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1.发明授权Reducing ethyl acetate concentration in recycle streams for ethanol production processes 有权在乙醇生产过程中减少循环流中的乙酸乙酯浓度公开(公告)号：US09073816B2
公开(公告)日：2015-07-07
申请号：US13339872
申请日：2011-12-29
Applicant: R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco
Inventor： R. Jay Warner , Heiko Weiner , Zhenhua Zhou , Emily Duff , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco
IPC: C07C27/04 , C07C29/80 , C07C29/149 , C07C29/88
CPC classification number: C07C29/80 , C07C29/149 , C07C29/88 , Y02P20/127 , C07C31/08
Abstract: Recycle streams in an ethanol production process are hydrolyzed to reduce ethyl acetate concentration. In the process, acetic acid is hydrogenated to form a crude ethanol product, which undergoes a separation or purification process. Ethyl acetate is formed as a byproduct of the hydrogenation of acetic acid. The hydrolysis of recycle steams from the separation process can reduce the concentration of ethyl acetate, converting some or all of the ethyl acetate to acetic acid and ethanol.
Abstract translation: 在乙醇生产过程中回收料流被水解以减少乙酸乙酯浓度。 在该过程中，将乙酸氢化以形成粗乙醇产物，其经历分离或纯化过程。 乙酸乙酯作为乙酸氢化的副产物形成。 从分离过程中再循环蒸汽的水解可以降低乙酸乙酯的浓度，将部分或全部乙酸乙酯转化为乙酸和乙醇。
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2.发明授权Esterification process using extractive separation to produce feed for hydrogenolysis 有权酯化过程采用萃取分离法生产饲料用于氢解公开(公告)号：US09024089B2
公开(公告)日：2015-05-05
申请号：US13299821
申请日：2011-11-18
Applicant: R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
Inventor： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC: C07C29/12 , C07C29/149 , C07C67/08 , C07C67/58
CPC classification number: C07C29/149 , C07C67/08 , C07C67/58 , C07C69/14 , C07C31/08
Abstract: Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product may be recovered using an extractive separation. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
Abstract translation: 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括酯化乙酸和醇如乙醇以产生酯化产物。 可以使用萃取分离回收酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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公开(公告)号：US09024084B2
公开(公告)日：2015-05-05
申请号：US13456548
申请日：2012-04-26
Applicant: David Lee , Adam Orosco , R. Jay Warner , Victor J. Johnston
Inventor： David Lee , Adam Orosco , R. Jay Warner , Victor J. Johnston
IPC: C07C29/149 , C07C51/12 , C07C29/80 , C07C67/08 , C07C67/54
CPC classification number: C07C51/12 , C07C29/149 , C07C29/80 , C07C67/08 , C07C67/54 , C07C31/08 , C07C53/08 , C07C69/14
Abstract: The present invention is directed to processes for the recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in one or more columns. At least one of the columns is operated at a controlled pressure to enhance separation of ethanol and organics. In one embodiment, there are at least two columns that operate at controlled pressures.
Abstract translation: 本发明涉及从使用低能量方法从乙酸氢化获得的粗乙醇产物中回收乙醇的方法。 将粗乙醇产物在一个或多个塔中分离。 至少有一列在受控的压力下运行，以增强乙醇和有机物的分离。 在一个实施方案中，存在至少两个在受控压力下操作的塔。
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公开(公告)号：US08932372B2
公开(公告)日：2015-01-13
申请号：US13197760
申请日：2011-08-03
Applicant: Victor Johnston , Lincoln Sarager , Mark Scates , Ronald David Shaver , G. Paull Torrence , R. Jay Warner , Heiko Weiner , Trinity Horton , Radmila Jevtic , James Zink , David Lee
Inventor： Victor Johnston , Lincoln Sarager , Mark Scates , Ronald David Shaver , G. Paull Torrence , R. Jay Warner , Heiko Weiner , Trinity Horton , Radmila Jevtic , James Zink , David Lee
CPC classification number: C07C29/149 , C07C29/84 , C10L1/023 , C10L1/026 , C10L1/18 , C10L1/1824 , Y02P20/125 , C07C31/10 , C07C31/08
Abstract: Processes for producing alcohols such as ethanol and propanol from a mixed acid feedstock in an integrated process. In one embodiment, the process comprises the step of carbonylating methanol in the presence of a carbonylation catalyst to form a mixed acid feedstock comprising acetic acid and one or more higher acids, preferably comprising propionic acid. The mixed acid feed is hydrogenated in the presence of a hydrogenation catalyst to form a crude alcohol product comprising ethanol and one or more higher alcohols, preferably including propanol.
Abstract translation: 在一体化方法中从混合酸原料生产醇如乙醇和丙醇的方法。 在一个实施方案中，该方法包括在羰基化催化剂存在下羰基化甲醇以形成包含乙酸和一种或多种较高级酸，优选包括丙酸的混合酸原料的步骤。 混合酸进料在氢化催化剂的存在下氢化以形成包含乙醇和一种或多种高级醇，优选包括丙醇的粗醇产物。
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公开(公告)号：US08927784B2
公开(公告)日：2015-01-06
申请号：US13292914
申请日：2011-11-09
Applicant: David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Kirk Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
Inventor： David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Kirk Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
IPC: C07C29/149 , C07C29/80 , C07C51/12
Abstract: Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
Abstract translation: 从使用低能量过程的乙酸氢化获得的粗乙醇产物中回收乙醇。 将粗乙醇产物在柱中分离以产生包含乙醛的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 从残余物流中回收乙醇产物。
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Patent Agency Ranking
公开(公告)号：US08853468B2
公开(公告)日：2014-10-07
申请号：US13299771
申请日：2011-11-18
Applicant: R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
Inventor： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC: C07C27/04 , C07C27/00 , C07C67/08 , C07C29/149
CPC classification number: C07C29/149 , C07C67/08 , C07C69/14 , C07C31/08
Abstract: Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying, in the vapor phase, acetic acid and an alcohol such as ethanol to produce the esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
Abstract translation: 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括在汽相中酯化乙酸和醇如乙醇以产生酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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公开(公告)号：US08846986B2
公开(公告)日：2014-09-30
申请号：US13094641
申请日：2011-04-26
Applicant: David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
Inventor： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
IPC: C07C29/149 , C07C29/76 , C07C29/80 , C07C31/08 , C07C67/08
CPC classification number: C07C29/149 , C07C29/76 , C07C29/80 , C07C31/08 , C07C67/08 , Y02P20/127 , C07C69/14
Abstract: Recovery of alcohol, in particular ethanol, from a crude product obtained from the hydrogenation of acetic acid using various combinations of membranes and/or distillation columns.
Abstract translation: 从使用膜和/或蒸馏塔的各种组合的乙酸氢化获得的粗产物中回收醇，特别是乙醇。
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公开(公告)号：US08829250B2
公开(公告)日：2014-09-09
申请号：US13178861
申请日：2011-07-08
Applicant: Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston , David Lee
Inventor： Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston , David Lee
IPC: C07C29/149 , C07C29/141 , C07C29/86 , C07C29/80 , C07C29/78 , C07C29/88 , C07C29/90 , C07C67/08
CPC classification number: C07C29/141 , C07C29/149 , C07C29/78 , C07C29/80 , C07C29/86 , C07C29/88 , C07C29/90 , C07C67/08 , C07C31/08 , C07C69/14
Abstract: A process for purifying ethanol by using a finishing reactor to remove impurities, such as ethyl acetate, acetaldehyde, acetic acid, and diethyl acetal, present in ethanol after distilling a crude product from a hydrogenation reactor. The finishing reactor may reduce the impurities in the presence of hydrogen and a catalyst or may hydrolyze the impurities.
Abstract translation: 在从氢化反应器中蒸馏出粗产物后，使用精整反应器来净化乙醇的方法，以除去乙醇中的杂质，如乙酸乙酯，乙醛，乙酸和二乙基缩醛。 精加工反应器可以在氢和催化剂存在下减少杂质，或者可能水解杂质。
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公开(公告)号：US08754268B2
公开(公告)日：2014-06-17
申请号：US13094657
申请日：2011-04-26
Applicant: David Lee , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
Inventor： David Lee , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
CPC classification number: C07C29/149 , C07C29/80 , C07C51/12 , C07C31/08 , C07C53/12
Abstract: A process for removing water from an alcohol mixture, such as an ethanol mixture in the production of ethanol by hydrogenating acetic acid. The water is removed from a distillate of a first column using an adsorption unit, membrane, extractive column distillation, or a combination thereof.
Abstract translation: 通过氢化乙酸从醇混合物中除去乙醇的方法，例如乙醇混合物生产乙醇。 使用吸附单元，膜，萃取柱蒸馏或其组合从第一塔的馏出物中除去水。
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公开(公告)号：US08710280B2
公开(公告)日：2014-04-29
申请号：US13094722
申请日：2011-04-26
Applicant: R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco , Lincoln Sarager
Inventor： R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco , Lincoln Sarager
IPC: C07C27/04
CPC classification number: C07C29/149 , B01D3/002 , B01D3/143 , C07C29/80 , C07C31/08
Abstract: Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid and recovery of unreacted acetic acid from a weak acid stream. The unreacted acetic acid may be recovered as a dry acetic acid composition and may be directly or indirectly fed to the hydrogenation reactor.
Abstract translation: 从乙酸氢化获得的粗乙醇产物中回收乙醇，并从弱酸流中回收未反应的乙酸。 未反应的乙酸可以作为干燥乙酸组合物回收，并且可以直接或间接地进料至氢化反应器。
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