摘要:
The invention discloses a waterless fiber dyeing method using supercritical carbon dioxide fluid as medium. Dry fibers are tightly loaded layer by layer in a porous yarn cage. After dyeing, the fibers are cleaned to remove unfixed dyes by an online way, thereby obtaining waterless dyed dry fiber products with good quality. With the supercritical carbon dioxide dyed by a dye, the invention can not only solve the problems of high energy consumption, high discharge, high pollution in the traditional dyeing process, but also obtain better dyeing effect. The invention has a simple process and convenient operation, which can effectively realize dry dyeing processing. The reaction is mild, avoiding the use of a large amount of water, heat and additives in high concentration, which has the features of being high efficiency and environmentally friendly.
摘要:
The invention discloses a proofing dyeing cup for supercritical fluid waterless dyeing and finishing, which achieves separate or simultaneous filling of the medium into multiple dyeing units, and simultaneous heating of the dyeing units for proofing processing. Efficiency of proofing processing such as high-pressure supercritical fluid waterless dyeing and thus the utilization rate of the medium boosting and filling system and separation and recycling system are significantly improved, so that the proofing requirements of commercial production of textile waterless dyeing and finishing are met. Furthermore, dye chemicals at the bottom of the cup can be stirred to facilitate dissolution, and the dye chemicals at the bottom of the cup can be swept and cleaned. Thus, defects of an existing fixed supercritical fluid dyeing proofing device or an equipment system thereof, such as low utilization efficiency, complex cleaning and incapability of meeting the proofing requirements of commercial production, are overcome.
摘要:
The invention discloses a special-purpose reactive disperse dye for waterless dyeing of natural fibers in supercritical CO2 fluid and an intermediate thereof. The reactive disperse dye has a longer alkane-chain bridging group between a chromophoric parent structure and an active group of the dye, which effectively promotes the donating-withdrawing effect on the electron cloud in the conjugated system, enhances the hyperchromic effect, effectively reduce the influence of the active group itself and its reaction on the dye coloring system, improves the color and stability against acid and alkali of the dye, and facilitate the improvement of the compatibility of the dye with supercritical fluid and the dyeing performance for natural fibers as well. The invention also discloses an intermediate of the reactive disperse dye, and a method for preparing the reactive disperse dye.
摘要:
A device for colour-fixing processing on textiles includes a system of supercritical carbon dioxide fluid, a fixing liquid storage tank (2) and a fixing reactor (9). The fixing liquid storage tank (2) is below the fixing reactor (9) and sealed connected by a connecting device (6). The fixing liquid storage tank (2) has a cylindrical cavity in which a fluid distributor (4) is mounted. The fluid distributor (4) is composed of several interconnected pipes which bending down with the nozzles downward, and one of the pipes is used as circulated fluid inlet (1) connected with the supercritical carbon dioxide fluid system, and the rest pipes are used as circulated fluid outlets.
摘要:
A method of photocatalytic white discharge printing for achieving patterns on textiles includes: substrates are closely integrated with patterned printing plates, or patterned printing plates are fixed in one side or both sides of the substrates; then put them in a reactor equipped with a light source and occupied by the photocatalytic white discharging formulation. The method has the characteristics of simple process, short processing, easy controlling and wide adaptability, along with eliminations of the need for printing pastes and expensive printing apparatuses, so as the complicated process in the conventional printing method. Additionally, photocatalytic solution can be reused, avoiding generous applications of chemical agents and waste discharges in the conventional printing method. It is also beneficial to cutting costs, along with significant advantages of energy saving, emission reduction and cleaner production.
摘要:
The invention discloses a mobile dyeing cup for supercritical fluid waterless dyeing and finishing. The dyeing cup achieves separate or simultaneous filling of the medium into multiple dyeing units, and simultaneous heating of the dyeing units for proofing processing. A medium outlet is provided at the lowest position of the bottom of the cup, and the inner surface of the dyeing cup is coated with polytetrafluoroethylene, to effectively reduce residual dye chemicals in the cup and improve the cleaning efficiency. The perforated baffle at the bottom of the cup effectively prevents a textile product from blocking the medium outlet during medium filling and outputting, so that the processing medium and residual dye chemicals can be smoothly discharged. Accordingly, defects of an existing fixed proofing device such as low utilization efficiency, complex cleaning and incapability of meeting the proofing requirements of commercial production are overcome.
摘要:
The invention relates to a multi-pipe quantitative medium filling system of a supercritical fluid waterless dyeing machine. The system comprises a supercritical fluid medium reservoir, a stop valve, and a medium filter sequentially connected by a high-pressure main pipe, and at least two filling branches independent of each other and connected to the medium filter. Each filling branch includes a booster pump, a supercritical fluid high-pressure mass flowmeter, a ball valve, and a dyeing unit sequentially connected along a medium forward direction by a high-pressure branch pipe. By using a mass-measurement filling system having multiple branches independent of each other, the invention can effectively realize simultaneous and accurate quantitative medium filling for separate dyeing units and differentiated filling for dyeing units with different medium masses, thus overcoming disadvantages such as unreliability, inaccuracy and low use efficiency of a conventional method, and also making a dyeing operation simple and scientifically feasible.
摘要:
A photocatalytic method of colored discharge printing for producing colorized patterns on textiles includes: textiles are over dyed with illuminant dyes and ground shade dyes respectively; then the patterned printing plates with hollow-outs decorative patterns are manufactured, and the photocatalyst is applied on the over-dyeing textiles through the hollow-outs; finally, with the photocatalytic method of colored discharge printing, the ground shade dyes are localized discolored, while the illuminant dyes are left on the substrates, having an effect of colorized patterns on textiles. The method has the characteristics of simple process and apparatuses, short processing, easy controlling and wide adaptability, along with eliminations of the needs for printing pastes and expensive printing apparatuses, so as the complicated process in the conventional printing method.
摘要:
The present invention relates to a waterless fiber dyeing method using a mixed fluid medium, in which supercritical carbon dioxide fluid medium is mixed with steam to form a mixed fluid medium, so that the waterless fiber dyeing effect to natural fibers is improved. The method of the invention can effectively modify the hydrophobic supercritical carbon dioxide fluid medium and improve the polarity thereof, thereby increasing the solubility of polar dye under the dyeing condition and simultaneously expanding the fiber. Thus, the present invention significantly improves the dyeability and dyeing behavior of the hydrophilic fibers in supercritical carbon dioxide fluids. The invention has the advantages of simple process, convenient operation and low energy consumption, and avoids consuming a large amount of water resources and discharging pollutants in the traditional process, and has the characteristics of environmentally friendly and high efficiency.
摘要:
The invention relates to a separation, recycling and self-cleaning system of a supercritical fluid dyeing machine. The system includes a supercritical fluid medium reservoir, one or more parallel dyeing units, a high-pressure pump, a primary separator, a secondary separator and a membrane separator sequentially connected. A dyeing medium and residual dye in dyeing units can be efficiently separated and recycled simultaneously, and when the separation and recycling is finished, each dyeing unit can be directly opened so that the dyeing units and products can be cleaned after dyeing, thereby improving the production and processing efficiency of supercritical fluid waterless dyeing and achieving simple operations, complete separation, stability and reliability and a blowback self-cleaning. The invention has a broad application prospect and practical significance in fundamentally addressing generation and emission of pollutants in the textile printing and dyeing industry and realizing energy conservation, consumption reduction, emission reduction and clean production.