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公开(公告)号:US20110091365A1
公开(公告)日:2011-04-21
申请号:US12919846
申请日:2009-02-27
IPC分类号: C08F212/08 , C01G13/00 , C01G49/00 , C01G3/00 , C01G9/00 , C01G21/00 , C01G11/00 , C01G45/00 , C01G56/00 , C01G31/00 , C01G55/00 , C01G51/00 , C01G53/00 , C01G5/00 , C01G7/00
CPC分类号: C22B3/42 , B01J45/00 , C08F8/30 , C08F8/34 , C08F8/40 , C08F8/44 , C22B11/04 , C22B23/00 , Y02P10/234 , C08F212/08
摘要: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C═S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式(I)的结构中含有叔氮原子的新型凝胶型或大孔吡甲基胺树脂 )作为官能团,其中R 1是由吡啶基,甲基喹啉和甲基哌啶组成的组中的任意取代的基团,R 2是-CH 2 -S-CH 2 COOR 3或-CH 2 -S-C 1 -C 4烷基或-CH 2 -S-CH 2 CH( NH 2)COOR 3或-CH 2 -S-CH 2 -CH(OH)-CH 2(OH)或其衍生物或-C≡S(NH 2),R 3是由H,Na和K组成的组中的基团,m是 1〜4的整数,n和p各自独立地为0.1〜1.9的数,n和p的和为2,M为聚合物基质,其制备方法及其制备方法 尤其用于湿法冶金和电镀。
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公开(公告)号:US20110086935A1
公开(公告)日:2011-04-14
申请号:US12919851
申请日:2009-02-27
IPC分类号: C08F8/32
CPC分类号: C08F8/30 , B01J45/00 , C01G3/003 , C02F1/285 , C02F2101/20 , C02F2101/203 , C08F8/02 , C08F8/44 , C22B3/42 , C22B15/0089 , Y02P10/234 , Y02P10/236 , C08F212/08
摘要: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式结构中含有叔氮原子的新型单分散,凝胶型或大孔吡甲基胺树脂 (I)作为官能团,其中R 1是由吡啶甲基,甲基喹啉和甲基哌啶组成的组中的任选取代的基团,R 2是 - (CH 2)q -COOR 3基团,R 3是由H,Na和 K,m为1〜4的整数,n和p各自独立地为0.1〜1.9的数,n与p的和为2,q为1〜5的整数, M是聚合物基质,其制备方法及其用途,特别是在湿法冶金和电镀中的应用。
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公开(公告)号:US08563622B2
公开(公告)日:2013-10-22
申请号:US12919851
申请日:2009-02-27
CPC分类号: C08F8/30 , B01J45/00 , C01G3/003 , C02F1/285 , C02F2101/20 , C02F2101/203 , C08F8/02 , C08F8/44 , C22B3/42 , C22B15/0089 , Y02P10/234 , Y02P10/236 , C08F212/08
摘要: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式结构中含有叔氮原子的新型单分散,凝胶型或大孔吡甲基胺树脂 (I)作为官能团,其中R 1是由吡啶甲基,甲基喹啉和甲基哌啶组成的组中的任选取代的基团,R 2是 - (CH 2)q -COOR 3基团,R 3是由H,Na和 K,m为1〜4的整数,n和p各自独立地为0.1〜1.9的数,n与p的和为2,q为1〜5的整数, M是聚合物基质,其制备方法及其用途,特别是在湿法冶金和电镀中的应用。
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公开(公告)号:US08562922B2
公开(公告)日:2013-10-22
申请号:US12919846
申请日:2009-02-27
CPC分类号: C22B3/42 , B01J45/00 , C08F8/30 , C08F8/34 , C08F8/40 , C08F8/44 , C22B11/04 , C22B23/00 , Y02P10/234 , C08F212/08
摘要: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C═S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式(I)的结构中含有叔氮原子的新型凝胶型或大孔吡甲基胺树脂 )作为官能团,其中R 1是由吡啶基,甲基喹啉和甲基哌啶组成的组中的任意取代的基团,R 2是-CH 2 -S-CH 2 COOR 3或-CH 2 -S-C 1 -C 4烷基或-CH 2 -S-CH 2 CH( NH 2)COOR 3或-CH 2 -S-CH 2 -CH(OH)-CH 2(OH)或其衍生物或-C = S(NH 2),R 3是由H,Na和K组成的组的基团,m是 1〜4的整数,n和p各自独立地为0.1〜1.9的数,n和p的和为2,M为聚合物基质,其制备方法及其制备方法 尤其用于湿法冶金和电镀。
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公开(公告)号:US20100307979A1
公开(公告)日:2010-12-09
申请号:US12669969
申请日:2008-07-10
CPC分类号: C08F12/36 , B01D15/00 , B01D53/02 , B01D53/64 , B01D2251/90 , B01J13/10 , B01J20/26 , B01J20/261 , B01J20/265 , B01J41/14 , B01J45/00 , C02F1/42 , C02F1/683 , C02F2101/20 , C08F8/30 , C08F8/44 , C08F2800/20 , C22B3/42 , C22B7/006 , Y02P10/234 , C08F212/08
摘要: The present application relates to novel chelate resins which contain, as a functional group, quaternary nitrogen atoms in structures of the general formula (I) in which at least one of the radicals R1 to R3 represents an optionally substituted radical of the series consisting of picolyl, methylquinoline or methylpiperidine, m represents an integer from 1 to 4 and M represents the polymer matrix and X represents a counterion of the series consisting of hydroxide OH−, halide, preferably Cl−, Br−, or sulphate SO42−, a process for their preparation and the use thereof, in particular the use of the novel chelate resins in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及新的螯合树脂,其中含有作为官能团的通式(I)结构中的季氮原子,其中基团R 1至R 3中的至少一个表示任选取代的由吡啶甲基 ,甲基喹啉或甲基哌啶,m表示1至4的整数,M表示聚合物基体,X表示由氢氧化物OH-,卤化物,优选Cl-,Br-或硫酸盐SO 4 2-组成的系列的抗衡离子, 其制备及其用途,特别是新型螯合树脂在湿法冶金和电镀中的应用。
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公开(公告)号:US20090158896A1
公开(公告)日:2009-06-25
申请号:US12087632
申请日:2007-01-26
申请人: Duilio Rossoni , Reinhold Klipper , Bruno Hees , Rudolf Wagner , Stefan Neumann , Olaf Halle , Wolfgang Podszun , Michael Schelhaas
发明人: Duilio Rossoni , Reinhold Klipper , Bruno Hees , Rudolf Wagner , Stefan Neumann , Olaf Halle , Wolfgang Podszun , Michael Schelhaas
CPC分类号: C22B3/42 , B01J45/00 , C22B3/24 , C22B23/0453 , Y02P10/234
摘要: The present invention relates to the use of monodisperse, macroporous chelating resins in the recovery of metals in hydrometallurgical processes, in particular in resin-in-pulp processes.
摘要翻译: 本发明涉及单分散大孔螯合树脂在湿法冶金方法中回收金属的用途,特别是在树脂 - 纸浆法中。
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公开(公告)号:US20130139649A1
公开(公告)日:2013-06-06
申请号:US13512033
申请日:2010-12-02
IPC分类号: B01J45/00
摘要: The present invention relates to chelating resins containing methyleneaminoethylsulfonic acid groups, a process for producing them and also their use for removing heavy metals or metals of value from aqueous solutions having a pH of
摘要翻译: 本发明涉及含有亚甲基氨基乙基磺酸基团的螯合树脂,其制备方法,以及它们用于从pH值<4的水溶液中除去重金属或金属的用途,优选来自电子工业中的工艺用水, 电镀行业或采矿业。
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公开(公告)号:US08211950B2
公开(公告)日:2012-07-03
申请号:US12249148
申请日:2008-10-10
CPC分类号: B01J43/00
摘要: The present invention relates to novel amphoteric ion exchangers which possess not only phthalamide groups of the formula (I) but also —(CH2)mNR1R2 groups and/or if appropriate —(CH2)mNR1R2R3 groups, wherein m is an integer from 1 to 4 and R1, R2, R3 in each case independently of one another are hydrogen, —CH3, —CH2CH3, —CH2CH2CH3, benzyl, —OCH2CH3 or —CH2CH2OH and X is H or Na or K, to a process for production thereof and also use thereof.
摘要翻译: 本发明涉及新型的两性离子交换剂,其不仅具有式(I)的邻苯二甲酰胺基团,而且还具有 - (CH 2)m N R 1 R 2基团和/或如果合适的 - (CH 2)m N R 21 R 3基团,其中m是1至4的整数 R 1,R 2,R 3各自独立地为氢,-CH 3,-CH 2 CH 3,-CH 2 CH 2 CH 3,苄基,-OCH 2 CH 3或-CH 2 CH 2 OH,X为H或Na或K,为其制备方法,并且还使用 其中。
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公开(公告)号:US08177982B2
公开(公告)日:2012-05-15
申请号:US12218435
申请日:2008-07-15
IPC分类号: B01D53/14
CPC分类号: C22B3/42 , B01D53/64 , B01D2253/206 , B01D2257/60 , B01J45/00 , C02F1/683 , C02F2101/20 , C02F2103/10 , C08F8/30 , C22B3/24 , Y02P10/234 , C08F212/08
摘要: The present invention relates to a method of producing novel monodisperse chelate resins based on crosslinked polymer beads containing aminomethyl groups and/or aminomethyl nitrogen heterocyclic groups that have a high uptake capacity for heavy metals and rapid kinetics.
摘要翻译: 本发明涉及一种基于具有高重金属吸收能力和快速动力学的氨基甲基和/或氨基甲基氮杂环基团的交联聚合物珠粒生产新型单分散螯合树脂的方法。
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公开(公告)号:US07708892B2
公开(公告)日:2010-05-04
申请号:US11810520
申请日:2007-06-06
IPC分类号: C02F1/42
CPC分类号: C02F1/42 , B01J41/10 , B01J45/00 , B01J47/016 , C02F2101/103 , C02F2101/105 , C02F2101/20 , C02F2101/203 , C02F2101/206
摘要: The present invention relates to the use of inorganic salts for increasing the adsorption of oxoanions and/or thioanalogues thereof to metal-doped ion exchangers, preferably to iron oxide/iron oxyhydroxide-containing ion exchangers, preferably from water or aqueous solutions, and also the conditioning of these metal-doped ion exchangers having increased adsorption behaviour toward oxoanions and/or thioanalogues thereof by using inorganic salts with the exception of amphoteric ion exchangers which have both acidic and basic groups as functional groups.
摘要翻译: 本发明涉及无机盐用于增加氧化亚氨基和/或其硫代分子对金属掺杂的离子交换剂,优选氧化铁/含羟基氧化铁的离子交换剂,优选水或水溶液的吸附,以及 通过使用无机盐除了具有酸性和碱性基团作为官能团的两性离子交换剂之外,这些金属掺杂的离子交换剂的调理具有增加的吸附行为向氧阴离子和/或硫代分子的吸附行为。
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