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    Fiber lubricants derived from the oxyalkylation of a glycerol-1,3-dialkylether
    1.
    发明授权
    Fiber lubricants derived from the oxyalkylation of a glycerol-1,3-dialkylether 失效
    衍生自甘油-1,3-二烷基醚的烷氧基化的纤维润滑剂

    公开(公告)号：US4273946A

    公开(公告)日：1981-06-16

    申请号：US83466

    申请日：1979-10-10

    申请人： David D. Newkirk ,  Robert B. Login

    发明人： David D. Newkirk ,  Robert B. Login

    IPC分类号： D06M13/165 ,  C07C43/11

    CPC分类号： D06M13/165 ,  Y10T428/2969

    摘要： Lubricants and processing aids for synthetic fibers, particularly polyester and nylon fibers, are disclosed comprising compounds having the structural formulas: ##STR1## in which R is an aliphatic group generally having about 3 to about 22 carbon atoms; A is a mixture of residues from ethylene oxide and at least one other lower alkylene oxide, preferably a heteric mixture of oxyethylene and oxypropylene residues in the respective ratio by weight of 20:80 to 90:10; and n has a value to produce a molecular weight of about 300 to about 3000.Where liquid products are desired which contain the higher numbered carbon chain residues, low viscosity compounds can be obtained by oxyalkylating a glycerol-1,3-dialkylether with a mixture of ethylene oxide and 1,2-propylene oxide in the respective ratio as set forth above. Thus it is possible by properly balancing the carbon chain length of the R groups in the lubricant compounds of the invention with the oxyalkylene chain length to obtain products varying between water insoluble and water soluble. The oxyalkylated fiber lubricants of the invention have the properties of viscous liquids, solids or pastes at ambient temperature.

    摘要翻译： 公开了用于合成纤维，特别是聚酯和尼龙纤维的润滑剂和加工助剂，其包括具有以下结构式的化合物：其中R是通常具有约3至约22个碳原子的脂族基团; A是来自环氧乙烷和至少一种其它低级环氧烷的残基的混合物，优选氧化乙烯和氧化丙烯残基的杂化混合物，其重量比分别为20:80至90:10; 并且n具有产生约300至约3000的分子量的值。当需要含有较高编号的碳链残基的液体产物时，可以通过用混合物烷基化甘油-1,3-二烷基醚来获得低粘度化合物 的环氧乙烷和1,2-环氧丙烷以上述各自的比例。 因此，可以通过将本发明的润滑剂化合物中的R基团的碳链长度与氧化烯链长度适当平衡来获得在水不溶性和水溶性之间变化的产物。 本发明的烷氧基化纤维润滑剂在环境温度下具有粘性液体，固体或糊状物的性质。

    Linear saturated polyesters of phosphoric acid and halogenated diols as flame-retardant additives and coatings
    2.
    发明授权
    Linear saturated polyesters of phosphoric acid and halogenated diols as flame-retardant additives and coatings 失效
    磷酸和卤代二醇的线性饱和聚酯作为阻燃添加剂和涂料

    公开(公告)号：US4259222A

    公开(公告)日：1981-03-31

    申请号：US933986

    申请日：1978-08-16

    申请人： Robert B. Login ,  David D. Newkirk

    发明人： Robert B. Login ,  David D. Newkirk

    IPC分类号： C08G63/692 ,  D06M15/667 ,  C08G63/66 ,  C08G63/68

    CPC分类号： C08G63/692 ,  D06M15/667

    摘要： The present invention provides new linear phosphorus- and halogen-containing flame retardant polyester additives for normally flammable polymers and coatings for normally flammable natural and synthetic films and fibers, for instance, polyester and cellulose ester films and fibers. The phosphorus- and halogen-containing polymers of the invention are water dispersible or can be rendered water-soluble. They can be prepared by reacting a phosphorus acid reactant such as phosphoric acid with at least one halogenated difunctional monomer. The water-soluble polyesters can be cross-linked to render them insoluble in water by heating together with a methylol compound.Said halogenated monomer is preferably an oxyalkylated diacid or diol and said halogen is attached either on one or more aromatic rings or on a cycloaliphatic ring. The halogenated diols useful in preparing the flame-retardant polymer additives of the invention are selected from the group consisting of at least one of the halogenated, saturated diols having the formula: ##STR1## wherein m and p are integers of 2 to 6; n and q in formulas A, C, and D are 0 or integers of 1 to 10 and integers of 1-10 in formula B; wherein in formulas A-C, X which is attached to an aromatic ring represents 1 to 4 halogen atoms; and wherein in formula D, X represents 1 to 2 halogen atoms and Z is hydrogen, a C.sub.1 -C.sub.6 alkyl radical, or phenyl.Polymer fibers and films such as those made from polyethylene terephthalate and cellulose ester fibers and films such as those prepared from cellulose acetate and cellulose triacetate, each containing a flame-retardant amount of the phosphorus- and halogen-containing flame-retardant polymer additives of the invention are resistant to loss of the polymeric flame-retardant additives of the invention during use.

    摘要翻译： 本发明为通常可燃的聚合物和用于通常可燃的天然和合成膜和纤维的涂料提供了新的线性含磷和卤素阻燃聚酯添加剂，例如聚酯和纤维素酯膜和纤维。 本发明的含磷和含卤素聚合物是水分散的或可使其变成水溶性的。 它们可以通过使磷酸反应物如磷酸与至少一种卤化双官能单体反应来制备。 水溶性聚酯可以交联，通过与羟甲基化合物一起加热使其不溶于水。 所述卤化单体优选为烷氧基化二酸或二醇，所述卤素连接在一个或多个芳环上或脂环族环上。 用于制备本发明的阻燃聚合物添加剂的卤化二醇选自至少一种具有下式的卤化饱和二醇： B.图像C. 其中m和p是2至6的整数; 式A，C和D中的n和q是式B中的0或1-10的整数和1-10的整数; 其中在式A-C中，与芳环连接的X代表1-4个卤素原子; 并且其中在式D中，X表示1至2个卤素原子，Z是氢，C1-C6烷基或苯基。 由聚对苯二甲酸乙二醇酯和纤维素酯纤维制成的聚合物纤维和薄膜以及由醋酸纤维素和三乙酸纤维素制成的那些薄膜，各自含有阻燃量的含磷和卤素的阻燃聚合物添加剂 本发明在使用期间耐受本发明的聚合物阻燃添加剂的损失。

    Flame retardant antistatic additives and antistatic fibers
    3.
    发明授权
    Flame retardant antistatic additives and antistatic fibers 失效
    阻燃抗静电添加剂和抗静电纤维

    公开(公告)号：US4229554A

    公开(公告)日：1980-10-21

    申请号：US746723

    申请日：1976-12-02

    申请人： David D. Newkirk ,  Robert B. Login ,  Basil Thir

    发明人： David D. Newkirk ,  Robert B. Login ,  Basil Thir

    IPC分类号： C08G63/682 ,  D06M11/47 ,  D06M11/70 ,  D06M15/507 ,  D06M15/53 ,  C08F283/02 ,  C08G63/76 ,  C08G69/44

    CPC分类号： C08G63/6824 ,  D06M11/47 ,  D06M11/70 ,  D06M15/507 ,  D06M15/53

    摘要： Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Improved flame-retardant properties can be obtained by including with the flame-retardant, antistatic polymer composition an effective flame retardant proportion of a compound containing a metal from group Vb of the periodic table. Generally about 1:4 to about 4:1 parts halogen to antimony compound is used. Such compounds are oxides of metals such as phosphorus, arsenic, antimony, or bismuth with the preferred compound being antimony trioxide.

    摘要翻译： 提供了阻燃抗静电聚合物添加剂，其在将合成聚合物纤维即聚酰胺纤维加入这些组合物时抑制静电荷的累积，并且同时对这种聚合物纤维的可燃性没有贡献。 阻燃抗静电聚合物组合物可与纤维如聚酰胺，聚酯，聚脲，聚氨酯，聚磺酰胺，聚烯烃和聚丙烯酸纤维组合使用。 抗静电效果是通过将纤维涂布或分散在纤维中或在纤维上分散至约12重量％的聚合物组合物获得的，所述聚合物组合物是以下物质的反应产物：（a）聚氧化烯化合物或其聚酯和（b） 至少一种选自（1）二醇，（2）聚酯和（3）脂族或芳族二酸或（3）的衍生物的反应物，其中至少一种所述反应物被卤化。 通过使阻燃抗静电聚合物组合物包含含有周期表第Vb族中的金属的化合物的有效阻燃剂比例，可以获得改进的阻燃性能。 通常使用约1:4至约4:1的卤素至锑化合物。 这些化合物是金属的氧化物，例如磷，砷，锑或铋，优选的化合物是三氧化锑。

    Metal molds coated with oxidative stable polyoxyalkylene release agents
    4.
    发明授权
    Metal molds coated with oxidative stable polyoxyalkylene release agents 失效
    金属模具涂有氧化稳定的聚氧化烯脱模剂

    公开(公告)号：US4217394A

    公开(公告)日：1980-08-12

    申请号：US973100

    申请日：1978-12-26

    申请人： David D. Newkirk ,  Robert B. Login ,  Basil Thir

    发明人： David D. Newkirk ,  Robert B. Login ,  Basil Thir

    IPC分类号： B29C33/62 ,  C10M107/34 ,  B32B15/04

    CPC分类号： C10M107/34 ,  B29C33/62 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2209/106 ,  C10M2209/107 ,  C10M2209/109 ,  C10N2220/02 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  Y10T428/31678

    摘要： There are disclosed mold-release compositions suitable for lubricating metal molds which are used in molding natural and synthetic rubber and other polymers. The mold release agents of the invention are oxidation-stable homopolymer and copolymer, i.e., block or heteric polyoxyalkylene lubricant compounds. The lubricants of the invention can be used alone or in mixtures with prior art polyoxyalkylene lubricant compounds. The polyoxyalkylene mold release lubricants of the invention have the formula: ##STR1## R is individually selected from alkyl groups of 1 to about 21 carbon atoms, preferably about 7 to about 21 carbon atoms, and most preferably about 12 to about 18 carbon atoms. In lubricants I and III, R.sub.1 and R.sub.2 are the residue of the same or different and in lubricant II different alkylene units, all individually selected from the group consisting of the residue of ethylene oxide, propylene oxide, butylene oxide and an aromatic glycidyl ether, R.sub.3 is the residue of a difunctional phenol, R.sub.4 is hydrogen, an acyl or alkyl group and where alkyl, derived from an aliphatic monofunctional alcohol having 1 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 4 to about 12 carbon atoms or where acyl derived from an aliphatic monocarboxylic acid of 2 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 6 to about 12 carbon atoms, R.sub.5 is the residue of an aromatic glycidyl ether, preferably a phenyl glycidyl ether and n or m+n have a value to produce a molecular weight of about 300 to about 6000, preferably about 600 to about 5000 and most preferably about 1000 to about 4000.

    摘要翻译： 公开了适用于润滑金属模具的脱模组合物，其用于模制天然和合成橡胶和其它聚合物。 本发明的脱模剂是氧化稳定的均聚物和共聚物，即嵌段或杂多聚氧化烯润滑剂化合物。 本发明的润滑剂可以单独使用或与现有技术的聚氧化烯润滑剂化合物混合使用。 本发明的聚氧化烯脱模润滑剂具有下式： I. II。 和 III。 R独立地选自1至约21个碳原子，优选约7至约21个碳原子的烷基，最优选约12至约18个碳原子。 在润滑剂I和III中，R1和R2是相同或不同的残基，润滑剂II不同的亚烷基单元，全部分别选自环氧乙烷，环氧丙烷，环氧丁烷和芳族缩水甘油醚的残基， R3是二官能苯酚的残基，R4是氢，酰基或烷基，其中烷基衍生自具有1至约21个碳原子，优选约4至约18个碳原子，最优选约4至约18个碳原子的脂肪族单官能醇 约12个碳原子，或其中衍生自2至约21个碳原子，优选约4至约18个碳原子，最优选约6至约12个碳原子的脂肪族单羧酸的酰基，R 5为芳族缩水甘油醚的残基， 优选苯基缩水甘油醚，n或m + n具有产生约300至约6000，优选约600至约5000，最优选约1000至约4000的分子量的值。

    Flame retardant antistatic additives and antistatic fibers
    5.
    发明授权
    Flame retardant antistatic additives and antistatic fibers 失效
    阻燃抗静电添加剂和抗静电纤维

    公开(公告)号：US4303767A

    公开(公告)日：1981-12-01

    申请号：US094033

    申请日：1979-11-13

    申请人： David D. Newkirk ,  Robert B. Login ,  Basil Thir

    发明人： David D. Newkirk ,  Robert B. Login ,  Basil Thir

    IPC分类号： C08G63/682 ,  D06M11/47 ,  D06M11/68 ,  D06M15/507 ,  D06M15/53 ,  C08L67/00

    CPC分类号： D06M11/47 ,  C08G63/6824 ,  D06M11/68 ,  D06M15/507 ,  D06M15/53

    摘要： Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Improved flame-retardant properties can be obtained by including with the flame-retardant, antistatic polymer composition an effective flame retardant proportion of a compound from group Vb of the periodic table. Generally about 1:4 to about 4:2 parts halogen to antimony compound is used. Such compounds are oxides of metals such as phosphorus, arsenic, antimony, or bismuth with the preferred compound being antimony trioxide.

    摘要翻译： 提供了阻燃抗静电聚合物添加剂，其在将合成聚合物纤维即聚酰胺纤维加入这些组合物时抑制静电荷的累积，并且同时不影响这种聚合物纤维的可燃性。 阻燃抗静电聚合物组合物可与纤维如聚酰胺，聚酯，聚脲，聚氨酯，聚磺酰胺，聚烯烃和聚丙烯酸纤维组合使用。 抗静电效果是通过将纤维涂布或分散在纤维中或在纤维上分散至约12重量％的聚合物组合物获得的，聚合物组合物是以下物质的反应产物：（a）聚氧化烯化合物或其聚酯和（b） 至少一种选自（1）二醇，（2）聚酯和（3）脂族或芳族二酸或（3）的衍生物的反应物，其中至少一种所述反应物被卤化。 通过使阻燃抗静电聚合物组合物包含有效的阻燃比例的元素周期表中的Vb族化合物，可以获得改进的阻燃性能。 通常使用约1：4至约4：2份卤素至锑化合物。 这些化合物是金属的氧化物，例如磷，砷，锑或铋，优选的化合物是三氧化锑。

    Fiber lubricants derived from the oxyalkylation of a glycerol-1,3-dialkylether
    6.
    发明授权
    Fiber lubricants derived from the oxyalkylation of a glycerol-1,3-dialkylether 失效
    衍生自甘油-1,3-二烷基醚的烷氧基化的纤维润滑剂

    公开(公告)号：US4241224A

    公开(公告)日：1980-12-23

    申请号：US82792

    申请日：1979-10-09

    申请人： David D. Newkirk ,  Robert B. Login

    发明人： David D. Newkirk ,  Robert B. Login

    IPC分类号： C07C41/03 ,  C07C43/11 ,  C07C43/13 ,  C08G65/26 ,  C10M107/34 ,  D06M13/148

    CPC分类号： C07C41/03 ,  C08G65/2609 ,  C10M107/34 ,  D06M13/148 ,  C10M2209/107

    摘要： Lubricants and processing aids for synthetic fibers, particularly polyester and nylon fibers, are disclosed comprising compounds having the structural formulas: ##STR1## in which R is an aliphatic group generally having about 3 to about 22 carbon atoms; A is a mixture of residues from ethylene oxide and at least one other lower alkylene oxide, preferably a heteric mixture of oxyethylene and oxypropylene residues in the respective ratio by weight of 20:80 to 90:10; and n has a value to produce a molecular weight of about 300 to about 3000.Where liquid products are desired which contain the higher numbered carbon chain residues, low viscosity compounds can be obtained by oxyalkylating a glycerol-1,3-dialkylether with a mixture of ethylene oxide and 1,2-propylene oxide in the respective ratio as set forth above. Thus it is possible by properly balancing the carbon chain length of the R groups in the lubricant compounds of the invention with the oxyalkylene chain length to obtain products varying between water insoluble and water soluble. The oxyalkylated fiber lubricants of the invention have the properties of viscous liquids, solids or pastes at ambient temperature.

    摘要翻译： 公开了用于合成纤维，特别是聚酯和尼龙纤维的润滑剂和加工助剂，其包括具有以下结构式的化合物：其中R是通常具有约3至约22个碳原子的脂族基团; A是来自环氧乙烷和至少一种其它低级环氧烷的残基的混合物，优选氧化乙烯和氧化丙烯残基的杂化混合物，其重量比分别为20:80至90:10; 并且n具有产生约300至约3000的分子量的值。当需要含有较高编号的碳链残基的液体产物时，可以通过用混合物烷基化甘油-1,3-二烷基醚来获得低粘度化合物 的环氧乙烷和1,2-环氧丙烷以上述各自的比例。 因此，可以通过将本发明的润滑剂化合物中的R基团的碳链长度与氧化烯链长度适当平衡来获得在水不溶性和水溶性之间变化的产物。 本发明的烷氧基化纤维润滑剂在环境温度下具有粘性液体，固体或糊状物的性质。

    Water-insoluble treated textile and processes therefor
    8.
    发明授权
    Water-insoluble treated textile and processes therefor 失效
    水不溶性处理的纺织品及其工艺

    公开(公告)号：US4145469A

    公开(公告)日：1979-03-20

    申请号：US841165

    申请日：1977-10-11

    申请人： David D. Newkirk ,  Robert B. Login

    发明人： David D. Newkirk ,  Robert B. Login

    IPC分类号： D06M15/507 ,  B32B7/00

    CPC分类号： D06M15/5075 ,  D06M15/507 ,  Y10T428/2969 ,  Y10T442/2352 ,  Y10T442/2402

    摘要： There are disclosed processes for preparing a textile treated with a water-insoluble polyester wherein a linear or branched chain water-soluble sulfonate or phosphate group containing polyester is coated or impregnated onto a textile substrate in combination with a crosslinking agent and subsequent to heating to co-react the crosslinking agent with the polyester, the treated textile substrate is exposed to an aqueous solution of a polyvalent metal ion reactive with said sulfonate or phosphate groups in said polyester. Alternatively, there are disclosed processes for preparing a water-insoluble polyester on a textile substrate wherein a branched chain polyester having sulfonate or phosphate groups is coated or impregnated onto a textile substrate, the substrate is dried and subsequently exposed to an aqueous solution of a polyvalent metal ion reactive with said sulfonate or phosphate groups in said polyester. The processes disclosed herein are useful in the preparation of nonwoven fabrics and finished woven fabrics such as sized fabrics including use as a pigment binder in sizing woven fabrics.

    摘要翻译： 公开了制备用水不溶性聚酯处理的纺织品的方法，其中将含有直链或支链的水溶性磺酸酯或磷酸酯基团的聚酯涂覆或浸渍到纺织品基材上并与交联剂组合并随后加热至共混物 将交联剂与聚酯反应，将经处理的织物基材暴露于与所述聚酯中的所述磺酸盐或磷酸酯基反应的多价金属离子的水溶液。

    Linear saturated polyesters of phosphoric acid and halogenated diols as flame-retardant additives and coatings
    10.
    发明授权
    Linear saturated polyesters of phosphoric acid and halogenated diols as flame-retardant additives and coatings 失效

    公开(公告)号：US4315847A

    公开(公告)日：1982-02-16

    申请号：US059170

    申请日：1979-07-20

    申请人： Robert B. Login ,  David D. Newkirk

    发明人： Robert B. Login ,  David D. Newkirk

    IPC分类号： C08G63/692 ,  C08G79/04 ,  D06M15/667 ,  C08K5/52 ,  C08L67/02

    CPC分类号： C08G63/692 ,  C08G79/04 ,  D06M15/667 ,  Y10S428/92 ,  Y10S428/921 ,  Y10T428/2969 ,  Y10T442/2697

    摘要： The present invention provides new linear phosphorus- and halogen-containing flame retardant polyester additives for normally flammable polymers and coatings for normally flammable natural and synthetic films and fibers, for instance, polyester and cellulose ester films and fibers. The phosphorus- and halogen-containing polymers of the invention are water dispersible or can be rendered water-soluble. They can be prepared by reacting a phosphorus acid reactant such as phosphoric acid with at least one halogenated difunctional monomer. The water-soluble polyesters can be cross-linked to render them insoluble in water by heating together with a methylol compound.Said halogenated monomer is preferably an oxyalkylated diacid or diol and said halogen is attached either on one or more aromatic rings or on a cycloaliphatic ring. The halogenated diols useful in preparing the flame-retardant polymer additives of the invention are selected from the group consisting of at least one of the halogenated, saturated diols having the formula: ##STR1## wherein m and p are integers of 2 to 6; n and q in formulas A, C, and D are 0 or integers of 1 to 10 and integers of 1-10 in formula B; wherein in formulas A-C, X which is attached to an aromatic ring represents 1 to 4 halogen atoms; and wherein in formula D, X represents 1 to 2 halogen atoms and Z is hydrogen, a C.sub.1 -C.sub.6 alkyl radical, or phenyl.Polymer fibers and films such as those made from polyethylene terephthalate and cellulose ester fibers and films such as those prepared from cellulose acetate and cellulose triacetate, each containing a flame-retardant amount of the phosphorus- and halogen-containing flame-retardant polymer additives of the invention are resistant to loss of the polymeric flame-retardant additives of the invention during use.