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公开(公告)号:US09475735B2
公开(公告)日:2016-10-25
申请号:US14415288
申请日:2014-08-14
Applicant: SAINT-GOBAIN TM K.K.
Inventor: Toshimitsu Kuboki , Hiroshi Sugiyama , Yasuo Misu , Itaru Hashimoto
IPC: C04B35/48 , C04B35/49 , C03B5/43 , C04B35/657 , F27B14/10 , F27D1/00 , C04B35/484 , F27D1/16
CPC classification number: C04B35/49 , C03B5/43 , C04B35/48 , C04B35/484 , C04B35/657 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3225 , C04B2235/3232 , C04B2235/327 , C04B2235/3272 , C04B2235/3281 , C04B2235/3293 , C04B2235/34 , C04B2235/3409 , C04B2235/3418 , C04B2235/72 , F27B14/10 , F27D1/00 , F27D1/0006 , F27D1/16
Abstract: [Problems] To provide a high zirconia fused cast refractory that suffers less cracks in production and on heating, has excellent productivity, is hard to form zircon crystals with the refractory solely and under conditions where the refractory is in contact with molten glass, is hard to suffer cracks on receiving heat cycles in operation of a glass melting furnace, and has durability for a prolonged period of time.[Solution to Problems] A high zirconia fused cast refractory containing, as chemical components, from 85 to 95% by weight of ZrO2, from 0.4 to 2.5% by weight of Al2O3, from 3.5 to 10% by weight of SiO2, from 0.05 to 1% by weight in total of Na2O and K2O, more than 0.04% by weight and 1% by weight or less of B2O3, 0.02% by weight or less of P2O5, 0.05% by weight or less of MgO, from 0.01 to 0.2% by weight of CaO, in the case where any one of SrO and BaO is contained, from 0.3 to 3% by weight of SrO or more than 0.5% by weight and 3% by weight or less of BaO, and in the case where both of them are contained, 0.3% by weight or more of SrO and from 0.3 to 3% by weight in total of SrO and BaO, from 0.01 to 0.7% by weight of SnO2, and 0.3% by weight or less in total of Fe2O3 and TiO2.
Abstract translation: [问题的解决方案]一种高氧化锆熔融铸造耐火材料,其包含作为化学成分的85至95重量%的ZrO 2,0.4至2.5重量%的Al 2 O 3,3.5至10重量%的SiO 2,0.05至 Na 2 O和K 2 O的总重量为1重量%,大于0.04重量%,B 2为1重量%以下,P 2 O 5为0.02重量%以下,MgO为0.05重量%以下,0.01〜0.2重量% 的CaO,在含有SrO和BaO的情况下,为0.3〜3重量%的SrO或超过0.5重量%且3重量%以下的BaO,在两者均为 含有0.3重量%以上的SrO和0.3〜3重量%的SrO和BaO,0.01〜0.7重量%的SnO 2和0.3重量%以下的Fe 2 O 3和0.3重量% TiO2。
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公开(公告)号:US20170088470A1
公开(公告)日:2017-03-30
申请号:US15307873
申请日:2014-11-26
Applicant: Saint-Gobain TM K.K.
Inventor: Hiroshi Sugiyama , Toshimitsu Kuboki , Itaru Hashimoto , Yasuo Misu
IPC: C04B35/49 , C04B35/484 , C03B5/43
CPC classification number: C04B35/49 , C03B5/43 , C04B35/484 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3225 , C04B2235/3232 , C04B2235/3244 , C04B2235/3272 , C04B2235/3281 , C04B2235/3293 , C04B2235/34 , C04B2235/3409 , C04B2235/3418 , C04B2235/6565 , C04B2235/667 , C04B2235/72 , C04B2235/727 , C04B2235/9669
Abstract: A high zirconia electrically fused cast refractory having long time durability with less cracking during production and in the course of temperature rising, excellent in productivity, less forming zircon crystals in the refractory itself and even in contact with molten glass, excellent in bubble foamability to molten glass, less generating cracks even undergoing heat cycles during operation of a glass melting furnace. A high zirconia electrically fused cast refractory comprises, as chemical component, 85 to 95% by weight of ZrO2, 0.4 to 2.5% by weight of Al2O3, 3.5 to 10.0% by weight of SiO2, 0.05% by weight or more of Na2O, 0.05 to 0.7% by weight of Na2O and K2O in total, 0.01 to 0.04% by weight of B2O3, 0.1 to 3.0% by weight of SrO or BaO when one of BaO and SrO is contained, 0.1% by weight or more of SrO and 0.1 to 3.0% by weight of SrO and BaO in total when both of BaO and SrO are contained, 0.01 to 0.2% by weight of CaO, 0.1% by weight or less of MgO, 0.01 to 0.7% by weight of SnO2, 0.3% by weight or less of Fe2O3 and TiO2 in total, less than 0.01% by weight of P2O5, and less than 0.01% by weight of CuO.
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公开(公告)号:US11691920B2
公开(公告)日:2023-07-04
申请号:US16981557
申请日:2019-08-13
Applicant: Saint-Gobain TM K.K.
Inventor: Koya Abe , Hiroshi Sugiyama , Shinji Tsuchiya , Itaru Hashimoto , Yasuo Misu
IPC: C04B35/107 , C04B35/64
CPC classification number: C04B35/107 , C04B35/64 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3215 , C04B2235/3217 , C04B2235/3409 , C04B2235/3418 , C04B2235/9607 , C04B2235/9684
Abstract: The present invention provides a high alumina fused cast refractory that is easily produced and has low porosity and high corrosion resistance, and a method of producing the same. The high alumina fused cast refractory of the present invention has the following chemical composition: 95.0 mass % to 99.5 mass % Al2O3, 0.20 mass % to 1.50 mass % SiO2, 0.05 mass % to 1.50 mass % B2O3, 0.05 mass % to 1.20 mass % MgO and balance. The method of producing the high alumina fused cast refractory of the present invention includes obtaining a mixture by mixing an Al2O3 source material, a SiO2 source material, a B2O3 source material and an MgO source material, and fusing the mixture.
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公开(公告)号:US20210053878A1
公开(公告)日:2021-02-25
申请号:US16981557
申请日:2019-08-13
Applicant: Saint-Gobain TM K.K.
Inventor: Koya Abe , Hiroshi Sugiyama , Shinji Tsuchiya , Itaru Hashimoto , Yasuo Misu
IPC: C04B35/107 , C04B35/64
Abstract: The present invention provides a high alumina fused cast refractory that is easily produced and has low porosity and high corrosion resistance, and a method of producing the same. The high alumina fused cast refractory of the present invention has the following chemical composition: 95.0 mass % to 99.5 mass % Al2O3, 0.20 mass % to 1.50 mass % SiO2, 0.05 mass % to 1.50 mass % B2O3, 0.05 mass % to 1.20 mass % MgO and balance. The method of producing the high alumina fused cast refractory of the present invention includes obtaining a mixture by mixing an Al2O3 source material, a SiO2 source material, a B2O3 source material and an MgO source material, and fusing the mixture.
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公开(公告)号:US09751806B2
公开(公告)日:2017-09-05
申请号:US15121682
申请日:2015-03-02
Applicant: SAINT-GOBAIN TM K.K.
Inventor: Hiroshi Sugiyama , Toshimitsu Kuboki , Itaru Hashimoto , Yasuo Misu
IPC: C04B35/484 , C03B5/43 , C03B5/02
CPC classification number: C04B35/484 , C03B5/02 , C03B5/43 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3225 , C04B2235/3244 , C04B2235/3272 , C04B2235/3281 , C04B2235/3293 , C04B2235/34 , C04B2235/3409 , C04B2235/3418 , C04B2235/72 , C04B2235/727 , C04B2235/9607 , C04B2235/9669
Abstract: A high zirconia electrically fused cast refractory of high electric resistance having long time durability, less suffering from cracking during production and upon temperature rising, excellent in productivity, less forming zircon crystals even upon heating the refractory in itself and when the refractory is in contact with molten glass, generating less cracks even when undergoing heat cycles during operation of a glass melting furnace is provided. A high zirconia electrically fused cast refractory has, as chemical components, 85 to 95% by weight of ZrO2, 0.1 to less than 0.8% by weight of Al2O3, 3.5 to 10.0% by weight of SiO2, less than 0.05% by weight of Na2O and K2O in total, 0.1 to 1.5% by weight of B2O3, 0.1% by weight or less of MgO, 0.01 to 0.2% by weight of CaO, in the case where any one of BaO and SrO is contained, from 0.05 to 3.0% by weight of BaO or 0.01 to 3.0% by weight of SrO, or in the case where both of them are contained, 0.01% by weight or more of SrO and from 0.01% to 3.0% by weight in total of SrO and BaO, 0.1 to 0.7% by weight of SnO2, 0.3% by weight or less of Fe2O3 and TiO2 in total, less than 0.01% by weight of P2O5, and less than 0.01% by weight of CuO.
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公开(公告)号:US20230406775A1
公开(公告)日:2023-12-21
申请号:US18037974
申请日:2021-11-24
Applicant: Saint-Gobain TM K.K.
Inventor: Hiroshi Sugiyama , Yasuo Misu , Itaru Hashimoto
CPC classification number: C04B35/49 , F27D1/0006 , C04B2235/3244 , C04B2235/3217 , C04B2235/3418 , C04B2235/77 , C04B2235/9669 , C04B2235/725 , C04B2235/727
Abstract: A high zirconia electrically-fused cast refractory has a chemical composition including more than 95% by mass and 98% by mass or less of ZrO2, 0.1 to 1.5% by mass of Al2O3, 1 to 2.5% by mass of SiO2, 0 to 0.1% by mass of K2O, 0.01 to 0.3% by mass of Na2O and K2O in total, 0.02 to 0.4% by mass of B2O3, 0.01 to 0.6% by mass of BaO, 0.01 to 0.4% by mass of SnO2, 0.3% by mass or less of Fe2O3 and TiO2 in total, and 0.04% by mass or less of P2O5, wherein the contents of B2O3 and SnO2 satisfy the following Formulas (1) and (2):
0.20≤(SnO2/B2O3)-
公开(公告)号:US09896383B2
公开(公告)日:2018-02-20
申请号:US15307873
申请日:2014-11-26
Applicant: Saint-Gobain TM K.K.
Inventor: Hiroshi Sugiyama , Toshimitsu Kuboki , Itaru Hashimoto , Yasuo Misu
IPC: C04B35/484 , C04B35/49 , C03B5/43
CPC classification number: C04B35/49 , C03B5/43 , C04B35/484 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3225 , C04B2235/3232 , C04B2235/3244 , C04B2235/3272 , C04B2235/3281 , C04B2235/3293 , C04B2235/34 , C04B2235/3409 , C04B2235/3418 , C04B2235/6565 , C04B2235/667 , C04B2235/72 , C04B2235/727 , C04B2235/9669
Abstract: A high zirconia electrically fused cast refractory having long time durability with less cracking during production and in the course of temperature rising, excellent in productivity, less forming zircon crystals in the refractory itself and even in contact with molten glass, excellent in bubble foamability to molten glass, less generating cracks even undergoing heat cycles during operation of a glass melting furnace. A high zirconia electrically fused cast refractory comprises, as chemical component, 85 to 95% by weight of ZrO2, 0.4 to 2.5% by weight of Al2O3, 3.5 to 10.0% by weight of SiO2, 0.05% by weight or more of Na2O, 0.05 to 0.7% by weight of Na2O and K2O in total, 0.01 to 0.04% by weight of B2O3, 0.1 to 3.0% by weight of SrO or BaO when one of BaO and SrO is contained, 0.1% by weight or more of SrO and 0.1 to 3.0% by weight of SrO and BaO in total when both of BaO and SrO are contained, 0.01 to 0.2% by weight of CaO, 0.1% by weight or less of MgO, 0.01 to 0.7% by weight of SnO2, 0.3% by weight or less of Fe2O3 and TiO2 in total, less than 0.01% by weight of P2O5, and less than 0.01% by weight of CuO.
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