor, at a first pressure and a first temperature; feeding a first liquid component into the reactor at a second temperature lower than the first temperature; converting the carbon dioxide and hydrogen into methanol and water; removing the methanol from a gas phase in at least one liquid phase comprising the first component and the water; and discharging a first liquid material stream comprising the first component, methanol, and water from the reactor. At the first temperature and the first pressure the methanol is in a gaseous state and the first component and the water are in a liquid state.
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公开(公告)号:US20210285111A1
公开(公告)日:2021-09-16
申请号:US16336758
申请日:2017-08-24
Applicant: Siemens Aktiengesellschaft
Inventor: Elvira María Fernández Sanchis , Marc Hanebuth , Ralf Krause , Katharina Meltzer
Abstract: Various embodiments include a method for electrochemical utilization of carbon dioxide comprising: reducing carbon dioxide to a product gas in an electrolysis cell of an electrolyzer; delivering the product gas comprising carbon dioxide into a gas scrubbing apparatus; scrubbing the product gas to remove carbon dioxide using an absorbent in the gas scrubbing apparatus; regenerating the absorbent in an electrodialysis cell of an electrodialysis unit; at least partly recycling the regenerated absorbent into the gas scrubbing apparatus; and at least partly recycling the carbon dioxide released during the regenerating as reactant gas into the electrolyzer.
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公开(公告)号:US20200263311A1
公开(公告)日:2020-08-20
申请号:US16641753
申请日:2018-09-13
Applicant: Siemens Aktiengesellschaft
Inventor: Marc Hanebuth , Günter Schmid , Katharina Meltzer , Dan Taroata
Abstract: An electrolyser arrangement with at least one electrolytic cell, having two electrodes, namely an anode and a cathode, each of the two electrodes being in contact with an electrode compartment for filling with a liquid electrolyte, the two electrode compartments being separated by a membrane and a conveying device being provided, one for each of the two electrodes, for conveying the electrolyte in each case in a circuit, a cathode circuit and an anode circuit, through the electrode compartment via at least one collection vessel per circuit and back into the electrode chamber. A device is provided outside the electrolytic cell, for conveying an auxiliary volume flow between the cathode circuit and the anode circuit.
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公开(公告)号:US20200149170A1
公开(公告)日:2020-05-14
申请号:US16631600
申请日:2018-06-26
Applicant: Siemens Aktiengesellschaft
Inventor: Marc Hanebuth , Ralf Krause , Erhard Magori , Katharina Meltzer , Elvira María Fernández Sanchis
Abstract: Various embodiments include a CO2 electrolyzer comprising: a gas space adjoining a cathode comprising a gas diffusion electrode adjoining a cathode space; an anode in an anode space; a membrane separating the cathode space from the anode space; a feed apparatus feeding reactant gas into the gas space; a mixing vessel for at least partial joint accommodation of the anolyte and the catholyte; and a connection line between the gas separating region and the gas space. The mixing vessel includes a gas separating region closed off with respect to a surrounding atmosphere. The cathode space accommodates a catholyte and the anode space accommodates an anolyte.
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公开(公告)号:US20190217267A1
公开(公告)日:2019-07-18
申请号:US16307932
申请日:2017-06-09
Applicant: Siemens Aktiengesellschaft
Inventor: Jakob Albert , Manfred Baldauf , Katharina Meltzer , Jenny Reichert , Alexander Tremel , Peter Wasserscheid
CPC classification number: B01J8/0257 , B01J8/0278 , B01J8/10 , B01J8/222 , B01J2208/00814 , B01J2208/00876 , B01J2208/00884 , B01J2208/00938
Abstract: Various embodiments include a reactor for implementation of equilibrium-limited reactions comprising: a reaction space; a reactant feed; an outlet for reaction products; a device for accommodating catalyst material; and a stirrer device comprising: a hollow shaft with a gas inlet opening at one end of the hollow shaft; a first stirrer paddle with gas exit orifices mounted on the hollow shaft; and a second stirrer paddle mounted on the hollow shaft proximate the device for accommodating the catalyst material.
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