3-isothiazolone biocide process
    2.
    发明授权
    3-isothiazolone biocide process 失效
    3-异噻唑酮杀生物剂法

    公开(公告)号:US5466818A

    公开(公告)日:1995-11-14

    申请号:US220763

    申请日:1994-03-31

    CPC分类号: C07D275/03

    摘要: Process for producing substantially separated 5-chloro-2-methyl-3-isothiazolone (CMI) and 2-methyl-3-isothiazolone (MI) from a mixture of their hydrochloride salts, or in a special mixture having a higher ratio of CMI to MI, comprising heating a mixture of CMI.HCl and MI.HCl for a period of time necessary to fully dissociate said CMI.HCl and form substantially pure CMI, but insufficient to fully dissociate said MI.HCl.

    摘要翻译: 从其盐酸盐的混合物中制备基本分离的5-氯-2-甲基-3-异噻唑酮(CMI)和2-甲基-3-异噻唑酮(MI)的方法,或在具有较高CMI比率的特殊混合物中 MI,包括加热CMI.HCl和MI.HCl的混合物一段时间以完全解离所述CMI.HCl并形成基本上纯的CMI,但不足以完全解离所述MI.HCl。

    Bromate stabilizers for 3-isothiazolones
    3.
    发明授权
    Bromate stabilizers for 3-isothiazolones 失效
    溴异构酮的溴酸盐稳定剂

    公开(公告)号:US5145501A

    公开(公告)日:1992-09-08

    申请号:US790943

    申请日:1991-11-12

    CPC分类号: A01N25/22 A01N43/80

    摘要: A composition comprising(a) a 3-isothiazolone compound of the formula ##STR1## wherein R and R.sup.1 are independently selected from hydrogen, halogen or R is a (C.sub.1 -C.sub.4) alkyl group and R.sup.1 is a halogen or R and R.sup.1 may be joined to form an unsaturated 5- or 6-membered carbocyclic ring; Y is hydrogen, a (C.sub.1 -C.sub.18) alkyl group, an unsubstituted or halo-substituted alkenyl or alkynyl of 2 to 8 carbon atoms, a cycloalkyl or substituted cycloalkyl of 3 to 12 carbon atoms, an aralkyl or halo-, (C.sub.1 -C.sub.4) alkyl-, or (C.sub.1 -C.sub.4) alkoxy-substituted aralkyl of up to 10 carbon atoms, or an aryl or halo-, (C.sub.1 -C.sub.4) alkyl-, or (C.sub.1 -C.sub.4) alkoxy-substituted aryl group of up to 10 carbon atoms; and(b) an amount of a metal bromate salt sufficient to stabilize said composition;wherein said composition if free of metal nitrate salt is disclosed. Methods of use of the above compositions are also disclosed.

    3-Isothiazolones as biocides
    6.
    发明授权
    3-Isothiazolones as biocides 失效
    3-异噻唑酮作为杀生物剂

    公开(公告)号:US4310590A

    公开(公告)日:1982-01-12

    申请号:US107006

    申请日:1979-12-26

    摘要: Disclosed novel substituted 3-isothiazolones, salts thereof, metal complexes thereof, their preparation, agricultural compositions containing them, and their utilization in the control of living organisms. In particular, novel 5-(substituted thiocarbamoyl)thio-2-substituted-4-isothiazolin-3-ones and related compounds including 5-piperidino and 5-cyano derivatives are disclosed.

    摘要翻译: 公开的新型取代的3-异噻唑酮,其盐,其金属络合物,它们的制备方法,含有它们的农业组合物及其在控制活生物体中的应用。 特别地,公开了5-(取代的硫代氨基甲酰基)硫代-2-取代-4-异噻唑啉-3-酮和包括5-哌啶子基和5-氰基衍生物的相关化合物。

    Purification of isothiazolones
    10.
    发明授权
    Purification of isothiazolones 失效
    异噻唑酮的纯化

    公开(公告)号:US5008395A

    公开(公告)日:1991-04-16

    申请号:US289069

    申请日:1988-12-22

    IPC分类号: C07D275/02 C07D275/03

    CPC分类号: C07D275/03

    摘要: A process for obtaining pure 2-substituted-3(2H)-isothiazolones is presented, wherein the substituent is alkyl, linear or branched. By developing suitable conditions, the isothiazolone hydrochloride is isolated from the complex reaction media wherein it is formed as readily filterable crystals of high purity. Such purified crystals are then utilized in isolation of isothiazolone of high purity.