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    S-(pyridyl)methyl thio- and dithio-carbamates
    2.
    发明授权
    S-(pyridyl)methyl thio- and dithio-carbamates 失效
    S-（吡啶基）甲基硫代和二硫代碳酸酯

    公开(公告)号：US3579525A

    公开(公告)日：1971-05-18

    申请号：US3579525D

    申请日：1968-10-07

    Applicant: STAUFFER CHEMICAL CO

    Inventor： TILLES HARRY ,  BROKKE MERVIN E

    IPC: C07D213/32 ,  C07D31/50

    CPC classification number: C07D213/32

    Abstract: S-(PYRIDYL)METHYL THIO- AND DITHIO-CARBAMATES HAVING THE FORMULA

    R-N(-R1)-C(=X)-S-CH2-PYRIDINE

    IN WHICH X IS OXYGEN OR SULFUR, R AND R1 ARE INDEPENDENTLY ALKYL, ALKENYL, OR CYCLOHEXYL AND R AND R1 TAKEN TOGETHER ARE ALKYLENE AND DIALKYL SUBSTITUTED ALKYLENE, PROVIDED THAT WHEN X IS SULFUR AND R AND R1 ARE BOTH ALKYL, AT LEAST ONE OF THE ALKYL GROUPS CONTAINS 3 OR MORE CARBON ATOMS. THE ABOVE COMPOUNDS, AS WELL AS THOS EXCLUDED BY THE PROVISO, ARE EFFECTIVE HERBICIDES. REPRESENTATIVE COMPOUNDS ARE

    S-(3-PYRIDYL)METHYL DI-N-PROPYLTHIOCARBAMATE, S-(2-PYRIDYL)METHYL DI-N-BUTYLTHIOCARBAMATE, S-(4-PYRIDYL)METHYL METHYLCYCLOHEXYLTHIOCARBAMATE, S-(4-PYRIDYL)METHYL ETHYL-N-BUTYLTHIOCARBAMATE AND S-(3PRYIDYL)METHYL 1-(5-ETHYL-2-METHYL-PIPERIDINECARBOTHIOATE).

    Herbicide compositions
    5.
    发明授权
    Herbicide compositions 失效
    除草剂组合物

    公开(公告)号：US3879455A

    公开(公告)日：1975-04-22

    申请号：US28038972

    申请日：1972-08-14

    Applicant: STAUFFER CHEMICAL CO

    Inventor： TILLES HARRY

    IPC: C07C103/00

    CPC classification number: C07D471/04

    Abstract: Herbicidally active sulfoxide compounds are described herein. The compounds have the following generic formula:

    WHEREIN R and R1 are lower alkyl; and R2 can be selected from the group consisting of phenyl and benzyl.

    Abstract translation: 除草活性亚砜化合物在本文中描述。 该化合物具有以下通式：

    Carbamoyl sulfoxide derivatives
    6.
    发明授权
    Carbamoyl sulfoxide derivatives 失效
    氨基甲酰亚砜衍生物

    公开(公告)号：US3928436A

    公开(公告)日：1975-12-23

    申请号：US37132873

    申请日：1973-06-18

    Applicant: STAUFFER CHEMICAL CO

    Inventor： TILLES HARRY ,  CASIDA JOHN E

    IPC: C07C147/11

    Abstract: Herbicidal active sulfoxide and sulfone compounds are described herein. The compounds have the following generic formula:

    wherein n is 1 or 2; R is selected from the group consisting of lower alkyl, haloalkyl, alkoxyalkenyl and alkenyl; R1 and R2 can be the same or different and can be selected from the group consisting of lower alkyl, cycloalkyl, alkylcycloalkyl, alkenyl and alkynyl.

    Abstract translation: 本文描述了除草活性亚砜和砜化合物。 化合物具有以下通式：其中n为1或2;其中n为1或2; R选自低级烷基，卤代烷基，烷氧基烯基和烯基; R 1和R 2可以相同或不同，并且可以选自低级烷基，环烷基，烷基环烷基，烯基和炔基。

    S-(pyridyl)methyl thiocarbamates
    7.
    发明授权
    S-(pyridyl)methyl thiocarbamates 失效
    S-（吡啶基）甲基硫代碳酸酯

    公开(公告)号：US3704236A

    公开(公告)日：1972-11-28

    申请号：US3704236D

    申请日：1970-11-20

    Applicant: STAUFFER CHEMICAL CO

    Inventor： TILLES HARRY ,  BROKKE MERVIN E

    IPC: C07D213/32 ,  C07D31/50

    CPC classification number: C07D213/32

    Abstract: S-(PYRIDYL)METHYL THIO- AND DITHIO-CARBAMATES HAVING THE FORMULA

    (R-N(-R1)-C(=X)-S-CH2-)PYRIDINE

    IN WHICH X IS OXYGEN OR SULFUR, R AND R1 ARE INDEPENDENTLY ALKYL, ALKENYL, OR CYCLOHEXYL AND R AND R1 TAKEN TOGETHER ARE ALKYLENE AND DIALKYL SUBSTITUTED ALKYLENE, PROVIDED THAT WHEN X IS SULFUR AND R AND R1 ARE BOTH ALKYL, AT LEAST ONE OF THE ALKYL GROUPS CONTAINS 3 OR MORE CARBON ATOMS. THE ABOVE COMPOUNDS, AS WELL AS THOSE EXCLUDED BY THE PROVISO, ARE EFFECTIVE HERBICIDES. REPRESENTATIVE COMPOUNDS ARE

    S-(3-PYRIDYL)METHYL DI-N-PROPYLTHIOCARBAMATE, S-(2-PYRIDYL)METHYL DI-N-BUTYLTHIOCARBAMATE, S-(4-PYRIDYL)METHYL METHYLCYCLOHEXYLTHIOCARBAMATE, S-(4-PYRIDYL)METHYL ETHYL-N-BUTYLTHIOCARBAMATE AND S-(3PYRIDYL)METHYL 1 - (5-ETHYL-2-METHYL-PIPERDINECARBOTHIOATE).

    Method of making carbamoyl sulfoxide derivatives
    8.
    发明授权
    Method of making carbamoyl sulfoxide derivatives 失效
    制备氨基甲酰基亚砜衍生物的方法

    公开(公告)号：US3897492A

    公开(公告)日：1975-07-29

    申请号：US37132973

    申请日：1973-06-18

    Applicant: STAUFFER CHEMICAL CO

    Inventor： TILLES HARRY ,  MACDONALD ALAN A

    IPC: A01N47/08 ,  C07C67/00 ,  C07C325/00 ,  C07C333/02 ,  C07C381/00 ,  C07C381/14 ,  C07C103/76 ,  C07C147/14

    Abstract: Intermediate compounds and the process of manufacturing herbicidally active sulfoxide and sulfone compounds are described herein. The intermediate compounds have the following generic formula:

    WHEREIN R is selected from the group consisting of halophenyl, phenalkyl, substituted phenalkyl, wherein said substituents can be selected from halogen, alkyl and haloalkyl; R1 and R2 can be the same or different and can be selected from the group consisting of lower alkyl, cycloalkyl, alkenyl, alkynyl and benzyl. The active compounds are made by reacting the intermediate compound with an oxidizing agent.

    Abstract translation: 本文描述了中间体化合物和制备除草活性亚砜和砜化合物的方法。 中间体化合物具有以下通式：

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