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公开(公告)号：US20160068673A1
公开(公告)日：2016-03-10
申请号：US14942202
申请日：2015-11-16
发明人： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC分类号： C08L33/08
CPC分类号： C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
摘要： The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
摘要翻译： 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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公开(公告)号：US20190119431A1
公开(公告)日：2019-04-25
申请号：US15736545
申请日：2016-06-09
发明人： Kaoru Aou , Thomas H. Kalantar , Qinghao Meng , John Klier , Antony K. Van Dyk , Gary W. Dombrowski , Joseph Jacobs
IPC分类号： C08G18/48 , C08G18/18 , C08G18/24 , C08G18/40 , C08G18/63 , C08G18/16 , C08G18/08 , C08G18/76
摘要： A reaction system for forming a viscoelastic polyurethane foam includes an isocyanate component and an isocyanate-reactive component that includes at least a polyol component, an additive component, and a preformed aqueous polymer dispersant. The mixture includes 50.0 wt % to 99.8 wt % of the polyol component, 0.1 wt % to 49.9 wt % of the additive component, and 0.1 wt % to 6.0 wt % of the preformed aqueous polymer dispersant. The aqueous polymer dispersant has a pH from 6.0 to 12.0 and includes from 5 wt % to 60 wt % of a polymeric component and from 40 wt % to 95 wt % of a fluid medium. The polymeric component includes at least one base polymer derived from 20 wt % to 100 wt % of at least one hydrophilic acid monomer having at least one carbonyl group, phosphate group, phosphonate group, or sulfonyl group, and optionally derived from at least one hydrophobic terminally unsaturated hydrocarbon monomer.
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公开(公告)号：US08907004B2
公开(公告)日：2014-12-09
申请号：US13951588
申请日：2013-07-26
发明人： Kevin J. Henderson , Thomas H. Kalantar , Lidaris San Miguel Rivera , Anurima Singh , Antony K. Van Dyk
IPC分类号： C08F220/06 , C08K5/09 , C09D141/00 , C08F220/38 , C09D133/14 , C08L101/00
CPC分类号： C09D141/00 , C08F212/14 , C08F220/38 , C08F220/58 , C08F2220/382 , C08F2220/585 , C08L101/00 , C09D133/08 , C09D133/14 , C08L33/14 , C08F220/34 , C08F2220/286 , C08F2220/1825 , C08L33/24 , C08F220/36 , C08F220/06 , C08F220/14
摘要： The present invention relates to a composition which comprises a stable aqueous dispersion of discrete polymer particles and a water-soluble dispersant adsorbed onto the surfaces of pigment particles, wherein the polymer particles comprise structural units of a sulfonic acid monomer or a salt thereof. The present invention addresses a need in the art by providing a way to improve the hiding efficiency of compositions containing pigment such as TiO2 and associative rheology modifiers.
摘要翻译： 本发明涉及包含离散聚合物颗粒的稳定的水分散体和吸附在颜料颗粒表面上的水溶性分散剂的组合物，其中聚合物颗粒包含磺酸单体或其盐的结构单元。 本发明通过提供一种提高包含颜料如TiO 2和缔合流变学改性剂的组合物的遮盖效率的方法来满足本领域的需要。
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公开(公告)号：US20140350178A1
公开(公告)日：2014-11-27
申请号：US14281944
申请日：2014-05-20
发明人： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
CPC分类号： C08G18/831 , C08F283/006 , C08F290/067 , C08G18/3228 , C08G18/3819 , C08G18/751 , C08G18/755 , C08G18/7614 , C08G18/7671 , C08L75/02 , C08L75/16 , C09D133/06 , C09D175/02 , C09D133/12
摘要： The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. In another aspect, the present invention is the compound of Formula I.Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
摘要翻译： 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 另一方面，本发明是式I的化合物。使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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公开(公告)号：US09783669B2
公开(公告)日：2017-10-10
申请号：US14942202
申请日：2015-11-16
发明人： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC分类号： C08L33/24 , C08L33/06 , C08F283/00 , C08L33/08 , C08G18/75 , C08G18/76 , C08G18/32 , C08G18/63 , C08F290/06
CPC分类号： C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
摘要： The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
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公开(公告)号：US09217081B2
公开(公告)日：2015-12-22
申请号：US14281947
申请日：2014-05-20
发明人： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC分类号： C08L33/24 , C08F283/00 , C08G18/75 , C08G18/76 , C08G18/32 , C08G18/63 , C08F290/06
CPC分类号： C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
摘要： The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
摘要翻译： 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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公开(公告)号：US09505874B2
公开(公告)日：2016-11-29
申请号：US14281944
申请日：2014-05-20
发明人： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC分类号： C08G18/83 , C08G18/75 , C08G18/76 , C08F283/00 , C08F290/06 , C09D175/02 , C08G18/32 , C08G18/38 , C08L75/02
CPC分类号： C08G18/831 , C08F283/006 , C08F290/067 , C08G18/3228 , C08G18/3819 , C08G18/751 , C08G18/755 , C08G18/7614 , C08G18/7671 , C08L75/02 , C08L75/16 , C09D133/06 , C09D175/02 , C09D133/12
摘要： The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an 5 aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: 10 where A1, A2, R1, R2, and R3 are as defined herein. In another aspect, the present invention is the compound of Formula I. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
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公开(公告)号：US08865827B2
公开(公告)日：2014-10-21
申请号：US13951591
申请日：2013-07-26
发明人： Kevin J. Henderson , Thomas H. Kalantar , Lidaris San Miguel Rivera , Anurima Singh , Antony K. Van Dyk
IPC分类号： C08F220/06 , C08K5/09 , C09D133/14 , C08F220/38 , C09D7/12
CPC分类号： C09D7/125 , C08F212/14 , C08F220/38 , C08F220/58 , C08F2220/382 , C08F2220/585 , C09D7/65 , C09D133/08 , C09D133/14 , C08L33/24 , C08F220/34 , C08F2220/286 , C08F2220/1825 , C08F220/36 , C08F220/06 , C08F220/14
摘要： The present invention relates to a composition comprising a water-soluble dispersant comprising structural units of a sulfonic acid monomer or a salt thereof and a co-monomer. The dispersant of the present invention addresses a need in the art by providing a way to improve the hiding efficiency of coatings compositions.
摘要翻译： 本发明涉及包含包含磺酸单体或其盐和共聚单体的结构单元的水溶性分散剂的组合物。 本发明的分散剂通过提供一种改善涂料组合物的遮盖效率的方法来满足本领域的需要。
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公开(公告)号：US20140039115A1
公开(公告)日：2014-02-06
申请号：US13951588
申请日：2013-07-26
发明人： Kevin J. Henderson , Thomas H. Kalantar , Lidaris San Miguel Rivera , Anurima Singh , Antony K. Van Dyk
IPC分类号： C09D141/00
CPC分类号： C09D141/00 , C08F212/14 , C08F220/38 , C08F220/58 , C08F2220/382 , C08F2220/585 , C08L101/00 , C09D133/08 , C09D133/14 , C08L33/14 , C08F220/34 , C08F2220/286 , C08F2220/1825 , C08L33/24 , C08F220/36 , C08F220/06 , C08F220/14
摘要： The present invention relates to a composition which comprises a stable aqueous dispersion of discrete polymer particles and a water-soluble dispersant adsorbed onto the surfaces of pigment particles, wherein the polymer particles comprise structural units of a sulfonic acid monomer or a salt thereof. The present invention addresses a need in the art by providing a way to improve the hiding efficiency of compositions containing pigment such as TiO2 and associative rheology modifiers.
摘要翻译： 本发明涉及包含离散聚合物颗粒的稳定的水分散体和吸附在颜料颗粒表面上的水溶性分散剂的组合物，其中聚合物颗粒包含磺酸单体或其盐的结构单元。 本发明通过提供一种提高包含颜料如TiO 2和缔合流变学改性剂的组合物的遮盖效率的方法来满足本领域的需要。
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公开(公告)号：US20140350170A1
公开(公告)日：2014-11-27
申请号：US14281947
申请日：2014-05-20
发明人： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC分类号： C08L33/24
CPC分类号： C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
摘要： The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
摘要翻译： 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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