公开(公告)号：US20140325896A1

公开(公告)日：2014-11-06

申请号：US14265428

申请日：2014-04-30

Applicant: SHELL OIL COMPANY

Inventor： Johannes Pieter HAAN ,  Carolus Matthias Anna Maria MESTERS ,  Ivo Johannes DIJS ,  Arjen NIEUWHOF

IPC: C10G1/00 ,  C10L1/10 ,  C10G1/04

CPC classification number: C10G1/002 ,  C10B53/02 ,  C10G1/045 ,  C10G7/04 ,  C10G9/00 ,  C10G11/00 ,  C10G33/00 ,  C10G47/00 ,  C10G55/04 ,  C10G55/06 ,  C10G67/02 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/203 ,  C10G2300/302 ,  C10G2300/308 ,  C10L1/02 ,  C10L1/023 ,  C10L1/10 ,  Y02E50/14 ,  Y02P30/20

Abstract: A process for converting a biomass material comprising a) pyrolyzing a biomass material to produce a biomass-derived pyrolysis product; b) providing a petroleum-derived hydrocarbon composition having a C7-asphaltenes content of equal to or more than 0.2 wt %, based on the total weight of the petroleum-derived hydrocarbon composition, which petroleum-derived hydrocarbon composition has a total acid number of equal to or more than 0.5 mg KOH/g and/or a density at 15.5° C. of equal to or more than 0.8 grams/ml and/or a viscosity at 37.8° C. of equal to or more than 500 centiStokes (cSt); c) mixing at least part of the biomass-derived pyrolysis product and at least part of the petroleum-derived hydrocarbon composition to produce a hydrocarbon-containing mixture; and d) dewatering the hydrocarbon-containing mixture to produce a dewatered hydrocarbon-containing mixture.

Abstract translation: 一种用于转化生物质材料的方法，包括a）热解生物质材料以产生生物质衍生的热解产物; b）基于石油衍生的烃组合物的总重量，提供具有等于或大于0.2重量％的C7-沥青质含量的石油衍生的烃组合物，该石油衍生烃组合物的总酸值为 等于或大于0.5mg KOH / g和/或15.5℃下的密度等于或大于0.8克/毫升和/或在37.8℃下的粘度等于或大于500厘沲（cSt ）; c）将至少部分生物质衍生的热解产物和至少部分来自石油的烃组合物混合以产生含烃混合物; 和d）使含烃混合物脱水以产生脱水的含烃混合物。

公开(公告)号：US20130105356A1

公开(公告)日：2013-05-02

申请号：US13665751

申请日：2012-10-31

Applicant: Shell Oil Company

Inventor： Ivo Johannes DIJS ,  Arjen NIEUWHOF ,  Johannes Pieter HAAN ,  Karin BUS

IPC: C10G7/04 ,  C10G55/06 ,  C10L1/04

CPC classification number: C10G7/04 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/203 ,  C10G2300/206 ,  C10G2300/301 ,  C10G2300/302 ,  Y02P30/20

Abstract: Pyrolysis oil is upgraded by evaporating water from a mixture of the pyrolysis oil and a hydrocarbon having an atmospheric boiling point of at least 130° C. The method yields a de-watered pyrolysis oil mixture.

Abstract translation: 通过从热解油和常压沸点至少为130℃的烃的混合物蒸发水来提炼热解油。该方法产生脱水的热解油混合物。

公开(公告)号：US20140330057A1

公开(公告)日：2014-11-06

申请号：US14265411

申请日：2014-04-30

Applicant: SHELL OIL COMPANY

Inventor： Ivo Johannes DIJS ,  Arjen NIEUWHOF ,  Johannes Pieter HAAN ,  Josiane Marie-Rose GINESTRA ,  Jozef Jacobus Titus SMITS ,  Colin John SCHAVERIEN ,  Leticia ESPINOSA ALONSO ,  Wouter SPIERING

IPC: C10G1/04

CPC classification number: C10G1/045 ,  C10B53/02 ,  C10G33/00 ,  C10G47/00 ,  C10G47/24 ,  C10G47/26 ,  C10G47/28 ,  C10L1/02 ,  Y02E50/14

Abstract: A process for converting a biomass material comprising a) pyrolyzing a biomass material to produce a biomass-derived pyrolysis product; b) mixing at least part of the biomass-derived pyrolysis product and a petroleum-derived hydrocarbon composition, which petroleum derived hydrocarbon composition has a C7-asphaltenes content of equal to or more than 0.2 wt %, based on the total weight of the petroleum-derived hydrocarbon composition, to produce a hydrocarbon-containing mixture; c) dewatering the hydrocarbon-containing mixture to produce a dewatered hydrocarbon-containing mixture; d) contacting the dewatered hydrocarbon-containing mixture with hydrogen in one or more ebullating bed reactors comprising a catalyst at a temperature in the range from 350 to 500° C. to produce a reaction product.

Abstract translation: 一种用于转化生物质材料的方法，包括a）热解生物质材料以产生生物质衍生的热解产物; b）将至少部分生物质衍生的热解产物和石油衍生的烃组合物混合，所述石油衍生的烃组合物具有基于石油的总重量等于或大于0.2重量％的C7-沥青质含量 得到的含烃混合物; c）使含烃混合物脱水以产生脱水的含烃混合物; d）使脱水的含烃混合物与氢在一个或多个沸腾床反应器中接触，所述反应床包含催化剂，温度为350-500℃，以产生反应产物。