-
1.
公开(公告)号:US20180161761A1
公开(公告)日:2018-06-14
申请号:US15834103
申请日:2017-12-07
申请人: SHELL OIL COMPANY
CPC分类号: B01J23/688 , B01J27/12 , B01J35/0006 , B01J35/1009 , B01J35/1038 , B01J35/1042 , B01J35/1071 , B01J35/1076 , B01J37/0201 , B01J37/0215 , B01J37/082 , C07D301/10 , Y02P20/52
摘要: An ethylene epoxidation catalyst is disclosed that comprises a fluoride-mineralized carrier having silver and a rhenium promoter deposited thereon, wherein the fluoride-mineralized carrier has: a total fluorine (TF) content less than 5000 ppm as measured by XRF, a water extractable fluorine (WEF) content greater than 45 ppm as measured by microwave extraction and ion specific electrode, and wherein the ratio of TF:WEF is between 10 and 110. Associated methods of manufacturing such catalysts and epoxidation methods using such catalysts are similarly provided.