Polymerization of isoprene with catalyst of transition metal and polyiminoalane
    8.
    发明授权
    Polymerization of isoprene with catalyst of transition metal and polyiminoalane 失效
    异丙烯与过渡金属和聚亚胺的催化剂的聚合

    公开(公告)号:US3476734A

    公开(公告)日:1969-11-04

    申请号:US3476734D

    申请日:1968-11-08

    Applicant: SNAM PROGETTI

    Inventor: MARCONI WALTER

    Abstract: 1,131,257. Polymerization catalysts for butadiene. SNAM S.p.A. 4 Nov., 1965 [3 Feb., 1965], No. 46885/65. Heading C3P. A polymerization catalyst comprises (a) a transition metal compound of a metal of Group IV to VIII of the Periodic System, (b) a linear aluminium polymeric compound containing repeating units of the formula where R is an aryl, alkyl, or cycloalkyl hydrocarbon radical, and (c) if component (a) is free from cobalt, iodine is present therein or is introduced in the form of aluminium iodide whilst if cobalt is present any aluminium halide can be present. Compound (b) may be made by reacting LiAlH 4 with the hydrochloride of a primary amine or by reacting a primary amine with an aluminium hydride. Compound (a) may be TiCl 3 , TiCl 4 , TiI 4 , VCl 3 , VCl 4 , TiI 2 Cl 2 , NiCl 2 , VOCl 3 , CoCl 2 , or cobalt acetylacetonate. The (c) compound may be AlI 3 , AlCl 3 , or AlBr 3 . In the examples the R in the (b) polymer is ethyl, n-butyl, and phenyl. The catalyst is used to polymerize butadiene in the presence of a hydrocarbon solvent. The polymer is recovered by conventional techniques.

Patent Agency Ranking