PROCESS FOR THE MANUFACTURE OF DICHLOROPROPANOL
    3.
    发明申请
    PROCESS FOR THE MANUFACTURE OF DICHLOROPROPANOL 审中-公开
    二氯丙醇制备方法

    公开(公告)号:US20130225843A1

    公开(公告)日:2013-08-29

    申请号:US13832363

    申请日:2013-03-15

    申请人: SOLVAY SA

    IPC分类号: C07C29/62

    摘要: A process for manufacturing dichloropropanol in which glycerol and/or monochloropropanediol are reacted with hydrogen chloride, in a liquid reaction medium, which is in contact with a gaseous phase, in at least two reactors arranged in a loop, and under a partial pressure of hydrogen chloride in the first reactor which is greater than the partial pressure of hydrogen chloride in the second reactor. This process is suitable for recovering dichloropropanol free from hydrogen chloride and the recovered dichloropropanol may be used in subsequent reactions while avoiding overconsumption of basic agent and loss of recoverable hydrogen chloride, and corrosion during transfer and storage of dichloropropanol will be limited.

    摘要翻译: 一种制备二氯丙醇的方法,其中将甘油和/或一氯丙二醇与氯化氢在与气相接触的液体反应介质中在至少两个排列成环的反应器中并在氢气的分压下反应 在第一反应器中的氯化氢大于第二反应器中氯化氢的分压。 该方法适用于回收不含氯化氢的二氯丙醇,回收的二氯丙醇可用于后续反应,同时避免碱性试剂的过度消耗和可回收的氯化氢的损失,二氯丙醇的转移和储存期间的腐蚀将受到限制。